Geological characteristics and evolution of the eastern Qinghai-Tibetan plateau since the late Cenozoic

The eastern edge of the Qinghai-Tibetan plateau developed an integrated series of late Cenozoic lacustrine, loess, red and moraines deposits. Various genetic sediments recorded rich information of Quaternary palaeoenvironment changes. Xigeda Pliocene lacustrine deposits, formed during 4.2 Ma B.P.–2.6 Ma B.P., experienced nine periodic warm-cold stages. Eolian deposition in western Sichuan began at 1.15 Ma B.P., and the loess-soil sequences successively record fourteen palaeomonsoon change cycles. Red clay in the Chengdu plain record five stages of paleoclimatic change stages since 1.13 Ma B.P.. There was an old glacial period of 4.3 Ma B.P. in the eastern Qinghai-Tibetan plateau. During the Quaternary, there were five extreme paleoclimatic events corresponding to five glaciations. __________ Translated from Geological Bulletin of China, 2007, 26(12): 1620–1626 [译自: 地质通报]     

Pleistocene glacial relief of the central part of Mt. Prokletije (Albanian Alps)

The central and highest area of Mt. Prokletije (Albanian Alps) is situated in northern Albania and eastern Montenegro (at 42°30′N). The highest peak is Maja e Jezerces (2694 m). Detailed geomorphological mapping was used to reconstruct the positions of former glaciers. The longest Ropojana glacier had a length of 12.5 km and surface of 20 km²; others include Valbona Glacier (9.5 km, 10.5 km²), Grbaja Glacier (5 km, 6.7 km²) and Bogićevica Glacier (6 km, 6.9 km²). Three series of moraines can be distinguished: the lowest at an average altitude of 990 m (average ELA 1750 m), the middle series at 1350 m (ELA 1942 m), and the highest at 1900 m (ELA 2123 m). As no advanced dating methods have yet been used to provide a numerical chronological framework for these features, hypotheses are made based on the comparison with the advanced studies of other similar mountains in the Mediterranean region. The moraines of the first stage (lowest series) correspond to one of pre-LGM glaciations (Middle or even Early Würmian), the second stage moraines probably correspond to LGM, and the third stage could be attributed to Younger Dryas. The mapping included a number of inactive and active rock glaciers, as well as three small active glaciers (surface 5 ha and less), at 1980–2100 m altitude, in the area close to Maja e Jezerces.     

Mineralogy and Isotope Geochemistry of Active Submarine Hydrothermal Field at Suiyo Seamount, Izu–Bonin Arc, West Pacific Ocean

This report presents mineralogical, geochemical and isotopic data on samples obtained using the Benthic Multi‐coring System (BMS) to drill a submarine hydrothermal deposit developed in a caldera on the summit of the Suiyo Seamount in the Izu–Bonin Island Arc, south of Japan. This deposit is regarded as the first example of Kuroko‐type sulfide mineralization on a volcano at the volcanic front of an island arc. The mineralization and hydrothermal alteration below the 300 × 150‐m area of active venting was investigated to depths of 2–9 m below the sea floor. Drilling beneath the area of active venting recovered a sequence of altered volcanic rocks (dacite lavas, pyroclastic rocks of dacite–rhyolite compositions and pumice) associated with sulfide veining and patches/veins of anhydrite. No massive sulfide was found, however, and the subsea‐floor mineralization to 10 m depth is dominated by anhydrite and clay minerals with some sulfides. Sulfide‐bearing samples contained high Au (up to 42 ppm), Ag (up to 263 ppm), As (up to 1550 ppm), Hg (up to 55 ppm), Sb (up to 772 ppm), and Se (up to 24 ppm). Electron probe microanalyzer indicated that realgar, orpiment, and mimetite were major As‐bearing minerals. The sulfides were also characterized by high Zn (>10%) compared to Cu (<6.3%) and Pb (<0.6%). The δ²⁰²Hg/¹⁹⁸Hg, δ²⁰²Hg/¹⁹⁹Hg and δ²⁰²Hg/²⁰⁰Hg of the sulfide‐bearing dacite samples and a sulfide chimney decreased with increasing Hg/Zn concentration ratio. The variation of the δ²⁰²Hg/¹⁹⁸Hg ranged from ?2.8 to +0.5‰ to relative to S‐HG02027. The large range of these δ²⁰²Hg/¹⁹⁸Hg was greater than might be expected for such a heavy element and may be due to a predominance of kinetic effects. The variation of δ²⁰²Hg/¹⁹⁸Hg of sulfide‐bearing dacite samples suggested that light Hg isotope in the vapor mixed with oxygenated seawater near sea floor during mineralization. Lead isotope ratios of the sulfide were very similar to those of the dacite lava, suggesting that lead is of magmatic origin. The ⁸⁷Sr/⁸⁶Sr ratio (0.70872) of anhydrite was different from that of the dacite lava, and suggests an Sr derivation predominantly from seawater. Hydrothermal alteration of the dacite in the Suiyo hydrothermal field was characterized by Fe‐sulfides, anhydrite, barite, montmorillonite, chlorite/montmorillonite mixed‐layer minerals, mica, and chlorite with little or no feldspar or cristobalite. Hydrothermal clay minerals changed with depth from montmorillonite to chlorite/montmorillonite mixed‐layer minerals to chlorite and mica. Hydrogen isotope ratios of chlorite/montmorillonite and mixed‐layer, mica‐chlorite composites obtained below the active venting sites ranged from ?49 to ?24‰, suggesting seawater as the dominant fluid causing alteration. Oxygen isotope ratios of anhydrite ranged from 9.2 to 10.4‰ and anhydrite formation temperatures were calculated to be 188–207°C. Oxygen isotope ratios ranged from +5.2 to +9.2‰ for montmorillonite, +3.2 to +4.5‰ for chlorite/montmorillonite mixed‐layer minerals, and +2.8 to +3.8‰ in mixtures of chlorite and mica. The formation temperatures of montmorillonite and of the chlorite–mica mixture were 160–250°C and 230–270°C, respectively. The isotope temperatures for clay minerals (220–270°C) and anhydrite (188°C) were significantly lower than the borehole temperature (308.3°C) measured just after the drilling, suggesting that temperature at this site is now higher than when clay minerals and anhydrite were formed.     

南图尔盖盆地储层成岩作用及孔隙演化

储层储集性能普遍良好是南图尔盖盆地油气资源丰富的主要原因.通过对该盆地储层的岩石学特征、成岩作用及孔隙类型演化分析研究发现,砂岩的成岩作用及孔隙演化对储层的储集性能有着重要影响.在对大量薄片和岩心进行分析的基础上,运用扫描电镜和X衍射粘土分析等手段,对南图尔盖盆地砂岩储层研究结果表明,该区机械压实和压溶作用、杂基充填作用、胶结作用和交代作用使砂岩孔隙度降低,不稳定矿物的溶蚀作用导致储层次生孔隙发育.根据有机质的演化及粘土矿物的变化序列,成岩作用和孔隙演化随埋深具有明显的阶段性:早成岩阶段,孔隙类型以原生孔隙粒间孔为主;中成岩阶段,孔隙类型以原生、次生混合型为主;晚成岩阶段,孔隙类型以次生型为主.综合评价南图尔盖盆地储层发现,阿雷斯库姆组、阿克萨布拉克组和库姆科尔组为Ⅰ类储层,可作为今后油气勘探的主要目的层.     

Upper crustal abundances of trace elements: A revision and update

We report new estimates of abundances of rarely analyzed elements (As, B, Be, Bi, Cd, Ge, In, Mo, Sb, Sn, Te, Tl, W) in the upper continental crust based on precise ICP-MS analyses of well-characterized upper crustal samples (shales, pelites, loess, graywackes, granitoids and their composites) from Australia, China, Europe, New Zealand and North American. Obtaining a better understanding of the upper crustal abundance and associated uncertainties of these elements is important in placing better constraints on bulk crust composition and, from that, whole Earth models of element cycling and crust generation. We also present revised abundance estimates of some more commonly analyzed trace elements (Li, Cr, Ni, and Tm) that vary by > 20% compared to previous estimates. The new estimates are mainly based on significant (r² > 0.6) inter-element correlations observed in clastic sediments and sedimentary rocks, which yield upper continental crust elemental ratios that are used in conjunction with well-determined abundances for certain key elements to place constraints on the concentrations of the rarely analyzed elements. Using the well-established upper crustal abundances of La (31 ppm), Th (10.5 ppm), Al₂O₃ (15.40%), K₂O (2.80%) and Fe₂O₃ (5.92%), these ratios lead to revised upper crustal abundances of B = 47 ppm, Bi = 0.23 ppm, Cr = 73 ppm, Li = 41 ppm, Ni = 34 ppm, Sb = 0.075, Te = 0.027 ppm, Tl = 0.53 ppm and W = 1.4 ppm. No significant correlations exist between Mo and Cd and other elements in the clastic sediments and sedimentary rocks, probably due to their enrichment in organic carbon. We thus calculate abundances of these elements by assuming the upper continental crust consists of 65% granitoid rocks plus 35% clastic sedimentary rocks. The validity of this approach is supported by the similarity of SiO₂, Al₂O₃, La and Th abundances calculated in this way with their upper crustal abundances given in Rudnick and Gao [Rudnick, R., Gao, S., 2003. Composition of the continental crust. In: Rudnick, R.L. (Ed.), The Crust. In: Holland, H.D., Turekian, K.K. (Eds.), Treatise on Geochemistry, vol. 3. Elsevier–Pergamon, Oxford, pp. 1–64.]. The upper crustal abundances thus obtained are Mo = 0.6 ppm and Cd = 0.06 ppm. Our data also suggest a  20% increase of the Tm, Yb and Lu abundances reported in Rudnick and Gao [Rudnick, R., Gao, S., 2003. Composition of the continental crust. In: Rudnick, R.L. (Ed.), The Crust. In: Holland, H.D., Turekian, K.K. (Eds.), Treatise on Geochemistry, vol. 3. Elsevier–Pergamon, Oxford, pp. 1–64.].     

Permeability of compacted granule–clay mixtures

Achieving a sufficiently low permeability for the aggregate-clay mixtures, whether used as the core of embankment dam or soil liner, is essential. The study illustrates the role of granule (bead or aggregate) content and size, confining stress and fabric anisotropy on the permeability of ceramic bead–lean clay and aggregate-fat clay mixtures. It is shown that depending on the plasticity of the clay, the permeability may decrease or increase with bead/aggregate content. The permeability also decreases when either granule size or confining stress increases. It is found that the permeability is affected by fabric anisotropy in such a manner that its value in the horizontal direction (k_h) is more than that in the vertical direction (k_v), however, k_h/k_v decreases towards 1 for bead contents equal to or below 40%. In high bead content mixtures (i.e., 60% beads) k_h/k_v reaches as high as 3 with an increase in the confining stress. The concept of the development of heterogeneous field of density in the clay is also used to demonstrate the impact of granule size and fabric anisotropy on the permeability.     

The upper Volgian Substage in Northeast Siberia (Nordvik Peninsula) and its Panboreal correlation based on ammonites

Section of the middle and upper Volgian substages and basal Boreal Berriasian in the Cape Urdyuk-Khaya (Nordvik Peninsula) is largely composed of dark argillites substantially enriched in C_org. Characteristic of the section is a continuous succession of ammonite, foraminiferal, ostracode, and dinocyst zones known also in the other Arctic areas. Boundaries of the upper Volgian Substage are recognizable only based on biostratigraphic criteria. The succession of the middle Volgian Taimyrosphinctes excentricus to basal Ryazanian Hectoroceras kochi zones is characterized. The range of the substage is revised. The lower Exoticus Zone, where ammonites characteristic of the Nikitini Zone upper part in the East European platform have been found, is referred to the middle Volgian Substage. Newly found ammonites are figured. Two possible positions of the Jurassic-Cretaceous boundary in the Arctic region, i.e., at the lower and upper boundaries of the Chetae Zone at the top of the upper Volgian Substage, are discussed.     

Depositional model and stratigraphic architecture of rift climax Gilbert-type fan deltas (Gulf of Corinth, Greece)

Facies, depositional model and stratigraphic architecture of Pleistocene giant Gilbert-type fan deltas are presented, based on outcrop data from the Derveni–Akrata region along the southern coast of the Gulf of Corinth, Greece. The common tripartite consisting of topset, foreset and bottomset [Gilbert, G.K., 1885. The topographic features of lake shores: Washington, D.C., United States Geol. Survey, 5th Annual Report, 69–123.] has been identified, as well as the most distal environment consisting of turbidites, and is organised in a repetitive pattern of four main systems tracts showing a clear facies and volumetric partitioning.The first systems tract (ST1) is characterised by the lack of topset beds and the development of a by-pass surface instead, thick foresets and bottomset beds, and thick well-developed turbiditic systems. This systems tract (ST1) is organised in an overall progradational pattern. The second systems tract (ST2) is characterised by a thin topset and almost no foreset equivalent. This systems tract is not always well-preserved and is organised in an overall retrograding trend with a landward shift in the position of the offlap break. The offshore is characterised by massive sandy turbidites. The third systems tract (ST3) is characterised by small-scale deltas prograding above the staked topsets of the giant Gilbert-type fan delta. Those small Gilbert-type fan deltas are generally organised in a pure progradation evolving to an aggradational–progradational pattern. In the distal setting of those small Gilbert-type fan deltas, almost no deposits are preserved on the remaining topography of the previous Gilbert-type fan delta. The fourth systems tract (ST4) is characterised by continuous vertically aggrading topsets that laterally pass into aggrading and prograding foresets. Bottomsets and distal turbiditic systems are starved. This fourth systems tract (ST4) is organised in an overall aggrading trend.These giant Gilbert-type fan deltas correspond to the Middle Group of the Corinth Rift infill and their stratigraphic development was strongly influenced by evolving rift structure. They record the migration of the depocenter from the rift shoulder to the rift axis in four main sequences from ca. 1.5 to 0.7 Ma, related to the migration of fault activity. It is worth noting that the maximum paleobathymetry was recorded during the final stage of the progradation of the Middle Group, suggesting that the rift climax was diachronous at the scale of the entire basin. The rapid (< 1 Ma) structural and sedimentological evolution, the migration of fault activity as well as the youth of the Corinth Rift, are probably exceptional factors allowing the characterisation of such diachronism.     

Origin, weathering, and geochemical composition of loess in southwestern Hungary

Loess geochemistry generally reflects paleo-weathering conditions and it can be used to determine the average composition of the upper continental crust (UCC). In this study, major and trace element concentrations were analyzed on loess samples from southwestern Hungary to determine the factors influencing their chemical compositions and to propose new average loess compositions. All studied loess samples had nearly uniform chemical composition, suggesting similar alteration history of these deposits. Chemical Index of Alteration values (58–69) suggested a weak to moderate degree of weathering in a felsic source area. Typical non-steady state weathering conditions were shown on the Al₂O₃–CaO + Na₂O–K₂O patterns, indicating active tectonism of the Alpine–Carpathian system during the Pleistocene. Whole-rock element budgets were controlled by heavy minerals derived from a felsic magmatic or reworked sedimentary provenance. Geochemical parameters indicated that dust particles must have been recycled and well homogenized during fluvial and eolian transport processes.