原油在储层介质中的加水裂解生气模拟实验

采用高温高压热模拟实验方法,开展了原油在砂岩和火成岩储层介质中的加水裂解生气模拟实验研究.结果表明,原油开始大量裂解的温度是400℃,随模拟温度增加,甲烷相对含量增大,乙烷以上重烃气尤其是丙烷相对含量减小.其中砂岩的油水混合物裂解生气主要发生在450～500℃之间,生气窗范围小,对应的烃气产率高,火成岩的油水混合物裂解生气主要发生在450～600℃之间,生气窗范围大,对应的烃气产率小.模拟烃气的组分碳同位素分馏显著,随模拟温度增加呈变重趋势.在裂解生气过程中,水解加氢和催化作用对烃气的组成、产率和碳同位素分布有重要影响。     

湘中锑(金)矿床成矿物质来源——Ⅰ.微量元素及其实验地球化学证据

为了查明湘中盆地中-低温梯（金）矿床的成矿物质来源，文章应用高分辨率ICP-MS、ICP-AES等方法对岩石与矿石进行了系统测定，并结合作者以往分析数据和实验地球化学结果，对该区盆地及周边基底地层与矿床中的微量元素分布特征及其水/岩反应效应进行了综合分析和系统研究。结果表明：Sb、Au等成矿元素在元古界基底碎屑岩中具有高的背景含量，在近似成矿条件下的水/岩反应实验中，成矿元素的淋出率达20%～90%，元古界基底碎屑岩中的金（锑、钨）矿床的周围蚀变围岩中出现明显的金负异常区。而盆地内泥盆系统地层中的高锑含量仅局限于锑矿床（化）及其蚀变围岩中；湘中锑（金）矿床中的矿石与基底碎屑岩具有相似的稀土元素球粒陨石标准化配分曲线特征，以上微量元素地球化学特征充分证明该区锑（金）矿床锑、金等成矿物质主要来源于元古界底碎屑岩。     

Electrons in feldspar II: a consideration of the influence of conduction band-tail states on luminescence processes

 Most natural feldspars contain many charged impurities, and display a range of bond angles, distributed about the ideal. These effects can lead to complications in the structure of the conduction band, giving rise to a tail of energy states (below the high-mobility conduction band) through which electrons can travel, but with reduced mobility: transport through these states is expected to be thermally activated. The purpose of this article is twofold. Firstly, we consider what kind of lattice perturbations could give rise to both localized and extended conduction band-tail states. Secondly, we consider what influence the band tails have on the luminescence properties of feldspar, where electrons travel through the sample prior to recombination. The work highlights the dominant role that 0.04–0.05-eV phonons play in both the luminescence excitation and emission processes of these materials. It also has relevance in the dating of feldspar sediments at elevated temperatures. Received: 11 May 2001 / Accepted: 6 September 2001     

川滇黔桂76种元素地球化学图编制中分析方法与分析质量研究(一) 不同实验室产生地球化学图的相似性——以Ag、Cs、Ga、Ge为例

编制中国76种元素地球化学图将使我们首次了解元素周期表上除氢、氧及惰性气体之外所有元素在中国大陆表层的分布,川滇黔桂76种元素地球化学图的编制是这一研究项目的试点。本文以不同实验室取得的Ag、Cs、Ga、Ge分析数据为例,探索、衡量不同实验室地球化学图相似性的方法,以优选实验室进行川滇黔桂4省区约4000件组合样76种元素的大规模分析工作。     

Momentum transport of wave zero during March: A possible predictor for the Indian summer monsoon

Analysis of monthly momentum transport of zonal waves at 850 hPa for the period 1979 to 1993, between ‡S and ‡N for January to April, using zonal (u) and meridional (v) components of wind taken from the ECMWF reanalysis field, shows a positive correlation (.1% level of significance) between the Indian summer monsoon rainfall (June through September) and the momentum transport of wave zero TM(0) over latitudinal belt between 25‡S and 5‡N (LB) during March. Northward (Southward) TM(0) observed in March over LB subsequently leads to a good (drought) monsoon season over India which is found to be true even when the year is marked with the El-Nino event. Similarly a strong westerly zone in the Indian Ocean during March, indicates a good monsoon season for the country, even if the year is marked with El-Nino. The study thus suggests two predictors, TM(0) over LB and the strength of westerly zone in the Indian Ocean during March.     

Experimental Study on Mine Spoils During Superficial Geochemistry Processes

Based on the mineral and chemical compositions of spoils taken from the Shilu Cu-Mo deposit and Hetai gold deposit, the leaching and batch experiments were made on spoils taken from these two deposits using the leaching column designed by the authors. The experimental results showed that it is not always true that the mine drainage is acidic. Its acidity depends on acid-buffering capacity of gangue, host rock and its alteration mineral assemblage. The composition of the drainage water is related with the interaction between superficial or underground water and solid materials in the spoils, including minerals, hydroxides and amorphous substances. The leaching extent of the element is related with its occurrence form in the deposit. The preferential flow results in leaching-out of heavy metals in large amounts. So it is important to prevent the generating of preferential flow in the system. The results will provide very important grounds for the comprehensive management of land and ecological rehabilitation of the mine site.     

MODELING THE FATE AND TRANSPORT OF HYDROPHOBIC ORGANIC COMPOUNDS IN AN UNSTEADY RIVER-ESTUARINE SYSTEM

1 INTRODUCTION Extensive literature (Brown et al., 1985; Sawhney et al., 1981; Bierman and Swain, 1982; Connolly, 1980; Lopez-Avila and Hites, 1980; O扖onnor, 1988) described lots of sorbed pollutants or toxic substances in bed sediments of rivers, even after the effluent was halted for a long time. This is particularly true for hydrophobic organic compounds that can be sorbed on the particles and accumulated in the river bed sediments (Karickhoff et al., 1979). Pollution events of…     

地震前兆时空非均匀性指标Cv值的实验检验

在双向加载条件下，对两种构造和介质不同的岩石标本进行变形实验，测量了标本表面不同部位的应变．在此基础上，利用王晓青和陈学忠等提出的描述地震前兆非均匀分布的参量————Cv值，分析了标本变形失稳过程中应变异常的分布，以期从实验角度检验Cv值方法并探讨其物理意义．研究表明，Cv值的变化与岩石变形特征的变化有关，是描述前兆分布非均匀性的一种有效指标；Cv值在失稳发生前先异常上升，然后下降，并在Cv值恢复过程中或恢复后伴随着失稳事件的发生．因此，Cv值是一种有效的预报指标．      

Hybrid vibration experiments with a bridge foundation system model

In order to improve seismic design technology of bridges, it is necessary to evaluate the vibration characteristics of a bridge–soil system that consists of soil, foundation structure, pier and superstructure. However, there have been few experimental studies on seismic behavior of bridge–soil system. In this paper, we conducted the hybrid vibration experiment on seismic behavior of bridge–soil system, and examined the applicability of hybrid vibration experiment to study seismic response of bridge–soil system. Based on the experiment results, seismic response of bridge was quantitatively studied.