L'hétérogénéité du manteau supérieur à l'aplomb du volcan de Nyos (Cameroun) révélée par les enclaves ultrabasiques

Volcanic deposits from the lake Nyos (Cameroon) contain ultrabasic xenoliths: lherzolites, harzburgites and websterites, sometimes containing amphibole. Major and trace element compositions of clinopyroxene and amphibole allow the recognition of an old depletion event followed by two episodes of incompatible-element enrichment. One is high in light rare-earth elements, while the other one is low in these elements, but high in U and Th. Their relative chronology is not yet established. To cite this article: R. Temdjim et al., C. R. Geoscience 336 (2004).     

科马提岩成因研究述评

科马提岩仅限于超镁铁质熔融体(Mgo>30wt%)所生成的火山岩.它具有高温、高密度和低粘度的特征.以及独特的地球化学性质.结合高压熔融实验成果,评述了有关科马提岩成因的干地幔熔融模式、湿地幔熔融模式、温超镁铁质板块俯冲模式和热地幔柱熔融模式,并认为热地幔柱熔融模式较好地解释了科马提岩的成因.     

Occurrence of Alaskan-type mafic-ultramafic intrusions in the North Qilian Mountains, northwest China: Evidence of Cambrian arc magmatism on the Qilian Block

Field relationships, mineralogy and petrology, whole‐rock chemistry, and age of the Zhamashi mafic–ultramafic intrusion in the North Qilian Mountains, northwest China, have been studied in the present work. The Zhamashi intrusive body consists of ultramafic, gabbroic, and dioritic rocks in a crudely concentrically zoned structure. The ultramafic rocks are layered cumulates with rock types varying continuously from dunite through wehrlite and olivine clinopyroxenite to clinopyroxenite. The gabbroic and dioritic rocks are also layered or massive cumulates with rock types varying continuously from noritic gabbro through hornblende gabbro to diorite. The ultramafic and adjoining gabbroic rocks are discontinuous in lithology and discordant in structure across the interface. The interface is steep, sharp, and fractured. Contact metamorphic zones are well developed between the Zhamashi intrusive body and the country rock. The concentrically zoned structure of the intrusive body and the intrusion into the continental crust are the two main pieces of evidence for considering that the Zhamashi intrusion is Alaskan‐type. The mineral chemistry of the chromian spinels (Cr‐spinels) and clinopyroxenes, and the variation trend of the whole‐rock compositional plot in the (Na₂O + K₂O)–FeO–MgO (AFM) diagram are also supportive of this consideration. The age of the Zhamashi intrusive body, determined with sensitive high mass‐resolution ion microprobe on the zircon grains, is 513.0 ± 4.5 Ma. Parental magma of the Zhamashi intrusion is compositionally close to the primitive magma produced by partial melting of the mantle peridotite. It was differentiated by fractional crystallization at low total pressure and under H₂O‐rich conditions in an arc environment to form all the major rock types. The concentrically zoned structure of the Zhamashi intrusive body was constructed in two stages: formation of a stratiform‐type layered sequence, followed by diapiric re‐emplacement. The occurrence of the Alaskan‐type intrusion suggests an active continental margin and Cambrian arc magmatism for the northern margin of the Qilian Block.     

Oligocene crustal xenolith‐bearing alkaline basalt from Jandaq area (Central Iran): implications for magma genesis and crustal nature

The Oligocene alkaline basalts of Toveireh area (southwest of Jandaq, Central Iran) exhibit northwest–southeast to west–east exposure in northwest of the central‐east Iranian microcontinent (CEIM). These basalts are composed of olivine (Fo_70–90), clinopyroxene (diopside, augite), plagioclase (labradorite), spinel, and titanomagnetite as primary minerals and serpentine and zeolite as secondary ones. They are enriched in alkalis, TiO₂ and light rare earth elements (La/Yb = 9.64–12.68) and are characterized by enrichment in large ion lithophile elements (Cs, Rb, Ba) and high field strength elements (Nb, Ta). The geochemical features of the rocks suggest that the Toveireh alkaline basalts are derived from a moderate degree partial melting (10–20%) of a previously enriched garnet lherzolite of asthenospheric mantle. Subduction of the CEIM confining oceanic crust from the Triassic to Eocene is the reason of mantle enrichment. The studied basalts contain mafic‐ultramafic and aluminous granulitic xenoliths. The rock‐forming minerals of the mafic‐ultramafic xenoliths are Cr‐free/poor spinel, olivine, Al‐rich pyroxene, and feldspar. The aluminous granulitic xenoliths consist of an assemblage of hercynitic spinel + plagioclase (andesine–labradorite) ± corundum ± sillimanite. They show interstitial texture, which is consistent with granulite facies. They are enriched in high field strength elements (Ti, Nb and Ta), light rare earth elements (La/Yb = 37–193) and exhibit a positive Eu anomaly. These granulitic xenoliths may be Al‐saturated but Si‐undersaturated feldspar bearing restitic materials of the lower crust. The Oligocene Toveireh basaltic magma passed and entrained these xenoliths from the lower crust to the surface.     

Tectonics of an Early Carboniferous forearc inferred from a high-P/T schist-bearing conglomerate in the Nedamo Terrane, Northeast Japan

The Nedamo Terrane, an Early Carboniferous accretionary complex, is the oldest biostratigraphically dated accretionary complex in Japan. The purpose of this study is to describe and interpret a conglomerate from the Nedamo Terrane that contains clasts of high-pressure/low-temperature (high- P/T ) schist (mainly garnet-bearing phengite schist) and ultramafic rock, and to infer the tectonics of an Early Carboniferous arc–trench system at the eastern margin of the paleo-Asian continent. Clasts of high- P/T schist and ultramafic rock within the conglomerate make up 8.4 and 6.7% of the total clasts, respectively, based on modal counts. These clasts are subangular to subrounded, whereas volcanic clasts are well rounded. The source of the schist clasts, which yield a radiometric age of 347–317 Ma, is considered to be the Renge Metamorphic Rocks of Southwest Japan or equivalent rocks. Based on the chemical composition of chromian spinel, the source of ultramafic clasts is inferred to be the island-arc-type Ordovician Miyamori and Hayachine ultramafic complexes in the Kitakami Massif. The conglomerate records multiple provenance regions, including an island arc (South Kitakami Terrane) and a forearc ridge; the high P/T schist and ultramafic rocks were exhumed in the forearc region. The duration of the interval from the early stages of exhumation of the schist to its deposition in the trench as clasts is estimated to have been less than 30 my.     

Petrogenetic processes in the ultramafic, alkaline and carbonatitic magmatism in the Kola Alkaline Province: A review

Igneous rocks of the Devonian Kola Alkaline Carbonatite Province (KACP) in NW Russia and eastern Finland can be classified into four groups: (a) primitive mantle-derived silica-undersaturated silicate magmas; (b) evolved alkaline and nepheline syenites; (c) cumulate rocks; (d) carbonatites and phoscorites, some of which may also be cumulates. There is no obvious age difference between these various groups, so all of the magma-types were formed at the same time in a relatively restricted area and must therefore be petrogenetically related. Both sodic and potassic varieties of primitive silicate magmas are present. On major element variation diagrams, the cumulate rocks plot as simple mixtures of their constituent minerals (olivine, clinopyroxene, calcite, etc). There are complete compositional trends between carbonatites, phoscorites and silicate cumulates, which suggests that many carbonatites and phoscorites are also cumulates. CaO / Al₂O₃ ratios for ultramafic and mafic silicate rocks in dykes and pipes range up to 5, indicating a very small degree of melting of a carbonated mantle at depth. Damkjernites appear to be transitional to carbonatites. Trace element modelling indicates that all the mafic silicate magmas are related to small degrees of melting of a metasomatised garnet peridotite source. Similarities of the REE patterns and initial Sr and Nd isotope compositions for ultramafic alkaline silicate rocks and carbonatites indicate that there is a strong relationship between the two magma-types. There is also a strong petrogenetic link between carbonatites, kimberlites and alkaline ultramafic lamprophyres. Fractional crystallisation of olivine, diopside, melilite and nepheline gave rise to the evolved nepheline syenites, and formed the ultramafic cumulates. All magmas in the KACP appear to have originated in a single event, possibly triggered by the arrival of hot material (mantle plume?) beneath the Archaean/Proterozoic lithosphere of the northern Baltic Shield that had been recently metasomatised. Melting of the carbonated garnet peridotite mantle formed a spectrum of magmas including carbonatite, damkjernite, melilitite, melanephelinite and ultramafic lamprophyre. Pockets of phlogopite metasomatised lithospheric mantle also melted to form potassic magmas including kimberlite. Depth of melting, degree of melting and presence of metasomatic phases are probably the major factors controlling the precise composition of the primary melts formed.     

云南金宝山含铂钯超镁铁质侵入体中铬铁矿的成因研究

位于扬子地台西缘的金宝山岩体赋存我国最大的独立铂族元素矿床，岩体为似层状产出的小型超镁铁岩，在时间和空间上与晚二叠纪（260Ma）峨眉山大火成岩省相关。该岩体由单辉橄榄岩、辉橄岩及橄辉岩、辉石岩异离体组成。铬铁矿以副矿物形式出现，从形态上可以分为三类：包嵌于橄榄石中的自形铬铁矿、以自形或半自形体存在于辉石中铬铁矿以及环绕结构铬铁矿。其中环绕结构铬铁矿外壁浑圆，内为棱角状，其中心为橄榄石、辉石。本文在薄片观察的基础上，结合电子探针研究，认为包嵌于橄榄石中的自形铬铁矿是在岩浆早期深部岩浆房中结晶形成的；存在于辉石中的铬铁矿则是岩浆进一步结晶演化的结果，主要为就地结晶的产物；在岩体形成的过程中，作为岩体赋存空间的堆晶相与后续岩浆持续反应，使铬铁矿不断聚集和生长，最终形成了环绕橄榄石晶体的形态。铬铁矿的生成模式进一步说明了金宝山侵入体为一岩浆通道，并且经历深部结晶分异演化。     

Petrology of marble and peridotite in the Seiad ultramafic complex, northern California, USA

Abstract Peridotite and infolded marble of the Seiad ultramafic complex were recrystallized in the upper amphibolite facies as part of the regional progressive metamorphism of the Rattlesnake Creek terrane. Field relations, including the occurrence of metarodingites, and metasomatic zones between dissimilar rock types, demonstrate that the metasediments and serpentinized ultramafic rocks were juxtaposed prior to regional, barrovian metamorphism. Temperatures are estimated to have reached 760–800°C at pressures of 7–8 kbar during the peak of metamorphism. Four low-variance parageneses have been identified within a small (3 km²) area of the complex, which may reasonably be assumed to have formed under the same P and T conditions. Isobaric T-X co₂ diagrams of appropriate equilibria are presented for three different internally consistent sets of thermodynamic data. Despite the seemingly small numerical differences between the standard state thermodynamic properties of the data sets, only one diagram allows the four observed assemblages to coexist within a reasonable temperature range. All three phase diagrams require differences in fluid composition on the scale of a thin section; strong evidence for effective control of pore fluid composition by local mineral reactions during metamorphism.     

Backarc mafic–ultramafic magmatism in Northeastern Vietnam and its regional tectonic significance

The geology of Northern Vietnam offers critical clues on the convergence history between the South China and Indochina blocks. We constrain the tectonic evolution of the South China and Indochina blocks using geochemical, mineral chemical and geochronological data collected from mafic–ultramafic rocks exposed in the Cao Bang area, Northeastern Vietnam. These rocks show significant enrichment in large ionic lithophile elements (LILEs) such as Cs, Rb, Ba, Th, U, and Pb and depletion in high field strength elements (HFSEs) such as Nb, Ta, Zr, and Ti showing [Nb/La]_N between 0.28–0.41, [La/Yb]_N = 3.94–10.00 and Zr/Y = 2.0–4.4. These geochemical features as well as the petrology and mineral chemistry of the Cao Bang mafic–ultramafic magmas are comparable to those of magmatic complexes formed in a back-arc environment. The basalts yield Rb–Sr whole rock ages of 263 ± 15 Ma, that are consistent with the zircon U–Pb and K–Ar ages reported in previous studies from the same area. The spatial and temporal distribution of the arc magmas within the Indochina block and along the southern margin of the South China block suggest that the Permo-Triassic mafic–ultramafic magmas formed during a tectonic event that is different from the subduction and collision event between the Indochina and South China blocks.     

Origin of the early Permian Wajilitag igneous complex and associated Fe–Ti oxide mineralization in the Tarim large igneous province,NW China

The Wajilitag igneous complex is part of the early Permian Tarim large igneous province in NW China, and is composed of a layered mafic–ultramafic intrusion and associated syenitic plutons. In order to better constrain its origin, and the conditions of associated Fe–Ti oxide mineralization, we carried out an integrated study of mineralogical, geochemical and Sr–Nd–Hf isotopic analyses on selected samples. The Wajilitag igneous rocks have an OIB-like compositional affinity, similar to the coeval mafic dykes in the Bachu region. The layered intrusion consists of olivine clinopyroxenite, coarse-grained clinopyroxenite, fine-grained clinopyroxenite and gabbro from the base upwards. Fe–Ti oxide ores are mainly hosted in fine-grained clinopyroxenite. Forsterite contents in olivines from the olivine clinopyroxenite range from 71 to 76 mol%, indicating crystallization from an evolved magma. Reconstructed composition of the parental magma of the layered intrusion is Fe–Ti-rich, similar to that of the Bachu mafic dykes. Syenite and quartz syenite plutons have ε_Nd(t) values ranging from +1.4 to +2.9, identical to that for the layered intrusion. They may have formed by differentiation of underplated magmas at depth and subsequent fractional crystallization. Magnetites enclosed in olivines and clinopyroxenes have Cr₂O₃ contents higher than those interstitial to silicates in the layered intrusion. This suggests that the Cr-rich magnetite is an early crystallized phase, whereas interstitial magnetite may have accumulated from evolved Fe–Ti-rich melts that percolated through a crystal mush. Low V content in Cr-poor magnetite (<6600 ppm) is consistent with an estimate of oxygen fugacity of FMQ + 1.1 to FMQ + 3.5. We propose that accumulation of Fe–Ti oxides during the late stage of magmatic differentiation may have followed crystallization of Fe–Ti-melt under high fO₂ and a volatile-rich condition.