低品位磷矿的生物选矿、化工冶金一体化研究

利用生物冶金的方法,将不溶性磷源转化为水溶性或枸溶性磷源,从而提供了一条利用低品位磷矿的新途径.讨论了生物和微生物在磷化工中的研究与应用,介绍了用自制菌磷肥在田间试验所取得的结果,提出了利用生物工程的方法处理低品位磷矿而直接生产磷肥的技术路线.     

Assessing the geochemical reactivity of inorganic phosphorus along estuaries by means of laboratory simulation experiments

Phosphate behaviour in natural estuarine systems can be studied by performing field measurements and by undertaking laboratory simulation experiments. Thus, in this paper we describe the use of a dynamic automated estuarine simulator to characterize the geochemical reactivity of phosphate in varying salinity gradients in order to study possible mechanisms of phosphate removal from the dissolved phase (e.g. formation of some kind of apatite) and how changes in pH and salinity values influence this removal. Six laboratory assays, representing various salinity and pH gradients (average pH values between 7 and 8), were carried out. The geochemical equilibrium model MINTEQA2 was employed to characterize removal of phosphate. Among the minerals from which dissolved phosphate can originate, it seems that hydroxyapatite is by far the mineral that shows the greatest saturation indexes in the experiments. Thus, there is evidence that a type of calcium phosphate (hydroxyapatite) is involved in phosphate removal in the assays. Phosphate removal by Ca²⁺ occurs sharply at salinity values of 1–2, whereas by Fe³⁺ it is relatively gradual, at least until a salinity value of 7. Copyright © 2006 John Wiley & Sons, Ltd.     

磷酸铈共沉淀原子吸收光谱法测定硫酸钴中的痕量铁

探讨了用CePO4共沉淀火焰原子吸收光谱法测定CoSO4溶液中的痕量Fe3 。共沉淀效率受pH、Ce(NO3)3和H3PO4用量的影响。试验结果表明,在溶液pH为3.0～4.0时,CePO4能够定量共沉淀CoSO4溶液中的Fe3 。对于20mL的样品溶液,方法的检出限为24.8μg/L,铁的加标回收率为101.7%。方法用于CoSO4试剂中Fe3 的测定,6份样品测定的RSD<5%。     

Response of microbial community to petroleum stress and phosphate dosage in sediments of Jiaozhou Bay,China

The dynamic microcosms were used to evaluate the effect of oil spills on microbial ecological system in marine sediment and the enhancement of nutrient on the oil removal. The function and structure of microbial community caused by the oil pollution and phosphate dosage were simultaneously monitored by dehydrogenase activity assay and PCR-denaturing gradient gel electrophoresis (DGGE) techniques. The results indicated that the amount of total bacteria in all dynamic microcosms declined rapidly with incubation time. The number of petroleum-degrading bacteria and the activity of sediment dehydrogenase were gradually enhanced by petroleum in the oil-treated microcosms, while they both showed no obvious response to phosphate dosage. In comparison, phosphate spiked heterotrophic bacteria and they showed a significant increase in amount. DGGE profiles indicated that petroleum dosage greatly changed community structure, and the bacteria belonged to class Deltaproteobacteria, and phyla Bacteroidetes and Chlorobi were enriched. This study demonstrated that petroleum input greatly impacted the microbial community structure and consequently the marine sediment petroleum-degrading activity was enhanced. Phosphate dosage would multiply heterotrophic bacteria but not significantly enhance the petroleum degradation.     

二苯碳酰二肼光度法测定超基性岩石中三氧化二铬的改进

二苯碳酰二肼光度法是测定微量Cr(Ⅵ)的行业标准方法,以硫酸作为显色介质,酸度要求严格,显色稳定时间短,体系显色后需在10 min～1 h测定完毕,灵敏度较差。本文对标准方法进行改进,将显色介质由硫酸改为磷酸。结果表明,在H3PO4介质中显色剂与Cr(Ⅵ)反应生成的络合物可稳定3 h,方法相对标准偏差(RSD)≤5.25%,加标回收率为99.2%～102.0%,检出限由标准方法的13.6μg/g降至3.8μg/g。建立的方法用于超基性岩标准物质分析,相比于标准方法,稳定性、精密度和准确性均有提高。     

Enhancement of edges of Sidi Chennane phosphate “disturbances” using sunshading responses of resistivity data

Sunshading is a powerful tool for the enhancement of edges in images. Given the azimuth and elevation of a source illumination, it calculates the reflectance from a surface which is composed of the data to be interpreted. It is a standard tool used in the interpretation of geophysical potential field data. In the great Oulad Abdoun phosphate basin, inclusions of sterile hardpan — so-called “disturbances” — are hard to detect as they interfere with phosphates. Their resistivity is above 200 Ohmm against 80 to 150 Ohmm for a phosphate-rich mineral. A Schlumberger resistivity survey over an area of 50 hectares was carried out. The geologic setting was successfully modeled on the basis of sunshaded maps of disturbances. A new field procedure was tested to deal with the extended edges of anomalous zones of phosphate deposit disturbances. Phosphate reserves were estimated more reliably.     

New Extraction System for Lithium from Brine with High Magnesium Content

正Lithium is an important element with a wide variety of applications,especially in lithium ion batteries and in the exploration of nuclear energy.Salt lake brine is the most abundant lithium source available in world,comp-rising70%~80%of all known lithium deposits.Lithium can be abstracted from brines with low magnesium content and processed into kinds of lithium compound in Atacama and Hombre Muerto of South America(Nie et al.,2013).     

湖北省磷矿资源的空间富集规律及其产业布局

湖北省的磷矿资源储量居全国之首,矿床类型以元古宙海相沉积型磷块岩矿床为主,分布集中在五大区域,开发利用条件较好。虽然湖北的磷矿资源勘查近年取得了突破性的进展,但由于资源利用合理度欠缺、磷化工企业规模小、产业链不完善及产业集中度低等原因,对磷矿开发和磷化工产业的可持续发展构成了制约。磷矿资源的合理开发利用对建设磷矿开发及磷化工产业集群、保障国家粮食安全具有重要意义。因此,在勘查部署上,要根据成矿条件、空间富集规律和勘查开发现状,统一部署,分类开展工作;在产业布局上,以宜昌、保康、荆襄、黄麦岭4大磷化工基地为主体,新建鹤峰、黄梅磷肥基地,打造"一圈多点"式产业集群;在产业关联上,新建磷矿产地与现有磷化工基地之间形成以老带新、以新助老、空间互动的产业格局;在产品分工上,支持现有磷化工基地内的骨干企业兼并重组,提高产业集中度。     

Environmental and land use factors affecting phosphate hysteresis patterns of stream water during flood events (Carpathian Foothills,Poland)

Flood events play a substantial role in the circulation of catchment phosphate (PO₄^3?). The purpose of the research was to analyze the factors determining PO₄^3? hysteresis patterns (direction and width) during four types of floods: short and long rainfall floods and snowmelt floods on frozen and thawed soil. The research took place in small catchments (forested, agricultural, mixed‐use) in the Carpathian Foothills in Poland. Anticlockwise hysteresis was identified in the forested catchment during short and long rainfall floods. Under the same conditions, the clockwise direction was observed in the agricultural catchment. In the mixed‐use catchment, the direction of PO₄^3? hysteresis loops was various, driven by the share of water flowing from each part of the catchment. For snowmelt floods, the PO₄^3? hysteresis pattern was similar in all the streams studied (usually clockwise). The direction of PO₄^3? hysteresis loops depends on water circulation patterns, which are determined by the different influx times of particular runoff components. The stream recharge mechanism during a flood event is affected both by the factor initiating the event (precipitation, snowmelt) as well as by land use in the given catchment. Hysteresis loop width was determined by the pool of PO₄^3? in a given catchment during the time period immediately preceding a flood event as well as by the quantity of PO₄^3? flushed out of the soil. The greater a catchment's pool of PO₄^3? and the greater its ability to flush PO₄^3? out of the soil and into surface flow, the wider the hysteresis loops. Copyright © 2012 John Wiley & Sons, Ltd.     

湖北樟村坪磷矿矿床三维地质建模及资源量估算

对湖北宜昌磷矿黑良山矿区进行矿床三维模型建立及储量估算。黑良山普查区是全国主要成磷区之一,经过几十年的开采建设,矿山已成为危机矿山。在对该地区成矿背景研究及资源勘探的前提下,收集了钻孔、剖面等数据,利用“探矿者”软件以及三维可视化和三维建模技术,建立了樟村坪磷矿的三维矿床模型并对矿体进行储量估算。