An X-ray excited optical luminescence study of a zoned quartz crystal from an emerald-bearing quartz vein,Hiddenite, North Carolina,USA

The optical luminescence excited with synchrotron radiation along a preferential orientation of a quartz crystal has been investigated. It is found that the crystal is composed of two distinct regions, only one of which luminesces upon X-ray excitation. This luminescence is generally uniform and exhibits emission bands in the blue (470 nm with a shoulder at 522 nm) and in the UV (340 nm) regions of the spectrum. The branching ratio for the intensity of these bands is sensitive to the excitation energy across the Si K-edge. XANES spectra collected by partial luminescence yield (PLY) suggest that both emission bands originate from the de-excitation of Si atoms in the quartz. The possible defect sites within the crystal structure that could account for the observed luminescence are investigated and discussed. Additional experiments are proposed to verify this assignment of the optical emission bands.     

The Cosmolian program for simulating aeolian dynamics and its application to central Australia

The wide spatial coverage of sand dunes in continental interiors makes the understanding of their activity and accumulation history valuable for palaeoenvironmental reconstructions and the interpretation of landscape evolution. Nevertheless, the study of aeolian landscape development at the million-year timescale is hampered by the complex interaction of factors determining dune migration and the inherently self-destructive nature of their chronostratigraphy, thus limiting the applicability of traditional dating methods. This study presents a standalone program that simulates aeolian transport based on luminescence-derived chronologies coupled with numerical modelling of the accumulation of cosmogenic nuclides. This integrative approach to modelling the history of aeolian landforms reveals phases of emergence of aeolian sand into the landscape, and provides a data-based scheme that facilitates the morphodynamical study of aeolian processes over multiple timescales and up to several millions of years. The application of the program for reanalysing previously reported data from the Australian Simpson Desert reveals multiple pulses of sand dispersion into central Australia at 3.8–3.4, 2.9–2.5 and 1.5–1 Ma, corresponding to pronounced changes in climatic conditions and landscape deformation events. The synchronicity of the results with the established environmental framework that would promote the production and aeolian distribution of sand exemplifies the applicability of process-based modelling in constructing a timeframe of key landscape evolution events in arid environments by studying aeolian deposits. The dependence of the parameters used to determine environmental settings on sand transportation patterns additionally makes the program a powerful tool to further investigate the triggers and mechanisms of aeolian processes.     

On the dose dependency of the bleachable and non-bleachable components of IRSL from K-feldspar: Improved procedures for luminescence dating of Quaternary sediments

The infrared (IR) stimulated luminescence (IRSL) and post-IR IRSL (pIRIR) signals from K-feldspar can, for convenience, be divided into two components, bleachable and ‘non-bleachable’, where the latter corresponds to the ‘residual’ signal observed in sunlight-bleached samples. In this paper, we examine the non-bleachable component of IRSL of K-feldspar for several sedimentary samples from across Eurasia. We observed a large variability in the residual doses among these samples after prolonged exposure to sunlight. By employing multiple elevated temperature (MET) IR stimulations at 50–300 °C, we show that the residual dose increases systematically with stimulation temperature, attaining values as high as ∼50 Gy at 300 °C, even after several hours to tens of hours of exposure to unfiltered sunlight. We examined two samples in detail and found that the bleachable and non-bleachable components produced different dose response curves. Pulse annealing studies showed that the non-bleachable component is more stable than the bleachable component, suggesting that a preheat procedure cannot eliminate the non-bleachable component. Additional experiments revealed that the non-bleachable component is dose dependent. Owing to this dose dependency, we demonstrate mathematically and empirically that the simple subtraction of a residual dose from the measured equivalent dose (D_e) – which is the most common approach employed (if any residual dose is subtracted at all) – will result in underestimation of the actual D_e. We present a method to correct for the dose dependency of the residual dose, which can improve the accuracy of either MET-pIRIR or pIRIR age estimates for samples in which the non-bleachable component represents a significant fraction of the measured signals.     

兰州黄河Ⅱ和Ⅲ级阶地的地层结构、年龄及环境意义

通过对兰州段黄河Ⅱ和Ⅲ级阶地剖面的地层岩性、粒度分析和光释光测年等,认为剖面中被普遍界定为河漫滩沉积的一套厚几米至几十米具水平层理的细粒砂土层是以冲、洪积与黄土互层的交互式沉积,其开始沉积的时期与气候进入冰期或冰阶相对应。据此可将兰州段黄河阶地剖面地层划分为三部分,即:河流砂砾石层、加积层与风成黄土层,分析了这一地层结构的发育过程,指出沉积相的识别和划分对于阶地研究具有重要意义。     

Last glacial megafaunal death assemblage and early human occupation at Lake Menindee, southeastern Australia

The Tedford subfossil locality at Lake Menindee preserves a diverse assemblage of marsupials, monotremes and placental rodents. Of the 38 mammal taxa recorded at the site, almost a third are of extinct megafauna. Some of the bones are articulated or semi-articulated and include almost complete skeletons, indicating that aeolian sediments rapidly buried the animals following death. New optical ages show the site dates to the early part of the last glacial (55,700 ± 1300 yr weighted mean age). This is close to the 51,200-39,800 yr Australia-wide extinction age for megafauna suggested by Roberts et al. [2001, Science 292:1888-1892], but like all previous researchers, we cannot conclusively determine whether humans were implicated in the deaths of the animals. Although an intrusive hearth at the site dating to 45,100 ± 1400 yr ago is the oldest evidence of human occupation of the Darling River, no artifacts were identified in situ within the sub-fossil-bearing unit. Non-anthropogenic causes, such as natural senescence or ecosystem stress due to climatic aridity, probably explain the mortality of the faunal assemblage at Lake Menindee.     

硅灰石矿物发光材料的人工合成研究

对硅灰石矿物发光材料进行了人工合成研究，在合成试样中，分别掺入少量Ｅｕ＾３＋，Ｇｄ＾３＋，Ｐｂ＾２＋，Ｍｎ＾２＋等激活剂，于１０００℃或１１８０℃条件下分别通入Ｈ２Ｓ（ｇ），Ｈ２Ｏ（ｇ）以及用ＮＨ３，Ｈ２Ｏ吸收ＣＯ２（ｇ）等方法进行合成低温ＴＣ型三斜硅灰石和高温型假硅灰石，合成产物通过扫描电镜、Ｘ射线衍射和红外光谱实验，对合成过程中温度高低，时间长短、冷却快慢、降低温度合成高温型假硅灰石的方法进行     

Bioturbation and erosion rates along the soil-hillslope conveyor belt,part 1: Insights from single-grain feldspar luminescence

The interplay of bioturbation, soil production and long-term erosion–deposition in soil and landscape co-evolution is poorly understood. Single-grain post-infrared infrared stimulated luminescence (post-IR IRSL) measurements on sand-sized grains of feldspar from the soil matrix can provide direct information on all three processes. To explore the potential of this novel method, we propose a conceptual model of how post-IR IRSL-derived burial age and fraction of surface-visiting grains change with soil depth and along a hillslope catena. We then tested this conceptual model by comparison with post-IR IRSL results for 15 samples taken at different depths within four soil profiles along a hillslope catena in the Santa Clotilde Critical Zone Observatory (southern Spain). In our work, we observed clear differences in apparent post-IR IRSL burial age distributions with depth along the catena, with younger ages and more linear age–depth structure for the hill-base profile, indicating the influence of lateral deposition processes. We noted shallower soils and truncated burial age–depth functions for the two erosional mid-slope profiles, and an exponential decline of burial age with depth for the hill-top profile. We suggest that the downslope increase in the fraction of surface-visiting grains at intermediate depths (20 cm) indicates creep to be the dominant erosion process. Our study demonstrates that single-grain feldspar luminescence signature-depth profiles provide a new way of tracing vertical and lateral soil mixing and transport processes. In addition, we propose a new objective luminescence-based criterion for mapping the soil-bedrock boundary, thus producing soil depths in better agreement with geomorphological process considerations. Our work highlights the possibilities of feldspar single grain techniques to provide quantitative insights into soil production, bioturbation and erosion–deposition. © 2019 The Authors. Earth Surface Processes and Landforms Published by John Wiley & Sons Ltd.     

Problems associated with luminescence dating of Late Quaternary glacial sediments in the NW Scottish Highlands

Linking the timing of glacial episodes and behaviour to climatic shifts that are documented in ice and marine sedimentary archives is key to understanding ocean-land interactions. In the NW Scottish Highlands a large number of closely spaced (‘hummocky’) moraines formed at retreating glacier margins. Independent age control on one palaeo-glacier limit is consistent with the timing of Younger Dryas (YD) glaciation in the area, but adjacent glacier lobes have remained undated due to the lack of sites and material for ¹⁴C dating. Direct dating of ice-marginal moraines using optically stimulated luminescence (OSL) techniques has never been attempted before in Scotland, but if successful, they may be the most appropriate methods for constraining the age of sediment deposition in the absence of organic material. Coarse-grained quartz and K-feldspar minerals from supraglacial sheet flow deposits and glacilacustrine sediments within ice-marginal moraines were analysed using the single-aliquot regenerative-dose (SAR) protocol. Independent age control and clear geomorphological relationships indicate that all samples should yield YD or post-Last Glacial Maximum (LGM) ages. Quartz OSL shine down curves showed low luminescence sensitivity, significant medium-to-slow components, a weak fast component, and scattered SAR data; Linearly Modulated-OSL (LM-OSL) measurements confirmed that the fast component was weak or absent. In contrast, feldspar infrared stimulated luminescence (IRSL) was highly sensitive with excellent SAR data. However, SAR data from 3 mm diameter aliquots of feldspar (200 grains) give higher than expected equivalent doses (D_e) by an order of magnitude. SAR measurements of small clusters of feldspar grains (ranging from 1–8) considerably broaden the apparent D_e distribution, but even the lowest value is about 2–3 times the expected D_e. Two possibilities arise to explain the quartz and feldspar data: (1) that glacial sequences in the NW Highlands re-work inherited (older) glacial deposits and that some of the pre-Devensian existing glacial landforms have only been modified during Devensian glaciation; or (2) that the sedimentary processes operating in these ice-marginal environments are not conducive to adequate bleaching of quartz and feldspar grains. Our study implies that ice-proximal supraglacial sediments from this region in NW Scotland reflect older ages of deposition, but dating YD sediments has not been possible.     

Postglacial sediment budget of Chilliwack Valley,British Columbia

The paraglacial reworking of glacial sediments by rivers and mass wasting is an important conditioning factor for modern sediment yields in mountainous catchments in formerly glaciated regions. Catchment scale and patterns of sediment storage are important influences in the rate of postglacial adjustment. We develop a quantitative framework to estimate the volume, sediment type, and fractional size distribution of legacy glacial materials in a large (1230 km²) watershed in the North Cascade Mountains in south‐western British Columbia, Canada. Chilliwack Valley is exceptional because of the well‐dated bounds of deglaciation. Interpolation of paleo‐surfaces from partially eroded deposits in the valley allows us to estimate the total evacuated sediment volume. We present a chronology of sediment evacuation from the valley and deposition in the outlet fan, based on infrared stimulated luminescence (IRSL) and ¹⁴ C dating of river terraces and fan strata, respectively. The effects of paraglacial sedimentation in Chilliwack Valley were intensified through a major fall in valley base‐level following ice retreat. The steepened mainstem valley gradient led to deep incision of valley fills and fan deposits in the lower valley network. The results of this integrated study provide a postglacial chronology and detailed sediment budget, accounting for long‐term sorting of the original sediments, lag deposit formation in the mainstem, deposition in the outlet fan, and approximate downstream losses of suspended sediment and wash load. The mass balance indicates that a bulk volume of approximately 3.2 km³ of glacial material has been evacuated from the valley. Copyright © 2012 John Wiley & Sons, Ltd.     

Landscape development in an hyperarid sandstone environment along the margins of the Dead Sea fault: Implications from dated rock falls

In this study, we explored the spatial and temporal relations between boulders and their original in-situ locations on sandstone bedrock cliffs. This was accomplished by combining field observations with dating methods using cosmogenic isotopes (¹⁰Be and ¹⁴C) and optically stimulated luminescence (OSL). Our conclusions bear both on the landscape evolution and cliff retreat process in the hyperarid region of Timna and on the methodology of estimating exposure ages using cosmogenic isotopes.

We recognize three discrete rock fall events, at 31 ka, 15 ka, and 4 ka. In this hyperarid region, the most plausible triggering mechanism for rock fall events is strong ground acceleration caused by earthquakes generated by the nearby Dead Sea fault (DSF). Our record, however, under represents the regional earthquake record implying that ongoing development of detachment cracks prior to the triggering event might be slower than the earthquake cycle.

Cliff retreat rates calculated using the timing of rock fall events and estimated thickness of rock removed in each event range between 0.14 m ky^− 1 and 2 m ky^− 1. When only full cycles are considered, we derive a more realistic range of 0.4 m ky^− 1 to 0.7 m ky^− 1. These rates are an order of magnitude faster than the calculated rate of surface lowering in the area. We conclude that sandstone cliffs at Timna retreat through episodic rock fall events that preserve the sharp, imposing, landscape characteristic to this region and that ongoing weathering of the cliff faces is minor.

A 10%–20% difference in the ¹⁰Be concentrations in samples from matching boulder and cliff faces that have identical exposure histories and are located only a few meters apart indicates that cosmogenic nuclide production rates are sensitive to shielding and vary spatially over short distances. However, uncertainties associated with age calculations yielded boulder and matching cliff face ages that are similar within 1 σ . The use of external constraints in the form of field relations and OSL dating helped to establish each pair's age. The agreement between calculated ¹⁴C and ¹⁰Be ages indicates that the accumulation of ¹⁰Be at depth by the capture of slow deep-penetrating muons was properly accounted for in the study.