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151.
湘中锑(金)矿床成矿物质来源——Ⅰ.微量元素及其实验地球化学证据 总被引:9,自引:0,他引:9
为了查明湘中盆地中-低温梯(金)矿床的成矿物质来源,文章应用高分辨率ICP-MS、ICP-AES等方法对岩石与矿石进行了系统测定,并结合作者以往分析数据和实验地球化学结果,对该区盆地及周边基底地层与矿床中的微量元素分布特征及其水/岩反应效应进行了综合分析和系统研究。结果表明:Sb、Au等成矿元素在元古界基底碎屑岩中具有高的背景含量,在近似成矿条件下的水/岩反应实验中,成矿元素的淋出率达20%~90%,元古界基底碎屑岩中的金(锑、钨)矿床的周围蚀变围岩中出现明显的金负异常区。而盆地内泥盆系统地层中的高锑含量仅局限于锑矿床(化)及其蚀变围岩中;湘中锑(金)矿床中的矿石与基底碎屑岩具有相似的稀土元素球粒陨石标准化配分曲线特征,以上微量元素地球化学特征充分证明该区锑(金)矿床锑、金等成矿物质主要来源于元古界底碎屑岩。 相似文献
152.
气藏评价尚未结束之前,开发的早期部署工作非常困难。针对洛带气田蓬莱镇组气藏的开发部署工作,利用目前许多新方法对开发层系划分、采气规模、开发规划、合理配产和井网部署等进行了优化研究,对气藏开发提出了指导性意见,且对类似气藏也具有参考意义。 相似文献
153.
成矿流体演化与成矿物理化学 总被引:7,自引:0,他引:7
成矿流体是富含挥发分 (CO2 、CH4等 )是具有较高含盐度的特殊地质流体。本文讨论了在流体演化过程中挥发分的来源 ,指出主要来自水岩作用、有机质分解及地幔去气和岩浆 ;碱金属及卤素同样具有多来源的性质 ,以海水、含盐系淋滤、建造水为主要来源 ,含盐系重熔可以形成富含碱金属的成矿流体。流体演化过程中氢氧同位素、硫同位素的分馏主要与温度、水岩比值或硫源丰度有关。一个重要的结论是 ,成矿流体的形成主要与地质作用有关 ,而流体来源是次要的。海底热水流体的地球化学特征以高δ3 4 S值、中稀土富集及正铕异常为特征。本文总结了热水流体成矿物理化学条件 ,指出水热流体物相点 :1) 10 80℃ ,7.5× 10 8Pa水溶液与硅酸岩熔浆分熔点 ;2 )水溶液的第二个临界点是气水溶液的超临界点 (374.15℃ ,2 .2 1× 10 7Pa) ;3)水溶液的沸点 (≥ 10 0℃ ,≥ 1× 10 5Pa) ;4)水溶液的冰点 (≤ 0℃ ,1× 10 5Pa) ;5 )H2 O CO2 体系的不混溶温度点 (2 6 6℃ ,2 .15×10 8Pa[1 3 ] 等是重要的成矿相变点。 相似文献
154.
Apatite fission track analysis was performed on 56 samples from central Spain to unravel the far field effects of the Alpine plate tectonic history of Iberia. The modelled thermal histories reveal complex cooling in the Cenozoic, indicative of intermittent denudation. Accelerated cooling events occurred across the Spanish Central System (SCS) from the Middle Eocene to Recent. These accelerated cooling events resulted in up to 2.8±0.9 km of denudation in the western Sierra de Gredos and 3.6±1.0 km in the central and eastern Gredos (assuming a paleogeothermal gradient of 28±5 °C and a surface temperature of 10 °C). The greatest amount of denudation (5.0±1.6 km) occurred in the Sierra de Guadarrama. Accompanying rock uplift was 4.7±1.0 and 5.9±1.6 km in the eastern Gredos and Guadarrama, respectively. Most denudation in the Gredos occurred from the Middle Eocene to the Early Miocene and can be related to the N–S stress field, induced by the Pyrenean compression. In the Guadarrama, the greatest denudation was Pliocene to Recent of age and seems related to the ongoing NW–SE Betic compression. The fact that the formation of the E–W trending Gredos coincides with the N–S Pyrenean compression and the creation of the present day morphology of the NE–SW trending Guadarrama with the younger NW–SE Betic compression, indicates that they record the far field effects of Alpine plate tectonics on Iberia. The trend of pre-existing lineaments was of major importance in influencing the style and magnitude of these of far field effects. 相似文献
155.
The mode of occurrence of gold in the Yata micro-disseminated gold deposit is ap-proached through chemical phase studies coupled with ore-dressing monitoring and micro-beam analysis.The results showed that gold occurred for the most part as ultra-microscopic particles adsorbed on the surfaces or fracture planes of pyrite and other sulphides.The proportions of gold of different occurrences were estimated solutions containing nanometer-sized gold particles were prepared following the hydrolysis-reduction procedure and the adsorption of nanometer-sized gold on ordinary sulphides and rocks was experimentally determined.It is evident that sulphides are good adsorbents of gold and this is consistent with geological observations. 相似文献
156.
157.
158.
华北陆块北缘西段狼山—白云鄂博裂谷系中元古代形成的大型多金属矿床 ,是我国重要的铁、稀土、铜、铅、锌矿产地。矿床为产于沉积岩中热水沉积型多金属矿床。其形成受地层、构造控制 ,与裂谷作用有着密切的关系。裂谷系内外分支的地质环境及矿床矿种不同 ,导致矿床特征及成因具有一定差异。白云鄂博铁、稀土矿床为钾、钠、磷等含量较高的热水沉积型 ,霍各乞铜、铅、锌多金属矿床为与中基性火山岩有关的过渡热水沉积型 ,东升庙和甲生盘等铅、锌多金属矿床为热水沉积型。文中将对上述矿床分别进行论述。 相似文献
159.
Abstract: Carbonate rocks of Cambrian (18 samples) and lower-middle Ordovician (11 samples) ages from South Korea were analyzed for sulfur contents of structurally substituted sulfate (SSS) and sulfides and their δ34 S values. The δ34 S values of SSS ranging from +25.9 to +45.2 permil, are averaged as +33.6 and +33.5 permil for the Cambrian and Ordovician rocks, respectively, which indicate high δ34 S values of the Cambro-Ordovician seawater. The SSS contents in the carbonate rocks are low being 2.9 to 17.3 ppm S (averaged as 7.0 ppm S). Sulfide sulfur, on the contrary, is much abundant containing 3 to 1,880 ppm S and the δ34 S values range widely between –17.6 and +31.1 permil. Sulfide sulfur of the studied rocks excluding impure carbonates has an average content of 187 ppm S and δ34 S value of +12.8 permil (n=24). The estimated δ34 S (sulfate–sulfide) values, which range from 13.8 to 25.4 permil in general with a few exceptions from 36.5 up to 52.3 permil for some impure carbonates, may provide evidence for the persistent oceanic anoxia with its temporary recovery during the Cambro-Ordovician time.
The SSS and sulfide sulfurs have often higher δ34 S values than the Mesozoic-Cenozoic ore sulfur (Ishihara et al., 2000). Since carbonate rocks are very reactive with circulating hydrothermal ore solution, high δ34 S values of the Korean ore deposits might be caused to some extent by 34 S enrichment from the host carbonates, resulting in the low SSS contents observed. 相似文献
The SSS and sulfide sulfurs have often higher δ
160.
The Mascot–Jefferson City (M-JC) Mississippi Valley-type (MVT) deposits are in the Valley and Ridge province of the Appalachian orogen in East Tennessee. They have been a major source of zinc for the USA but their age is uncertain and thus their genesis controversial. About 10 specimens from each of 37 sites have been analysed paleomagnetically using alternating field and thermal step demagnetisation methods and saturation isothermal remanence methods. The sites sample limestones, dolostones, breccia clasts and sphalerite–dolomite MVT mineralisation from mines in the Lower Ordovician Kingsport and Mascot formations of the Knox Group. The characteristic remanent magnetisation (ChRM) is carried by magnetite in the limestones, by both magnetite and pyrrhotite in the dolostones and by pyrrhotite preferentially to magnetite in the mineralisation. Mineralized sites have a more intense ChRM than non-mineralised, indicating that the mineralising and magnetisation event are coeval. Paleomagnetic breccia tests on clasts at the three sites are negative, indicating that their ChRM is post-depositional remagnetisation, and a paleomagnetic fold test is negative, indicating that the ChRM is a remagnetisation, and a post-dates peak Alleghanian deformation. The unit mean ChRM direction for the: (a) limestones gives a paleopole at 129°E, 12°N (dp=18°, dm=26°, N=3), indicating diagenesis formed a secondary chemical remanent magnetisation during the Late Ordovician–Early Silurian; (b) dolomitic limestones and dolostone host rocks gives a paleopole at 125.3°E, 31.9°N (dp=5.3°, dm=9.4°, N=7), recording regional dolomitisation at 334±14 Ma (1σ); and (c) MVT mineralisation gives a paleopole at 128.7°E, 34.0°N (dp=2.4°, dm=4.4°, N=25), showing that it acquired its primary chemical remanence at 316±8 Ma (1σ). The mineralisation is interpreted to have formed from hydrothermal fluid flow, either gravity or tectonically driven, after peak Alleghanian deformation in eastern Tennessee with regional dolomitisation of the host rocks occurring as part of a continuum during the 20 Ma prior to and during peak deformation. 相似文献