FeSO4对铬污染土的稳定特性及风险评价试验研究

采用硫酸亚铁（FeSO4）对铬污染土进行稳定化处理。选用浸出试验、Cr(VI)残留值试验和形态提取试验,研究了粒径和有机质对铬污染土稳定特性的影响规律。试验结果表明,粒径和有机质对铬污染土稳定特性有较大影响。粒径的减小可显著降低稳定土中Cr(VI)和总Cr的浸出浓度及稳定土中Cr(VI)的含量;当污染土粒径小于2 mm时,Fe(II)/Cr(VI)摩尔比为3,稳定土中Cr(VI)和总Cr的浸出浓度分别为4.68、8.9 mg/L,均低于我国《危险废弃物鉴别标准 浸出毒性鉴别》（GB/T5085.3－2007）的限值。有机质添加量的增加可明显降低稳定土中Cr(VI)和总Cr的浸出浓度及Cr(VI)的含量。当Fe(II)/Cr(VI)摩尔比为3时,有机质的添加量为5%,稳定土中Cr(VI)的含量为28.3 mg/kg,低于我国《土壤环境质量标准》（GB15618－2008）中工业和商业用地限值（30 mg/kg）;当有机质的添加量为10%时,稳定土中Cr(VI)的含量为4.8 mg/kg,低于居住用地限值（5 mg/kg）。形态提取试验结果表明：粒径的减小可降低弱酸提取态的铬含量,增加可还原态的铬含量,而对可氧化态和残渣态的铬含量影响不大;有机质可促使弱酸提取态、可还原态的铬转化为可氧化态的铬,而残渣态的铬变化不大。稳定土中铬从活性态向较稳定态转化,是铬稳定土稳定特性和环境风险变化的根本原因。     

Rock Mass Characteristics in Beishan, A Preselected Area for China’s High-Level Radioactive Waste Disposal

Geological and hydrological characteristics, joint geometric features, rock physical and mechanical properties and rock mass quality are studied in the Beishan area, preselected for China’s high-level radioactive waste (HLW) disposal engineering. A comprehensive survey method is developed to study joint geometric features in the outcrop and samples from borehole BS06 into the Xinchang rock mass were tested. The optimal joint sets are determined by rose diagrams and equal-area lower hemisphere plots of joint poles. Results show that: 1) the distribution of joint occurrence obeys a normal distribution, while the distribution of joint spacing obeys a negative exponential distribution; 2) concentric circular and tangent circular sampling windows are applied to study the trace length and the trace midpoint density. Results indicate that tangent circular sampling window is more stable and reasonable; 3) Beishan granite shows high density, low porosity and high strength based on many laboratory tests and the physical properties and mechanical properties are closely related; and 4) a synthesis index, Joint Structure Rating (JSR), is applied to evaluate the quality of rock mass. Through the research results of rock mass characteristics, the Xinchang rock mass in the Beishan preselected area has the favorable conditions for China’s HLW disposal repository site.     

冰碛土体起动泥石流的特征研究

与广泛分布于干旱河谷的宽级配砾石土体特征不同,冰碛土广泛分布在青藏高原地区,属粗大颗粒多、粘粒含量少、摩擦阻力大、粘滞阻力小的宽级配砾石土体。在冰川融雪与降雨的共同作用下冰碛土体可失稳并起动泥石流,形成灾害。针对冰碛土体起动泥石流机理研究薄弱的现状,本文选取波密县帕隆藏布流域的支流嘎弄沟一冰碛土堆积坡面,通过模拟降水与冰雪融水起动冰川泥石流实验,比较不同颗粒组成、不同实验条件下的土体起动泥石流特征,分析其起动成因及力学特性,探讨冰碛土体起动泥石流的机理。研究发现冰碛土体失稳起动泥石流是粘滞阻力降低、孔隙水压力升高、拖曳力与渗流侵蚀共同作用的结果,起动过程受粘土颗粒含量和径流类型的影响。当粘粒含量较高时(>3%),土体通过铲蚀与面蚀形成泥石流;粘粒含量中低时(不高于3%),大部分坡面土体主要经掏蚀与坍塌起动泥石流;粘粒含量过低时(<0.32%),土体难以起动泥石流。在降水作用下土体孔隙水压力迅速增加,易造成土体破坏,起动泥石流;而在冰雪融水的作用下,土体孔隙水压力波动幅度不大时,土体同样可能发生失稳破坏起动泥石流。     

超声波振动下不同应力条件对岩石强度影响的试验

振动有助于碎岩,以往关于振动碎岩机理的研究大多在低频率段展开。为填补超高频率段下振动碎岩机理的空白,采用单轴动静组合加载模式,开展了超声波振动下不同应力条件对岩石强度影响的试验研究,其中超声波振动频率为20kHz,预压范围为100～500N。研究结果表明:当预压小于200N时,岩石内部应力状态无法满足强度准则,岩石强度下降不明显;当预压大于等于200N时,岩石强度随振动时间的增加而逐渐降低且存在最优预压力值(400N)使得岩石强度最低。缩短振动频率与岩石固有频率的差值有利于提高超声波振动碎岩效率。     

渤中凹陷CFD18-2油田高岭石胶结作用及其对储层物性的影响

为探究成岩作用过程中所形成的次生黏土矿物对储层物性的影响,借助偏光显微镜及扫描电镜的镜下分析,并结合储层物性等数据,对渤中凹陷附近沙垒田凸起东南部CFD18-2油田东三段高岭石的特征、类型、成因及其对储层物性的影响进行了研究。研究结果表明：1）研究区高岭石为有机酸溶蚀长石形成的自生高岭石,呈现典型的"手风琴状"及"蠕虫状",常充填于粒间孔、长石次生溶孔及碳酸盐胶结物溶孔中并形成良好的晶间孔隙。2）研究区主要发育两期高岭石,第一期主要充填于早期碳酸盐胶结物溶孔中,呈微小"蠕虫状";第二期充填于铁方解石与铁白云石胶结物溶孔中,部分高岭石具碱性溶蚀特征,且第二期高岭石与晚期伊利石共生。3）研究区东三段储层具备一定的渗流能力,使长石溶蚀形成的"副产物"被流体带走;但在破坏性成岩作用下,储层渗流能力会逐渐变差,最终使得"副产物"堆积于孔隙,降低储层物性。4）高岭石及同期硅质胶结物对储层物性的影响是一把"双刃剑",当高岭石及硅质的体积分数低于6.81%时,长石溶蚀有利于改善储层物性;当高岭石及硅质的体积分数高于6.81%时,则不利于储层物性的改善。     

Effect of Covering-soil Thickness on Crop Growth on Bare Rock nd Gravel Land in an Ecological Restoration Project

To study the mechanism by which the thickness of covering soil effects crop growth in an ecological restoration project of bare rock and gravel land, the physiological characteristics of summer maize were observed during 2010-2015. This experiment was set up on exposed rock land, which had been covered by soil with six different thicknesses: 30 (C30), 40 (C40), 50 (C50), 60 (C60), 80 (C80) and 100 cm (C100). During the experiment, soil physical properties and the physiological traits and yields of crops were recorded. The results indicated several effects. 1) With the same thickness level, soil bulk density of the covering soil increased in successive planting years. There was a logarithmic relationship between soil bulk density and covering thickness. There was also a strong algorithmic relationship between covering thickness and sedimentation coefficient (R²=0.91). 2) The thickness of covering soil had a significant influence on both the height of summer maize, and soil and plant analyzer development (SPAD) values. In each treatment, the growth rates of the crops during the jointing and booting stages were higher than that in the booting to grain filling stage. After two years of land-use, the mean height of the crop in the C50 treatment was 8.16%, 3.32%, 3.31%, 9.86% and 7.55% higher than that for the C30, C40, C60, C80 and C100 treatments, respectively. The differences between treatments were significant (p < 0.05). SPAD values were highest at the heading stage. The highest value for the C50 treatment was 298.41 after two years of land-use. 3) Soil thickness significantly affected yields and the water use efficiency (WUE) of summer maize. The highest average crop yield and WUE value during the experimental period for the C50 treatment were 4614.12 kg hm^-2 and 13.57 kg hm^-2 mm, respectively. For the C50 treatment the multi-year average water use efficiency was significantly higher than that of the other treatments in 2010-2015. In conclusion, a soil thickness of 50 cm covering the bare exposed rock was adequate as a tillage layer for the crop, and all crop growth indexes in this treatment were better than for other soil thicknesses. The results provide a scientific basis for the land remediation and ecological restoration of bare rock and gravel land. At the same time, for Africa, where one-third of the land is desert, arable land resources are relatively scarce and agricultural ecology is fragile, can serve as a significant reference to improve the ecological environment, develop arable land resources and increase agricultural income.     

冰力学参数的超声波测试研究

利用非线性高能超声测试设备及超声波(纵波、横波)波速与物体力学参数的关系,对人造冰样进行了冰样力学参数(杨氏模量、泊松比、剪切模量、体积模量)随温度变化的研究。通过MATLAB进行所测数据曲线拟合,得到超声波波速在人造冰样中随温度的变化规律,进而由理论公式推导所测人造冰样力学参数随温度的变化规律。结果表明:冰样中超声波波速随温度降低而升高,冰样的杨氏模量、泊松比、剪切模量、体积模量也都随温度降低而升高。本研究有助于超声波检测法在冰样物理力学性质测量中的应用,为开展南极冰盖、海冰以及终年冻土等力学及流动特性研究提供理论模型和实验数据。     

Upscaling of transmissivity,derived from specific capacity: a hydrogeomorphological approach applied to the Doon Valley aquifer system in India

Transmissivity (T) is one of the most important parameters in groundwater studies, and is generally estimated from pumping tests. T can also be deduced from abundantly available specific-capacity (Q/s) data by using analytical and/or empirical approaches, further upscaled by geostatistical methods. A different, remote sensing based, hydrogeomorphological approach is proposed, to upscale T from point- or well-scale to aquifer-scale, and it is applied to the piedmont alluvial aquifer system of Doon Valley in India. In the first step, Q/s and T data-pairs available from aquifer tests were used to establish an empirical, logarithmic relation. Subsequently, satellite imagery along with available data from published and unpublished maps, literature sources and ground surveys were used to divide the aquifer system into major hydrogeomorphological domains that control the groundwater occurrence and flow. Then, the T data derived from Q/s (using the empirical relation) and that available from pumping tests at well-scale were upscaled to aquifer-scale by averaging the T values within each hydrogeomorphological domain. Such a stratification approach is especially useful in areas where availability of only a few data-pairs of known Q/s and T limit the use of geostatistical techniques. A comparative study of the published empirical relations between Q/s and T in various hydrogeologic settings revealed that the relation obtained for Doon Valley aquifer system is close to that found for a similar alluvial aquifer system in Morocco.     

不同方法提取马氏珠母贝外套膜胶原蛋白理化性质比较

【目的】系统分析不同方法提取的马氏珠母贝(Pinctada martensii)外套膜胶原蛋白的理化性质及生物学功能。【方法】分别采用酸-酶法和热水法从外套膜中提取得到两种胶原蛋白(A-PSC(Pm)和HSC(Pm)),对其氨基酸组成、微观结构及热变性温度等理化特性进行比较分析。【结果】HSC(Pm)提取率高于A-PSC(Pm);HSC(Pm)中,Gly、Glu与Arg相对含量较高,分别为20.16%、17.57%和10.07%;而A-PSC(Pm)中,Glu、Asp与Arg相对含量为19.67%、11.63%和10.07%;紫外光谱和红外光谱分别显示,两种胶原蛋白均在220 nm左右有强吸收峰,且具有典型的胶原蛋白特征带(酰胺A、B、Ⅰ、Ⅱ和Ⅲ带);扫描电镜结果显示,A-PSC(Pm)呈致密多孔网状结构,HSC(Pm)则基本为薄片状;DSC分析结果表明,HSC(Pm)具有更好的热稳定性。【结论】酸-酶法及热水法提取的胶原蛋白均具有类V型胶原蛋白特性,其结构特征及其理化性质均存在差异,可根据需求选择特定的胶原蛋白提取方法用以开发不同类型的产品。     

Collapsing loess-like soil in western Saudi Arabia

Earth fissures have developed at Wadi Al-Yutamah, western Saudi Arabia. The fissues are associated with land subsidence which is considered to be due to both rapid draw down of the ground-water level and hydrocompaction of the wadi soil after flooding. This phenomenon is relatively recent in the area.The wadi soil was investigated and classified in the field, and disturbed and undisturbed samples were collected for laboratory testing and analysis. The engineering properties of the wadi soils were determined, including in situ field density, specific gravity, liquid limit, plastic limit, plasticity index, shrinkage limit, and consolidation characteristics such as total settlement and coefficient of subsidence (collapse).Four types of silty soil of different colours were identified, in addition to yellowish-brown sand (representing the dunes) which accumulated on the surface of the study area. The silty soils include yellowish-brown silty sand, yellowish-gray silt, pale brown silt and yellowish-brown clayey silt. The results of X-ray diffraction analysis indicated that the clay is mainly kaolinite and illite with minor smectite. The dominant soil type in the study area is silt of low plasticity, high void ratio and low density which decreased with depth. This soil was classified as loess-like materials.The studied soils are of a collapsing type, and settlement is greatly increased by excessive wetting under constant pressure. The calculated coefficients of subsidence (collapse) of the soils at different depths generally increased with decreasing soil density and ranged between 3·1% and 10·8%. The wadi soils are considered to pose a moderate problem when wetted.