Geochemical and Petrological Studies on the Early Carboniferous Sidingheishan Mafic–Ultramafic Iintrusion in the Southern Margin of the Central Asian Orogenic Belt, NW China

The Sidingheishan mafic-ultramafic intrusion is located in the eastern part of the Northern Tianshan Mountain, along the southern margin of the Central Asian Orogenic Belt in northern Xinjiang autonomous region of China. The Sidingheishan intrusion is mainly composed of wehrlite, olivine websterite, olivine gabbro, gabbro and hornblende gabbro. At least two pulses of magma were involved in the formation of the intrusion. The first pulse of magma produced an olivine-free unit and the second pulse produced an olivine-bearing unit. The magmas intruded the Devonian granites and granodiorites.An age of 351.4±5.8 Ma(Early Carboniferous) for the Sidingheishan intrusion has been determined by U-Pb SHRIMP analysis of zircon grains separated from the olivine gabbro unit. A U-Pb age of 359.2±6.4 Ma from the gabbro unit has been obtained by LA-ICP-MS. Olivine of the Sidingheishan intrusion reaches 82.52 mole% Fo and 1414 ppm Ni. On the basis of olivine-liquid equilibria, it has been calculated that the MgO and FeO included in the parental magma of a wehrlite sample were approximately10.43 wt% and 13.14 wt%, respectively. The Sidingheishan intrusive rocks are characterized by moderate enrichments in Th and Sm, slight enrichments in light REE, and depletions in Nb, Ta, Zr and Hf. The ε_(Nd)(t) values in the rock units vary from +6.70 to +9.64, and initial ~(87)Sr/~(86)Sr ratios range between 0.7035 and0.7042. Initial ~(206)Pb/~(204)Pb, ~(207)Pb/~(204)Pb and ~(208)Pb/~(204)Pb values fall in the ranges of 17.23-17.91,15.45-15.54 and 37.54-38.09 respectively. These characteristics are collectively similar to the Heishan intrusion and the Early Carboniferous subduction related volcanic rocks in the Santanghu Basin, North Tianshan and Beishan area. The low(La/Gd)_(PM) values between 0.26 and 1.77 indicate that the magma of the Sidingheishan intrusion was most likely derived from a depleted spinel-peridotite mantle.(Th/Nb)_(PM)ratios from 0.59 to 20.25 indicate contamination of the parental magma in the upper crust.Crystallization modeling methods suggest that the parental magma of the Sidingheishan intrusion was generated by flush melting of the asthenosphere and subsequently there was about 10 vol%contamination from a granitic melt. This was followed by about 5 vol% assimilation of upper crustal rocks. Thus, the high-Mg basaltic parental magma of Sidingheishan intrusion is interpreted to have formed from partial melting of the asthenosphere during the break-off of a subducted slab.     

滇东南富宁地区基性侵入岩及喷出岩时代

在滇东南富宁地区基性侵入岩、喷出岩较发育,前人将其划分为"半瓦型"侵入岩、"安定型"侵入岩和"龙康型"喷出岩3类,3类岩石普遍缺乏可靠的同位素年代学资料。在对富宁地区基性侵入岩、喷出岩进行区域地质调查的基础上,应用LAICP-MS技术对其进行锆石U-Pb测年,在半瓦型侵入岩和安定型侵入岩中分别获得了254.0±2.0Ma和244.2±4.4Ma的加权平均年龄,在龙康型喷出岩中获得251.9±3.0Ma和255.92±0.72Ma加权平均年龄。结合野外调查和综合研究,将富宁地区"安定型"侵入岩的时代界定于中三叠世,将"半瓦型"侵入岩和"龙康型"喷出岩的时代界定于晚二叠世。     

Zircon SHRIMP U-Pb dating of the Neogene coral reefs,Xisha Islands,South China Sea: implications for tectonic evolution

The Xisha Block is a minor one in the South China Sea and an important tectonic unit in the northwestern part of the region. Zircon SHRIMP U-Pb ages for three volcanic intrusive core samples from Xike-1, an exploratory well penetrating the bioherms of the Xisha Islands. The core samples are from the Miocene reef carbonate bedrock and are recognized as dark-gray biotite-hornblende gabbro, gray fine-grained biotite diorite, and gray fine-grained granite, respectively. Zircon cathodoluminescence (CL) images and trace Th, U and Pb compositions of the zircons show that these rocks are of volcanic intrusive origin. Zircon SHRIMP U-Pb dating yielded six groups of ages, ranging from 2451-1857 Ma to early Cretaceous, which indicate that the formation and evolution of the Xisha Block was affected by the evolution and closure of Neotethys Ocean, probably within its eastern extension into South China Sea. Both old, deep-sourced material, including fragments from Rodina supercontinent, and recent mantle-derived magma products contributed to the emergence and formation of the Xisha block. The SHRIMP U-Pb results also proved that this process differed from that of the Kontum massif, the Hainan Block, and the South China Block, but is similar to that of the Nansha and Zhongsha blocks. The process was associated with the effects of Yanshanian magmatism induced by subduction mechanisms of the Paleo-Pacific Plate or the reworking of the multiple magmatisms since the Early to mid-Yanshanian, possibly jointly experienced by the Xisha-Zhongsha-Nansha Block.     

内蒙古1∶5万乌音呼日勒庙等四幅区域地质矿产调查新进展

内蒙古1∶5万乌音呼日勒庙等四幅区域地质矿产调查项目取得的新进展及主要成果为: 根据岩石组合、动植物化石及同位素年龄等,重新厘定、划分了16个岩石地层填图单位,在多个组段沉积岩层位中首次发现丰富的动、植物化石,建立了各地层年代学格架; 将侵入岩重新解体划分为4个填图单元,并建立了侵入岩年代学格架; 新发现1处规模较大的韧性变形带,主要为逆—左行走滑韧性断层,时代归属于中三叠世末期,为额尔古纳河—阿龙山NE向韧性变形域的南部延伸; 新发现矿(化)点20处,其中金属矿点3处,金属矿化点6处,非金属矿点9处,非金属矿化点2处; 总结了该区成矿规律,圈定了成矿远景区及找矿靶区。     

黑龙江省塔河县宝兴沟金矿床中生代侵入岩及其对成矿作用的制约

宝兴沟金矿床为近年来在漠河前陆盆地南缘新发现的大型金矿床。区内发育石英闪长岩、闪长玢岩、花岗细晶岩等侵入岩,矿体主要产于石英闪长岩、闪长玢岩内部及其与二十二站组砂岩的内外接触带中。地球化学研究表明,石英闪长岩具高钾、低钛、富碱特征,花岗细晶岩具高硅、高钾、低钛、富碱特征,二者均为高钾钙碱性系列岩石,富集大离子亲石元素Rb、Ba、Sr等,亏损高场强元素Nb、Ta、Ti和重稀土元素Yb、Y,但二者稀土元素特征和配分曲线差异较大,不具成因联系。矿石与石英闪长岩、闪长玢岩具有相似的微量元素、稀土元素组成和稀土元素配分曲线,表明石英闪长岩、闪长玢岩为成矿提供了热液和成矿物质等,与成矿具有密切的成因联系。LA-ICP-MS锆石U-Pb同位素测年结果显示,石英闪长岩成岩时间为118.13~121.77 Ma,限定了宝兴沟金矿床的形成时间不早于118Ma,为早白垩世,形成于太平洋板块俯冲后的伸展环境。漠河前陆盆地除中-晚侏罗世侵入岩外,早白垩世中酸性侵入岩对区域成矿也具有重要的作用,是今后找矿的重要方向之一。     

扬子陆块西缘江浪穹窿超基性岩的成因:锆石U-Pb定年、岩石地球化学及Sr-Nd同位素

江浪穹窿位于扬子陆块西缘,本文作者在穹窿南部新发现一套侵入于二叠系及志留系的超基性岩,岩石主要由蛇纹石(约60%)、橄榄石(约30%)和少量磁铁矿(约5%)、角闪石(约5%)组成。为探讨超基性岩的成因,本文进行了LA-ICP-MS锆石U-Pb定年、岩石地球化学及Sr-Nd同位素研究。定年结果表明,超基性岩中发育大量2427~430 Ma的捕获锆石,最年轻一组岩浆锆石²⁰⁶Pb/²³⁸U加权平均年龄为222.3±4.4 Ma(MSWD=1.9,n=6)。主微量元素分析显示岩石：(1)具有低的SiO₂含量(46.76%~39.07%)、高的Mg#值(82.3~74.0)与Cr、Co、Ni丰度;(2)稀土元素含量(ΣREE平均31.8 μg/g)与(La/Yb)_N值(5.26~1.38)偏低,稀土配分型式较为平坦,具有较弱的Ce负异常(Ce/Ce^*=0.80~0.67);(3)富集大离子亲石元素Rb、Ba和U,亏损高场强元素Zr和Hf;(4)(Th/Yb)_PM值(29.8~1.56)、(Th/Ta)_PM值(0.22~0.03)、(La/Nb)_PM值(1.91~0.39)及La/Sm值(5.88~1.11)较低。Sr-Nd同位素分析显示,超基性岩具有较低的(⁸⁷Sr/⁸⁶Sr)_i值(0.706872~0.702598)和高的ε_Nd(t)值(8.02~5.64),成分接近于亏损地幔和岛弧玄武岩,计算表明地壳物质的混染程度低于5%。结合前人研究成果,本文认为超基性岩结晶年龄为222.3 Ma,可能形成于古特提斯洋闭合阶段的岛弧背景;原始岩浆来自高度部分熔融的地幔源区,上升侵位过程中可能经历了铬铁矿与橄榄石的分离结晶作用。此外,捕获锆石的年龄谱反映江浪穹窿很可能存在太古宙—古元古代变质基底,并且具有Rodinia超大陆会聚—裂解以及泛非事件的地质年龄记录。     

奇异性理论在弱异常信息提取中的应用—以冀北隐伏中-酸性侵入岩体为例

冀北地区是河北省矿产资源重要聚集地之一,成矿条件优越,其中中-酸性侵入岩体与银铅锌多金属矿床成矿密切相关。然而,大量的第四系覆盖压制了一些深部及隐伏弱异常成矿信息,使得常规化探方法在该覆盖区提取效果微弱。本文运用奇异性分析及主成分分析对冀北1：20万水系沉积物常量元素化探数据进行分析处理,提取区内成矿元素弱异常,并将其与未进行奇异性处理的结果进行对比。结合区域地质背景、物化探资料圈定覆盖区内与中-酸性侵入岩体有关的异常区,对成矿作用、成矿规律进行分析、讨论,以期揭示区内元素富集规律。结果显示,上述组合方法可以有效提取元素弱异常并进行成矿有利区圈定,并且圈定位置与已知岩体位置、区域构造条件相吻合,共圈出隐伏异常点7个,推测其为成矿远景区。     

龙首山几个镁铁-超镁铁质岩体比较

文章选择龙首山隆起区金川、塔马子沟、毛草泉、小口子、藏布台几个镁铁-超镁铁质岩体进行地质、地球化学比较研究,发现岩体普遍具有橄榄石堆晶特征,中段金川岩体以二辉橄榄岩为主要特征,外围岩体以单辉橄榄岩为特征.地球化学数据显示,这些镁铁-超镁铁质岩体处于相同的岩石系列,源区具有相似性,岩体含矿差异主要源自岩浆演化.结合地质综合场模型,提出金川外围岩体在龙首山隆起区,沿构造带东西长约80～100km范围存在金川深部岩浆房响应的产物.     

苏鲁地体胡家林和梭罗树三叠纪变质超基性岩U-Pb、Lu-Hf和O同位素地球化学研究

胡家林超基性岩单矿物氧同位素组成基本上接近正常地幔值（石榴石4.7‰~5.4‰)。梭罗树超基性岩及其共生榴辉岩具有氧同位素正异常（超基性岩中石榴石9.8‰~10.4‰;榴辉岩中石榴石9.0‰~12.1‰)，指示超基性岩和榴辉岩原岩可能在板块俯冲之前，在浅层或地表环境中经历过蛇绿岩套顶部相似的低温热液蚀变。胡家林超基性岩样品中的变质锆石年龄227.2±2.4 Ma，可能代表俯冲板块经峰期超高压变质后，折返初期从金刚石榴辉岩相降压至柯石英榴辉岩相过程中流体活动和错石结晶的年龄。梭罗树超基性岩样品中变质锆石的一组变质年龄240.4±2.4 Ma代表了板块俯冲至超高压峰期变质之前流体活动过程中锆石的结晶年龄，而另一组变质年龄217.1±3.3 Ma代表了板块折返过程中高压榴辉岩相重结晶条件下的锆石结晶年龄。从变质锆石到重结晶锆石，其Th/U和176Lu/177Hf呈现出相似的变化趋势，可能指示了变质作用对锆石中的U-Th-Pb同位素体系和Lu-Hf同位素体系产生相似的地球化学效应。梭罗树超基性岩可能来源于俯冲地壳内部的“残留地幔”。胡家林超基性岩重结晶锆石中继承的放射成因铅或者来源于俯冲地壳与仰冲盘底部石榴辉石岩相地幔发生的壳幔相互作用而导致碎屑锆石的重结晶；或者来源于超基性岩岩浆在板块俯冲前，通过底侵作用上升侵位与地壳物质发生混染形成岩浆锆石，这种岩浆错石在超高压变质过程中经历了重结晶。     

塔里木克拉通东北缘二叠纪镁铁质岩浆氧化物与硫化物成矿条件对比

塔里木克拉通东北缘坡北、磁海等地二叠纪幔源岩浆活动形成了镍钴硫化物矿床和铁钴氧化物矿床,两者赋矿镁铁-超镁铁岩体的年龄相近(290～260 Ma),主、微量元素和Sr-Nd-Hf同位素组成相似,分配系数接近的微量元素比值分布于相同趋势线,揭示两者岩浆源区相同,可能为俯冲板片流体交代的亏损地幔或软流圈地幔。两类矿床镁铁-超镁铁质岩中Co与Ni含量正相关,Co主要富集在基性程度高的岩石中;块状硫化物与磁铁矿矿石中Co与Ni相关性差,Co和Ni具有不同的富集机制,Co热液富集作用明显。北山镁铁-超镁铁杂岩体是地幔柱相关软流圈上涌,诱发俯冲板片交代的亏损岩石圈地幔发生部分熔融,形成的高镁母岩浆演化过程中经历壳源混染、硫化物饱和富集镍钴形成铜镍钴硫化物矿床,富铁母岩浆氧逸度高、富水,岩浆分离结晶磁铁矿、叠加热液作用富集钴,形成铁钴氧化物矿床。