硬质合金复合片齿钎具

运用力学原理研制成功了复合片齿钎头和复合片齿整钎，并批量投入市场。该系列钎具凿岩速度、寿命和硬质合金片齿有效利用率均显著优于片状和球齿钎具。     

广东莲花山斑岩型钨-金矿床蚀变矿化特征及分带模式

莲花山斑岩型钨－金矿床蚀变类型可以分作钾化、云英岩化、绢云母化、绿泥石化和青盘岩化。矿化表现为黑钨矿化、白钨矿－硫化物矿化、多金属硫化物矿化及黄铁矿化。蚀变在水平和垂向上具有分带性。由内向外由钾化向云英岩化、叠加蚀变带、绿泥石化＋绢云母化、青盘岩化转化。由浅向深，钾化增强，云英岩化减弱，被叠加蚀变带和绿泥石化及绢云母化所代替。矿化由内向外表现为由黑钨矿化向白钨矿化、多金属硫化物矿化、黄铁矿化转变，由浅向深由钨矿化转变为金矿化及多金属硫化物矿化。与典型斑岩型矿床蚀变分带对比，莲花山斑岩型矿床不同原岩类型蚀变特征变化较大，矿化则表现出富钨、金贫铜及钨金共同产出的特征。     

磷对金刚石增强型硬质合金复合齿性能的影响

在金刚石增强型硬质合金复合齿基体中添加不同量红磷，可降低复合齿烧结温度，实现低温活化烧结。研究表明：添加0．3％(ωB)P的复合齿基体性能最好，采用化学镀Ni-P合金添加P和球磨添加0．1％P的方式，复合齿超硬部分的磨耗比和复合齿的抗冲击功优于单纯通过球磨添加0．3％P的超硬复合齿。为了实现金刚石增强型硬质合金复合齿的低温活化烧结，磷元素最优的添加方式是化学镀结合球磨的添加方式。     

桩基筒形翼状钻头的改进设计及应用

针对浙江省温州市世贸中心大厦桩基施工中硬岩钻进时出现的堵管、卡钻和效率低等问题,从所钻地层和钻头的磨损分析出发,提出了钻头的改进设计方案.改进型筒形翼状钻头比原先使用的平底滚刀钻头增加了18个孕镶金刚石-针状硬质合金复合式钻齿和3个钎头,并按受力特点进行了合理分布.实际钻进效果表明改进型钻头应用于超深、大直径钻孔的钻进效率较高、钻进过程平稳.针对钻头的实际磨损情况提出了钻头进一步改进设计的建议.     

南岭钨矿床研究进展

南岭钨矿床研究一直是重要的前沿课题,近十余年来测试方法和技术的革新为南岭钨矿床研究注入了新活力,也取得了众多新进展.本文在系统查阅前人研究基础上对其进行总结,概括如下:①该区的岩浆-钨成矿活动不仅有燕山期,也有加里东期和印支期,但以燕山期最为强烈;②花岗岩浆是南岭钨矿床主要的直接物质来源,即使有少部分成矿物质是热液直接对含矿地层淋滤、萃取而来,但却被认为是次要的;③与花岗岩有关钨矿床的成矿流体主要来自花岗岩浆,在成矿作用晚期有不同程度的大气降水混入;④与钨有关的花岗岩主要由下地壳的早—中元古代岩石重熔形成,但地幔岩浆一定程度上参与了花岗岩的形成作用;⑤碱质交代在花岗岩浆演化形成钨矿床的过程中发挥了关键性作用;⑥不同学者对燕山期钨成矿作用动力学背景尚有不同看法,但该时期确定为板内伸展和裂谷环境已达成共识.     

国际油气井钻头进展概述（二）——FuseTek融合钻头与Pexus组合钻头

NOV公司2013年向市场推出FuseTek融合钻头。它将PDC钻头的高钻速与孕镶金刚石钻头的耐磨性结合于一体,适宜于钻进中硬—坚硬、高研磨性地层。FuseTek钻头已广泛应用于刚果、厄瓜多尔、中国、哥伦比亚等国家。应用表明,该新型组合钻头比PDC钻头或牙轮钻头钻进效率提高许多,工作寿命增加1～3倍或更多。Shear Bits公司于2014年推出Pexus组合钻头。该钻头广泛应用于加拿大冰川冰碛物钻进。地层上部硬卵砾石层利用可转动硬质合金齿钻进,下部软砂岩与页岩则运用PDC碎岩。整个冰碛物地层用一个Pexus钻头一钻到底。所述3类组合式钻头（含Kymera钻头）对于未来实现“一个钻头,一口井”的目标有重要意义。     

Metallogenic Mechanism and Tectonic Setting of Tungsten Mineralization in the Yangbishan Deposit in Northeastern China

The Yangbishan iron–tungsten deposit in the Shuangyashan area of Heilongjiang Province is located in the center of the Jiamusi Massif in northeastern China. The rare earth element and trace element compositions of the scheelite show that it formed in a reducing environment and inherited the rare earth element features of the ore-forming fluid. The geochemical characteristics of the gneissic granite associated with the tungsten mineralization show that the magma formed in this reducing environment and originated from the partial melting of metamorphosed shale that contained organic carbon and was enriched with tungsten. In addition, in situ Hf isotopic analysis of zircons from the gneissic granite indicates that they probably originated from the partial melting of a predominantly Paleo–Mesoproterozoic crustal source. According to LA-ICP-MS zircon dating, the Yangbishan orerelated gneissic granite has an Early Paleozoic crystallization age of 520.6 ± 2.8 Ma. This study, together with previous data, indicates that the massifs of northeastern China, including Erguna, Xing'an, Songliao, Jiamusi, and Khanka massifs, belonged to an orogenic belt that existed along the southern margin of the Siberian Craton during the late Pan-African period. The significant continental movements of this orogeny resulted in widespread magmatic activity in northeastern China from 530 Ma to 470 Ma under a tectonic setting that transitioned from compressional syn-collision to extensional postcollision.     

Zircon U–Pb and Wolframite Sm–Nd Dating of the Bayinsukhtu Tungsten Deposit in Southern Mongolia and its Geological Significance

The Bayinsukhtu tungsten deposit is a newly discovered quartz‐vein tungsten deposit in the Xing'an–Mongolia Orogenic Belt (XMOB) in southern Mongolia, hosted by the Bayinsukhtu granite porphyry. The granite porphyry is located mainly south of the study area, over 3 km². The rock consists of quartz and feldspar phenocrysts in a fine‐grained matrix, also mainly composed of feldspar and quartz. The granite porphyry samples demonstrate high SiO₂ and high alkalinity. All samples also straddle the high‐potassium calc‐alkaline series. In a plot of the molar ratios of A/NK versus A/CNK, the granites are metaluminous. The chondrite‐normalized REE patterns are characterized by large negative Eu anomalies and fractionated LREEs. The U–Pb age of zircons from the granite porphyry is 298.8 ± 1.8 Ma, and the Sm–Nd age of the five wolframite samples from the tungsten deposit is 303 ± 19 Ma. The cooling age of the granite porphyry and tungsten mineralization is within the error of measurement and is of the Late Carboniferous age. Geological and geochronological evidence shows that the tungsten mineralization and the granite porphyry at Bayinsukhtu are genetically closely related and that they are results of Carboniferous magmatism. Their tectonic setting is related to the accretion of the Central Asian Orogenic Belt during the late Paleozoic era.     

赣南淘锡坑石英脉型钨矿床成矿机制探讨:来自流体包裹体的证据

赣南地区淘锡坑钨矿床是典型的大型石英脉型钨锡多金属矿床。矿体赋存于震旦系浅变质砂(板)岩,并延伸至深部花岗岩内,按空间产出位置分为内带矿体和外带矿体,包括宝山、西山、烂埂子、枫岭坑4大脉组,矿体产出各不相同,矿物组合也具有明显分带特征。在详细的岩相学研究基础上,文章选择淘锡坑主成矿期石英为研究对象,并与共生黑钨矿作对比,从空间角度开展不同脉组、不同矿体或中段的流体包裹体的对比研究。根据流体包裹体岩相学,石英包裹体类型有H_2O-NaCl型包裹体(Ⅰ型)、H_2O-NaCl-CO_2型包裹体(Ⅱ型)和纯CO_2体系裹体(Ⅲ型)及少量含石盐子晶的多相包裹体,并同时捕获贫CO_2的盐水溶液包裹体和纯CO-2气相包裹体。包裹体显微测温结果显示:内、外带石英脉气液两相的包裹体均具有较宽温度和盐度范围,外带均一温度和盐度w(NaCl_(eq))分别集中于200～220℃、1%～6%,内带均一温度和盐度w(NaCleq)分别集中于100～220℃、3%～7%,流体为中-低盐度、富含CO_2的H_2O-CO_2-NaCl体系,不同脉组不同矿脉之间对比结果均显示出多期成矿的特征。在矿脉形成过程中,流体的成分和温度在内外接触带有明显变化,表明岩体与围岩接触界面是造成淘锡坑矿床内带矿体和外带矿体的成矿条件改变的转折位置,成矿流体在此附近发生CO_2逸失引起相分离的不混溶作用是成矿的主要因素。     

赣南狮吼山硫铁-钨多金属矿床H-O-S同位素组成特征

狮吼山硫铁-钨多金属矿床位于银坑-青塘整装勘查区北部,是赣南地区唯一大型硫铁矿床。磁黄铁矿-黄铁矿(-黄铜矿-白钨矿)矿体赋存于石炭系梓山组上段地层中含铁、含钙层位,主要形成于石英-硫化物阶段。本文通过分析原生矿石矿物中H-O-S同位素组成特征,结合Pb同位素和成矿年代测试结果,探讨成矿流体来源及成矿演化过程。矿石硫化物中δ~(34)S组成特征(-5. 50‰～-0. 20‰,集中于-3. 0‰～0. 0‰)显示,硫源以岩浆硫为主,较宽的变化范围预示成矿流体遭受了叠加和改造作用。δD-δ~(18)O同位素组成主要集中于岩浆水与变质水重叠区域(δD=-74. 4‰～-48. 0‰,δ~(18)O_(H_2O)=3. 76‰～10. 86‰),说明成矿流体以岩浆水和变质水为主,后期有少量的天水混入。综合分析认为,该矿床成矿流体主要来自深部岩浆水,岩浆热液与含钙地层的接触交代作用形成大规模变质流体,再加上少量的天水混入,流体间的不混溶作用使成矿物质在岩体与含钙层位接触部位富集沉淀,形成热液充填交代型矿床。