烃源岩—流体相互作用模拟实验研究

为了探讨烃源岩与孔隙流体之间相互作用过程和机理以及有机酸的生成及其影响因素,我们开展了烃源岩-流体相互作用模拟实验研究。实验结果表明：Ⅱ型干酪根形成有机酸的能力大于Ⅰ型干酪根,水的矿化度对有机酸的形成影响甚微,随着温度升高,流体中有机酸的含量也随之增大。pH值对有机酸形成的影响非常明显,中性和碱性条件更有利于生成有机酸。其中乙酸的形成有利于碳酸盐矿物的溶解,而草酸的形成不利于碳酸盐的溶解。温度对烃源岩的影响与烃源岩的矿物组成有很大的关系,对于富碳酸盐烃源岩,Ca、Mg、Na三元素在水中的溶解量,与温度呈反相关的关系,对于贫碳酸盐烃源岩,与反应温度之间则呈现出正相关的关系。而无论碳酸盐含量高低,Si在溶液中的含量都会随着温度的升高而增大。酸性溶液对烃源岩的溶解能力最强,无论原始反应溶液的酸碱性,反应结果都最终趋于弱碱性。流体的含盐量对烃源岩中Mg的溶解影响差异较大,低盐度的流体有利于Mg溶解。     

空气潜孔锤在水源钻井中的应用

空气潜孔锤钻进是以压缩空气作为循环介质来洗孔、冷却钻头,将岩屑从孔底带出孔外的钻进方法。它具有钻井效率高、施工周期短和施工用水少等优点。通过两个不同情况钻孔的实际施工,介绍了施工背景、地层结构、配套设备及施工过程。从应用效果来看,该方法的钻效是传统泥浆钻进的3-4倍。根据水源井施工经验,总结出在干旱缺水和漏失层地区采用空气（泡沫）潜孔锤钻进的操作方法,并对其施工工艺进行了分析,指出了实际施工中的注意事项及应关注的问题。     

测老庙盆地水中铀的存在形式及其找矿意义

本文通过热力学的计算方法,确定了测老庙盆地水中铀的存在形式,分析了铀在水中的迁移规律和沉淀条件。并应用饱和指数的找矿机理,对测老庙盆地的找矿前景提出了水文地球化学依据。     

相山铀矿田变质基底的变质作用期次

相山铀矿田的变质基底,自晋宁期以来经历了长期而复杂的变质变形演化历史,至中生代为止,共经历了4个期次变质作用的叠加改造:中元古代区域热动力变质作用,中元古代后的热接触变质作用,中生代动力变质作用,中生代晚期的热接触变质作用.多期次变质作用的叠加改造,反映了本区自元古宙以来一直是一处地热异常区.相山地区铀成矿期的成矿作用,是一系列构造-岩浆-变质作用叠加的结果.     

运用因子分析评价山东黑泥湾沉积物重金属污染来源

在对山东黑泥湾沉积物中Cu、Pb、Zn、Cd、Hg、As、Cr和有机质进行分析测试的基础上,运用因子分析评价沉积物中重金属污染来源,结果表明,山东黑泥湾沉积物中存在Pb、Zn和Cd污染;主成分分析中前3个主成分的贡献率分别为44.656%、19.068%和18.098%;认为山东黑泥湾重金属污染主要有3个来源:有机质降解、海上船舶排污和环境背景。     

Petroleum composition in the Cuu Long Basin (Mekong Basin) offshore southern Vietnam

The Cuu Long Basin (Mekong Basin) is a rift basin off southern Vietnam, and the most important petroleum producing basin in the country. However, information on petroleum type and characteristics has hitherto been largely unavailable to the public. This paper presents petroleum geochemical data on nine oil samples from four different producing fields in the Cuu Long Basin: the Dragon (Rong), Black Lion (Sutu-Den), Sunrise (Rang ?ong) and White Tiger (Bach Ho) Fields. The oils are highly paraffinic with bimodal normal alkane distributions and show moderate pristane to phytane ratios and a conspicuous hyperbolic decrease in abundance with increasing carbon number of hopane homologues from C₃₀ to C₃₅. The TPP-index of Holba et al. (Holba, A.G., Dzou, L.I., Wood, G.D., Ellis, L., Adam, P., Schaeffer, P., Albrecht, P., Greene, T., Hughes, W.B., 2003. Application of tetracyclic polyprenoids as indicators of input from fresh–brackish water environments. Organic Geochemistry 34, 441–469) is equal to 1 in all samples which in combination with tricyclic triperpane T26/T25 ratios >1 and the n-alkane and hopane distributions mentioned above provide a strong indication of an origin from lacustrine source rocks. This is supported by the absence of marine C₃₀ desmethyl steranes (i.e. 24-n-propylcholestanes) and marine diatom-derived norcholestanes. Based on the overall biological marker distributions, the lakes probably belonged to the overfilled or balanced-fill types defined by Bohacs et al. (Bohacs, K.M., Carroll, A.R., Neal, J.E., Mankiewicz, P.J., 2000. Lake-basin type, source potential, and hydrocarbon character. An integrated sequence-stratigraphic–geochemical framework. AAPG Studies in Geology 46, 3–34). The oils were generated from source rocks at early- to mid-oil-window maturity, presumably Oligocene lacustrine shales that are present in the syn-rift succession. Oils from individual fields may, however, be distinguished by a combination of biological marker parameters, such as the oleanane index, the gammacerane index, the relative abundance of tricyclic terpanes, the proportions of diasteranes and 28-norspergulane, complemented by other parameters. The oils of the Cuu Long Basin show an overall similarity to the B-10 oil from the Song Hong Basin off northern Vietnam, but are markedly different from the seepage oils known from Dam Thi Nai on the coast of central Vietnam.     

鄂尔多斯盆地塔巴庙地区上古生界源岩热演化特征

鄂尔多斯盆地北部主力气源岩太原组、山西组煤系地层热成熟史的研究对本区天然气充注过程和有利目标区预测具有重要的参考价值。在对研究区烃源岩评价和一维、二维地质建模研究的基础上。利用BasinMod盆地模拟软件对单井以及研究区内二维剖面、平面进行了煤系烃源岩热演化史模拟研究。研究结果表明：（1）该区在中三叠世进入生烃门限,中侏罗世以后,烃源岩持续埋深,早白垩世末期至最大埋深（4000m左右）,绝大多数的天然气都在这一阶段生成,早白垩世末构造抬升以后只有少量天然气生成;（2）研究区上古生界太原组和山西组煤系源岩最大累积生烃强度可达到2200×10^8m^3／km^2,对现今天然气的分布具有较强的控制作用。     

西湖凹陷平北地区烃源岩特征及生排烃史

为了综合确定平北地区的主力烃源岩,深化其油气成藏动力学过程研究,在烃源岩分布特征及有机质丰度、类型和成熟度分析的基础上,应用舍油气盆地数值模拟技术,定量恢复了研究区主要烃源岩层系的生排烃历史。研究表明,平北地区主要发育始新统平湖组、渐新统花港组两套烃源岩系,其中平湖组暗色泥岩为主力烃源岩,具较高的有机质丰度、成熟度、生排烃强度与排烃效率;以平湖组为源岩的油气系统应是本区油气勘探的主要目标。     

A dynamic response analysis of tension leg platforms including hydrodynamic interaction in regular waves

A numerical procedure is described for predicting the motion and structural responses of tension leg platforms (TLPs) in waves. The developed numerical approach, in a TLP is assumed to be flexible instead of rigid, is based on a combination of the three dimensional source distribution method and the finite-element method. The hydrodynamic interactions among TLP members, such as columns and pontoons, are included in the motion and structural response analysis. Numerical results are compared with the experimental and numerical ones. The results of comparison confirmed the validity of the proposed approach.     

Facies recognition of some Tertiary coals applied to prediction of oil source rock occurrence

Coals are oil source rocks in many of the Tertiary basins of Southeast Asia. The precursors of these hydrogen rich and oxygen poor coals are coastal plain peats which have mainly developed in an everwet and tropical climate. In these environments water flow and reworking can concentrate liptinitic kerogen in preference to vitrinitic kerogen. The distribution, petrography and chemistry of the coaly Miocene source rocks present in the Kutai Basin are described. The recognition of environmental controls on the accumulation of potentially oil-prone coals and coaly shales in deltaic environments is an aid to predictive source bed recognition in petroleum exploration. Comments on the environment of deposition of coaly sediments in the basins of the Norwegian Sea are discussed with reference to their possible oil and/or gas sourcing potential. The Triassic - Jurassic coals of the Haltenbanken area may become more oil-prone towards the delta margins, and facies mapping could aid oil exploration in this area.