Crystal Structure and Geometry-Optimization Study of N-(2-hydroxy-1-naphthaldene)-4-aminoantipyrme

N-(2-hydroxy-1-naphthaldene)-4-aminoantipyrine has been synthesized. The structure is determined by X-ray diffraction method and elemental analysis. The crystal system belongs to orthorhombic space group P(2)2(1)2(1). The geometry has been ob-tained from the density functional theory (DFT) method and the B3LYP method employing the 6-31G* basis sets. The calculated results propose that the latter is close to the experimental data. The structural parameters from the theory are close to those of the crystal and the calculated total energy of coordination is -31677.172 eV. The energy of HOMO and LUMO and the energy gap are 5.179 eV, -1.603 eV and 3.577 eV, respectively.     

黑河上游山地土壤容重分布特征及影响因素

土壤容重不仅可用作计算土壤持水力和导水性,也是估算土壤养分和碳储量的重要变量。野外测定土壤容重一般费时费力,特别是在地形复杂的山区,因此山地土壤容重在国内外大多数清查数据库中缺失。本文以黑河上游山地为例,基于野外调查的124个土壤剖面,研究了山地土壤容重的空间分布特征及影响因素。结果表明:黑河上游山地0~10 cm和0~60 cm土壤容重分别为0.91±0.02 g·cm^-3 和1.04±0.01 g·cm^-3;不同植被类型下,高山寒漠容重最大,山地森林最小。随着土壤深度的增加,容重呈幂函数递增;随着土壤有机质含量的增加,容重呈指数递减。区域上,黑河上游从西北到东南,容重呈递减趋势,从高海拔到低海拔,容重呈先减小后增大趋势。主成分分析(PCA)和一般线性模型(GLM)表明,与土壤容重相关的环境因子中,海拔是影响土壤表层容重的第一主成分,土壤有机质含量是第二主成分,黏粒含量和大于2.0 mm砾石含量分别为第三、四主成分。第一、二、三、四主成分分别解释土壤容重空间变异的24.00%、29.40%、0.01%、6.20%。     

Entrepreneurial causation and effectuation logics in a regional context: Assessing the importance of population density

ABSTRACT

The purpose of the article is to assess whether an entrepreneurial causation or effectuation logic is a function of geographical location in densely populated economic regions versus sparsely populated economic regions. A causation logic implies that the entrepreneur primarily focuses on a predefined goal and further aims to identify the means to reach that goal. By contrast, an effectuation logic implies that the entrepreneur to a larger extent focuses on the means at hand, which she or he aims at materialising into one or more goals that are not necessarily predefined. The empirical data for the study are based on an investigation and evaluation of Norwegian entrepreneurs in business incubation that are located in many different economic regions of the country. Multilevel regression analyses showed that geographical location in sparsely populated economic regions is associated with a causation logic, whereas a location in densely populated economic regions is associated with an effectuation logic. An implication of the article is that entrepreneurial stakeholders, such as policymakers, incubator managers, public and private partners, and entrepreneurs themselves should be aware of differences in causation and effectuation logics between entrepreneurs located in densely versus sparsely populated economic regions.     

Analyzing Population Density Disparity in China with GIS-automated Regionalization: The Hu Line Revisited

The famous ’Hu Line’, proposed by Hu Huanyong in 1935, divided China into two regions(southeast and northwest) of comparable area size but drastically different in population. However, the classic Hu Line was derived manually in absence of reliable census data and computational technologies of modern days. It has been subject to criticism of lack of scientific rigor and accuracy. This research uses a GIS-automated regionalization method, termed REDCAP(Regionalization with Dynamically Constrained Agglomerative Clustering and Partitioning), to reconstruct the demarcation line based on the 2010 county-level census data in China. The results show that the logarithmic transformation of population density is a better measure of attributive homogeneity in derived regions than density itself, and produces two regions of nearly identical area size and greater contrast in population. Specifically, the revised Hu Line by Hu Huanyong in 1990 had the southeast region with 94.4% of total population and 42.9% of total land, and our delineation line yields a southeast region with 97.4% population and 50.8% land. Therefore, the population density ratio of the two regions is 27.1 by our line, much higher than the ratio of 22.4 by the Hu Line, and thus outperforms the Hu Line in deriving regions of maximum density contrast with comparable area size. Furthermore, more regions are delineated to further advance our understanding of population distribution disparity in China.     

培育密度和投饵量对长牡蛎壳黑选育品系幼虫生长存活及附着变态的影响

为探究长牡蛎(Crassostrea gigas)壳黑选育品系规模化繁育适宜的培育密度和投饵量,本研究以长牡蛎野生群体幼虫为对照组,分析了不同培育密度(3、7和15个/mL)和不同初始投饵量(0.4、0.8和1.6×10~3cells·ind^-1·d^-1)对长牡蛎壳黑选育品系幼虫生长、存活及附着的影响。研究显示,培育密度和投饵量对长牡蛎幼虫的生长速率、存活率和附着率有显著交互作用(P<0.05)。在培育密度3和7个/mL实验组,长牡蛎幼虫生长速率随投饵量增加而显著增大(P<0.05),并在培育密度7个/mL、投饵量1.6×10~3cells·ind^-1·d^-1实验组达到最大值。而在培育密度15个/mL实验组,投饵量增加对长牡蛎幼虫的生长速率无显著影响(P> 0.05)。且在培育密度15个/mL、投饵量1.6×10~3cells·ind^-1·d^-1实验组长牡蛎壳黑品系幼虫存活率和附着率最低。但在培育密度15个/mL实验组长牡蛎壳黑选育品系幼虫的壳高始终高于野生群体幼虫。且除投饵量0.4×10~3cells·ind^-1·d^-1实验组外,长牡蛎壳黑选育品系幼虫生长速率、存活率和附着率均高于野生群体幼虫。研究结果表明,长牡蛎壳黑选育品系幼虫最适培育条件为培育密度7个/mL、投饵量1.6×10~3cells·ind^-1·d^-1,增加投饵量可促进长牡蛎幼虫生长,但过高的培育密度会与投饵量产生拮抗作用,抑制幼虫生长,不利于幼虫存活和附着。与长牡蛎野生群体相比,壳黑选育品系幼虫能适应更高的培育密度环境,在饵料充足的条件下,其幼虫的生长、存活及附着性状均优于野生群体。     

Effects of stocking density on the growth and immunity of Atlantic salmon salmo salar reared in recirculating aquaculture system(RAS)

Atlantic salmon reared in recirculating aquaculture system(RAS) may lead to inappropriately high stocking density, because ?sh live in a limited space. Finding the suitable stocking density of Atlantic salmon reared in RAS is very important for RAS industry. In this paper, the in?uence of stocking density on growth and some stress related physiological factors were investigated to evaluate the ef fects of stocking density. The ?sh were reared for 220 days at ?ve densities(A: 24 kg/m^3; B: 21 kg/m^3; C: 15 kg/m^3; D: 9 kg/m^3 and E: 6 kg/m^3). The results show that 30 kg/m^3 might be the maximum density which RAS can af ford in China. The stocking densities under 30 kg/m^3 have no ef fect on mortality of Atlantic salmon reared in RAS. However, the speci?c growth rate(SGR), ?nal weight and weight gain in the high density group were signi?cantly lower than the lower density groups and middle density groups. Moreover, feed conversion rate(FCR) had a negative correlation with density. Plasma hormone T_3 and GH showed signi?cant decrease with the increase of the stocking density of the experiment. Furthermore, thyroid hormone(T 3), GH(growth hormone) activities were decreased with stocking density increase. However, plasma cortisol, GOT(glutamic oxalacetic transaminase) and GPT(glutamic pyruvic transaminase) activities were increase with stocking density increase. And the stocking density has no ef fects on plasma lysozyme of Atlantic salmon reared in RAS. These investigations would also help devise effcient ways to rear adult Atlantic salmon in China and may, in a way, help spread salmon mariculture in China.     

面向双/多变量的连续面域拓扑图可视化方法

面域拓扑图是一种利用区域面积大小定量表达区域属性信息的可视化方法。由于其区域面积本身已经表示某一变量,因此这更有利于双/多变量的制图表达。针对目前基于面域拓扑图的双/多变量表达方法中存在的难以表达相邻区域之间基本状况和不利于不同地理现象的空间分布规律及差异表达的问题,本文提出一种面向双/多变量的连续面域拓扑图可视化方法。首先通过格网密度补偿和积分步长逐步试探的方法对基于扩散模型的连续面域拓扑图生成算法进行部分优化,完成基本变量的表达,然后分别通过空间内插和符号扩展完成第2和第3变量在连续面域拓扑图中的表达。最后以慕尼黑市人口密度和银行/ATM分布(双变量)数据以及奥格斯堡市人口密度数据、幼儿园分布以及规模数据(多变量)为试验数据进行可视化,并通过实证分析验证了该方法的有效性和优越性。     

Estimation of crowd density from UAVs images based on corner detection procedures and clustering analysis

With rapid developments in platforms and sensors technology in terms of digital cameras and video recordings, crowd monitoring has taken a considerable attentions in many disciplines such as psychology, sociology, engineering, and computer vision. This is due to the fact that, monitoring of the crowd is necessary to enhance safety and controllable movements to minimize the risk particularly in highly crowded incidents (e.g. sports). One of the platforms that have been extensively employed in crowd monitoring is unmanned aerial vehicles (UAVs), because UAVs have the capability to acquiring fast, low costs, high-resolution and real-time images over crowd areas. In addition, geo-referenced images can also be provided through integration of on-board positioning sensors (e.g. GPS/IMU) with vision sensors (digital cameras and laser scanner). In this paper, a new testing procedure based on feature from accelerated segment test (FAST) algorithms is introduced to detect the crowd features from UAV images taken from different camera orientations and positions. The proposed test started with converting a circle of 16 pixels surrounding the center pixel into a vector and sorting it in ascending/descending order. A single pixel which takes the ranking number 9 (for FAST-9) or 12 (for FAST-12) was then compared with the center pixel. Accuracy assessment in terms of completeness and correctness was used to assess the performance of the new testing procedure before and after filtering the crowd features. The results show that the proposed algorithms are able to extract crowd features from different UAV images. Overall, the values of Completeness range from 55 to 70 % whereas the range of correctness values was 91 to 94 %.     

A geospatial study of the drought impact on surface water reservoirs: study cases from Texas,USA

Satellite images have been used historically to measure and monitor fluctuations in the surface water reservoirs. This study integrates remote sensing and Geographic Information System (GIS) technologies to investigate the impact of drought on 10 selected surface water reservoirs in San Angelo and Dallas, Texas. Oscillations in summer and winter months throughout the 2005–2016 period were assessed using multispectral images from Landsat-5, ?7, and ?8, and changes in the reservoirs were characterized and correlated against local climate data of each reservoir. For quantitative comparisons of the time-series measurements, a robust density slicing approach was employed to classify the range of values of the raster cells in the near-infrared band of Landsat images for each lake into three desired classes (deep water, shallow water, and dry area) based on the natural breaks inherent in the dataset. Statistical analysis shows that the overall accuracy of the classification is about 94%, which demonstrates the efficiency of the density slicer to accurately estimate surface water area changes from an individual Landsat band. Shrinkage in the surface water area over the study period reveals the concrete impact that the drought along with other factors have on the 10 selected lakes. The San Angelo lakes located in west central Texas experienced a nearly consistent pattern of change during most of the study period; whereas the Dallas lakes in northeast Texas followed the oscillating pattern of drought and correlated closely to the local conditions. Shockingly, the extreme drought caused complete vanishing of several lakes, and consequently Texas had to remove them from its recreational plans. Our new findings can certainly help with the water resource management in Texas and our study approach can be adapted for monitoring lake oscillations in other areas across the world. This geospatial study demonstrates the societal benefits from incorporating remote sensing and GIS in investigating geo-environmental problems associated with severe climate changes.     

机载LiDAR点云获取与高精度DEM建设关键技术探讨

结合广东省机载LiDAR点云获取与高精度DEM建设项目,介绍了项目总体技术路线,针对项目难点,从设备选择、点云密度设计、植被覆盖密集山区数据获取方法、点云数据分类组合算法、空白区处理等5个方面的关键技术进行了探讨,并提出解决方案,为同类项目的设计与实施提供参考。