琼东南盆地深水东区渐新统烃源岩发育模式

琼东南盆地深水东区勘探程度低,钻井样品受油基泥浆污染严重,目前关于该区浅海相和海陆过渡相烃源岩的有机地球化学研究较为局限。通过对深水东区渐新统受油基泥浆污染的泥岩岩屑进行有效地洗油实验及有机地球化学分析测试,结合东部浅水区渐新统烃源岩样品的有机岩石学、有机地球化学分析测试等地质资料,系统剖析了深水东区渐新统不同沉积相烃源岩的地球化学特征、发育控制因素和发育模式。研究结果认为,琼东南盆地深水东区渐新统烃源岩的发育模式可分为海陆过渡相三角洲前缘模式和浅海相模式。海陆过渡相三角洲前缘烃源岩为中等—高有机质丰度,有机质类型为Ⅲ型,具有Pr/Ph普遍大于3、(nC21+nC22/nC28+nC29)普遍小于1.2、高OL/C30H、高T/C30H、低C23TT/C30H、低C27ST/C29ST和相对较低的Ga/C30H、C35/C3422S的特征,烃源岩的TOC和硫含量相关性极好,沉积水体为氧化性淡水—半咸水环境。三角洲前缘烃源岩的TOC和母源输入参数相关关系较好,而与Ga/C30H、C35/C3422S参数相关关系较差,说明三角洲前缘烃源岩的有机质丰度主要受陆源有机质输入的控制。浅海相烃源岩有机质丰度中等,有机质类型为Ⅱ2~Ⅲ型,具有Pr/Ph普遍小于3、(nC21+nC22/nC28+nC29)普遍大于1.5、低OL/C30H、低T/C30H、高C23TT/C30H、高C27ST/C29ST和相对较高的Ga/C30H、C35/C3422S的特征,且烃源岩的TOC和硫含量相关性较差,沉积水体为弱氧化性半咸水—咸水沉积环境。浅海相烃源岩的TOC和母源输入参数、Ga/C30H、C35/C3422S等相关关系均较好,说明浅海相烃源岩有机质丰度受水生有机质输入和弱氧化性半咸水—咸水沉积环境控制。滨海相烃源岩的有机质丰度为差—中等,有机质类型以Ⅲ型为主,且TOC受母质来源或沉积水体的氧化还原性影响较小,其烃源岩发育模式是一种破坏性模式。     

Full-Sized Pore Structure and Fractal Characteristics of Marine-Continental Transitional Shale: A Case Study in Qinshui Basin,North China

Based on 10 shale samples collected from 4 wells in Qinshui Basin,we investigate the full-sized pore structure and fractal characteristics of Marine-Continental transitional shale by performing organic geochemistry,mineralogical composition,Nitrogen gas adsorption(N_2 adsorption)and Nuclear Magnetic Resonance(NMR)measurements and fractal analysis.Results show that the TOC content of the shale samples is relatively high,with an average value of 2.44wt%,and the thermal evolution is during the mature-over mature stage.The NMR T_2 spectrum can be used to characterize the fullsized pore structure characteristics of shale.By combining N_2 adsorption pore structure parameters and NMR T_2 spectrums,the surface relaxivity of samples are calculated to be between 1.7877 um/s and 5.2272 um/s.On this basis,the T_2 spectrums are converted to full-sized pore volume and surface area distribution curves.The statistics show that the pore volume is mainly provided by mesopore,followed by micropore,and the average percentages are 65.04%and 30.83%respectively;the surface area is mainly provided by micropore,followed by mesopore,and the average percentages are 60.8004%and39.137%respectively;macropore contributes little to pore volume and surface area.The pore structure characteristics of shale have no relationship with TOC,but strong relationships with clay minerals content.NMR fractal dimensions D_(micro) and D_(meso) have strong positive relationships with the N_2 adsorption fractal dimensions D_1 and D_2 respectively,indicating that D_(micro) can be used to characterize the fractal characteristics of pore surface,and D_(meso) can be used to characterize the fractal characteristics of pore structure.The shale surface relaxivity is controlled by multiple factors.The increasing of clay mineral content,pore surface area,pore surface fractal dimension and the decreasing of average pore size,will all lead to the decreasing of shale surface relaxivity.     

安徽东至查册桥矿区金矿地质特征及找矿潜力分析

查册桥矿区位于江南过渡带,包括牛头高家金矿床、程檀金矿床、路源金矿点和东边金矿化点、杨梅尖金矿点.其中牛头高家金矿是安徽省首次发现的具一定规模的红土型金矿.研究区主体位于东至断裂与高坦断裂带交汇处及其两侧,三岗尖-杨美桥背斜核部及北翼.区内存在多个重要的赋矿层位,主要包括南华系休宁组、南沱组,震旦系蓝田组,寒武系黄柏岭组、杨柳岗组,奥陶系仑山组、东至组.高坦断裂带、兰程畈断裂带、奥陶系/志留系间的推覆-滑覆断层界面均是重要的控岩控矿构造,区内岩浆岩主要受其控制,物化探异常也主要沿其分布.通过对矿床地质特征总结,并结合前人研究成果,对找矿潜力进行分析,认为区内具有寻找低温热液型-叠改型、层控夕卡岩型、岩浆热液脉型金、铜、钨、钼、银、铅锌等矿化的潜力.     

中国新疆矿床成矿系列类型

研究认为在不同时代、不同地质构造单元中重复出现的矿床成矿系列，可称为矿床成矿系列类型。新疆主要矿床成矿系列类型带有鲜明的古生代造山带成矿作用特点，它们联系于新疆各造山带古生代地壳发展的拉张型过渡壳－洋壳－汇聚型过渡壳－古生代新陆壳的各特定阶段，与各阶段地质构造作用密不可分。矿床成矿系列类型本身也随着地壳发展、地壳成熟度的提高而有规律地演化     

石榴子石族矿物的热发射率及其影响因素研究

本文主要研究石榴子石族矿物在１００，１５０，４００，６５０℃下，２．５～２５（４０）μｍ波长范围内的红外光谱发射率和总发射率，测试结果表明，石榴子石发射率大小受成分，铁离子价态，温度压力及铁，钴，镍等过渡族元素的影响。     

A mixed mid-Permian marine fauna from the Yanji area, northeastern China: A paleobiogeographical reinterpretation

Abstract Paleobiogeographically mixed marine faunas have been well recognized from many Permian marine sequences in northeast China. These mixed faunas are normally associated with Monodiexodina fusulinid assemblages. The mixed faunas are characterized by an admixture of both paleo-tropical Cathaysian taxa and cool-temperate elements. In addition, endemic taxa, especially at a specific level, and anti-tropical forms, are also very distinctive.
Previously, the presence of anti-tropical taxa in these mixed faunas has been used to argue that some of the northeast Asian terranes may have originated from northern Gondwana during the Permian, where they may have been m close proximity to Tibet. However, this interpretation is contrasted by the view offered in this paper. It is argued that the anti-tropical distribution of marine taxa is a normal, predictable biogeographical phenomenon that is probably controlled by certain climatic conditions. Permian anti-tropicality seems to have occurred most strongly during the Late Artinskian to Ufimian, probably in association with the presence of distinct mesothermal climatic zones at the time. In the present study we report a mixed mid-Permian marine fauna (fusulinids and brachiopods) from the Dasuangou Formation of the Yanji area in the eastern Jilin Province of northeast China, and discuss its possible origin in the context of Permian paleogeography and the climates of eastern Pangea.     

西藏岗巴晚白垩世有孔虫动物群与海平面变化

西藏南部岗巴地区上白垩统的有孔虫动物群十分丰富，经鉴定共有52属130种。根据岩性，该地区上白垩统可以划分出三个最基本的岩石地层单位：冷青热组、岗巴村口组及宗山组。依据其中有孔虫的形态结构、生态环境、系统演化及地史分布等特征，可以划分出五个主要的有孔虫动物群，Rotalipora动物群，Whiteinella-Helvetoglobotruncana动物群，Dicarinella-Marginotruncana动物群，Globotruncana-Globotuncanita动物群及Orbitoides-Omphalocyclus动物群。这五个有孔虫动物在晚白垩世相继绝灭，其绝灭与古水深有着十分密切的关系，主要是受海平面变化的影响。     

Study of crust-mantle transitional zone along the northeast margin of Qinghai-Xizang plateau

Introduction At the juncture of Qinghai-Xizang, Ordos and Alxa blocks lies the Qinghai-Xizang plateau, an area with complicated topographic and morphologic features, strong tectonic activities and frequent earthquakes (many large-magnitude earthquakes have taken place), has become a focal area for geoscience study. Many geophysical and geological surveys have been carried out in and around the area, such as deep seismic sounding (DSS), gravimetry, magnetotelluric sounding, magnetic anomaly …     

过渡带天然气地球化学特征

生物－热催化过渡带气作为一种新的天然气成因类型在国内外引起高度重视，其形成机制、分布规律和地球化学特征是当前研究的热点。本文通过分析我国十多个沉积盆地过渡带气组分和同位素组成，系统地探讨了过渡带气的地球化学特征，认为过渡带气是以甲烷为主含一定量重烃的烃类天然气，其δ＾１３Ｃ１为－６０‰－－４５‰。生气母质的沉积环境主要为陆相。各种类型的母质在演化的早期阶段均可形成过渡带气，但以偏腐殖型母质最为有利     

安徽含山中志留世海湾沉积环境中的痕迹化石组合

安徽含山中志留世坟头组地层中已识别出三种不同沉积环境条件下的痕迹化石组合:(1)Protopaleodictyon(始网迹)组合,由Protopaleodictyon submontanum,Acanthorhaphe sp., Planolites sp. 1和Gordia cf. molassica组成,产生于海湾(河口湾)潮下过渡带环境;(2)Arenicolites(沙蠋迹)组合,包括定形的Arenicolites sp., Skolithos sp.和Thalassinoides sp.以及Planokites sp. 1,并共生无定形的生物扰动潜穴和各种不规则形态的倾斜潜穴,伴生有腕足类的Lingula,腹足类的Orthonota, Hormotoma和Ecculiomphalus以及三叶虫类的Coronocephalus等实体化石,形成了海湾(河口湾)的泥砂质岸滨环境;(3)Chondrites(丛藻迹)组合,以高度分枝潜穴系统Chondrites furcatus和C. arbuscula的富集为特征,含少量Planolites化石,丰度高分异度低,伴生有腕足类的Striispirifer和三叶虫类的Coronocephalus以及瓣鳃类和腹足类等实体化石,代表具有一定局限性的海湾潮下带贫氧的底层沉积环境。