变质玄武岩体系相平衡及矿物 熔体微量元素分配：限定TTG/埃达克岩形成条件和大陆壳生长模型

埃达克质岩石是高Na、Al和Sr、低Y和HREE以及Nb、Ta亏损的钠质花岗质岩石,奥长花岗岩-英云闪长岩-花岗闪长岩(TTG)是早期(太古宙)大陆壳主要组分,成分与埃达克质岩石相似,这些成分独特的岩石总体上认为是俯冲洋壳、下地壳和拆沉的下地壳中变质玄武岩部分熔融的产物。文中综述我们近年来在变质玄武岩体系相平衡和矿物-熔体微量元素分配实验研究成果:相平衡实验和熔体微量元素特征研究表明,变质玄武岩部分熔融过程中金红石是导致TTG/埃达克岩浆Nb、Ta亏损的必要残留矿物,从而否定了前人“TTG由无金红石的角闪岩熔融产生”的观点;证实金红石仅仅在压力1.5GPa以上才能稳定存在,从而限定TTG/埃达克岩熔体必定产生在大约50km以上,表明TTG/埃达克岩是在相对较深的含金红石榴辉岩相条件下熔融产生的。矿物(石榴子石、角闪石,单斜辉石和金红石)-熔体微量元素分配系数测定和部分熔融模拟结果进一步限定俯冲洋壳和下地壳起源的TTG/埃达克岩浆由含金红石角闪榴辉岩熔融产生,而拆沉下地壳起源的埃达克岩浆的产生要求软流圈地幔高温,由无水或含有少量含水矿物的榴辉岩熔融产生。     

Column Amounts of ClONO2, HCl, HNO3, and HF from Ground-Based FTIR Measurements Made Near Kiruna, Sweden, in Late Winter 1994

During SESAME phase I ground-based FTIR measurements were performed atEsrange near Kiruna, Sweden, from 28 January to 26 March 1994. Zenith columnamounts of ClONO₂, HCl, HF, HNO₃,O₃, N₂O, CH₄, and CFC-12 werederived from solar absorption spectra. Time series of ClONO₂and HCl indicate a chlorine activation at the end of January and around 1March. On 1 March a very low amount of HCl of 2.09times; 10¹⁵molec. cm^-2 was detected, probably caused by a second chlorineactivation phase starting from an already decreased amount of HCl. The ratioof column amounts of HCl to ClONO₂ decreased inside the vortexfrom about 1 in January to 0.4 in late March compared to values of about 2outside the vortex. Although the Arctic stratosphere was rather warm in winter1993/94 and PSCs occurred seldom, chlorine partitioning into its reservoirspecies HCl and ClONO₂ changed during that winter andClONO₂ is the major chlorine reservoir at the end of thewinter as in cold winters like 1991/92 and 1994/95.     

The Geochemistry of Lake Joyce, McMurdo Dry Valleys, Antarctica

Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3O4). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters.     

Development of a Continental Volcanic Field: Petrogenesis of Pre-caldera Intermediate and Silicic Rocks and Origin of the Bandelier Magmas, Jemez Mountains (New Mexico, USA)

The Miocene–Quaternary Jemez Mountains volcanic field(JMVF) is the site of the Valles caldera and associated BandelierTuff. Caldera formation was preceded by > 10 Myr of volcanismdominated by intermediate composition rocks (57–70% SiO₂)that contain components derived from the lithospheric mantleand Precambrian crust. Simple mixing between crust-dominatedsilicic melts and mantle-dominated mafic magmas, fractionalcrystallization, and assimilation accompanied by fractionalcrystallization are the principal mechanisms involved in theproduction of these intermediate lavas. A variety of isotopicallydistinct crustal sources were involved in magmatism between13 and 6 Ma, but only one type (or two very similar types) ofcrust between 6 and 2 Ma. This long history constitutes a recordof accommodation of mantle-derived magma in the crust by meltingof country rock. The post-2 Ma Bandelier Tuff and associatedrhyolites were, in contrast, generated by melting of hybridizedcrust in the form of buried, warm intrusive rocks associatedwith pre-6 Ma activity. Major shifts in the location, styleand geochemical character of magmatism in the JMVF occur withina few million years after volcanic maxima and may correspondto pooling of magma at a new location in the crust followingsolidification of earlier magma chambers that acted as trapsfor basaltic replenishment. KEY WORDS: crustal anatexis; fractional crystallization; Jemez Mountain Volcanic Field; Valles Caldera; radiogenic isotopes; trace elements     

浙江安吉港口多金属矿床铅物质来源初探——铅同位素证据

位于浙西北安吉港口的铅锌银(钼)多金属矿床,是新近在钦杭成矿带东北缘发现的一个产于大陆环境且具较好前景的矿床.文章通过对矿区坞山关杂岩体三套岩性单元、细粒花岗岩和方铅矿铅同位素的全面对比研究,探讨了矿床的铅物源岩浆岩.矿区中的方铅矿为含较高放射性成因铅的J-型铅,在铅同位素的V1-V2和△γ-Δβ图解中,本次研究的样品分别落入华南和岩浆作用上地壳混合地幔铅范围,显示出方铅矿与华南地球化学省壳幔混合岩浆作用的密切关系.矿区铅锌矿体的方铅矿铅同位素比值显示其具有共同的物质来源,并基本保持了细粒花岗岩206Pb/204Pb值的特征,而207Pb/204Pb值具有坞山关杂岩体和细粒花岗岩混合的特征,208Pb/204Pb和208Pb/206Pb值则仅显示出与细粒花岗岩最相近.方铅矿铅同位素比值特征和比值等值线分布形式显示,铅主要来源于细粒花岗岩,杂岩体对铅成矿贡献了少量的206Pb和207Pb,矿区地层对铅成矿贡献了一定的208Pb.安吉矿区进一步针对铅的找矿工作围绕细粒花岗岩展开,取得成果的可能性更大.     

Mass Fractions of S,Cu, Se,Mo, Ag,Cd, In,Te, Ba,Sm, W,Tl and Bi in Geological Reference Materials and Selected Carbonaceous Chondrites Determined by Isotope Dilution ICP‐MS

Mass fractions of S, Cu, Se, Mo, Ag, Cd, In, Te, Ba, Sm, W and Tl were determined by isotope dilution sector field ICP‐MS in the same sample aliquot of reference materials using HF‐HNO₃ digestion in PFA beakers in pressure bombs and glassy carbon vessels in a high‐pressure asher (HPA‐S) for comparison. Additionally, Bi was determined by internal standardisation relative to Tl. Because isobaric and oxide interferences pose problems for many of these elements, efficient chromatographic separation methods in combination with an Aridus desolvator were employed to minimise interference effects. Repeated digestion and measurement of geological reference materials (BHVO‐1, BHVO‐2, SCo‐1, MAG‐1, MRG‐1 and UB‐N) gave results with < 5% relative intermediate precision (1s) for most elements, except Bi. Replicates of NIST SRM 612 glass digested on a hot plate were analysed by the same methods, and the results agree with reference values mostly within 2% relative deviation. Data for the carbonaceous chondrites Allende, Murchison, Orgueil and Ivuna are also reported. Digestion in a HPA‐S was as efficient as in pressure bombs, but some elements displayed higher blank levels following HPA‐S treatment. Pressure bomb digestion yielded precise data for volatile S, Se and Te, but may result in high blanks for W.     

电子探针和LA-ICP-MS技术研究内蒙古浩尧尔忽洞金矿床毒砂矿物学特征

毒砂的主微量元素组成可以用于判断元素的赋存状态,探讨元素在不同阶段的活化迁移行为.内蒙古浩尧尔忽洞金矿床是产自白云鄂博群黑色岩系中的一个超大型金矿,发育重要载金矿物毒砂和斜方砷铁矿.前人利用传统粉末溶样法对矿石进行同位素分析,探讨了成矿物质来源,但金的迁移富集机制尚未获得解决.为探讨该矿床金迁移富集过程,本文在矿相学的...     

Lead analysis of sediment cores from seven Connecticut lakes

Lead analyses were performed on sediment cores from seven Connecticut lakes by dilute acid leaching. The absolute concentrations of lead varied from core to core, but the lead profiles were similar in all of the cores, and each depicted a point where the concentration of lead sharply increased above background levels. The background lead concentrations observed in the bottom portions of the cores ranged from 12-54 g Pb/g sediment with a mean of 30 g Pb/g, and increased to a mean maximum of 310 g Pb/g. In six of the lakes significant increases above background levels were not noted until between 1924 and 1952, suggesting that, at least for Connecticut lakes, the point in a lake sediment core where the concentration of lead began to increase was after ca. 1924, and on average about 1930. Lead concentrations declined in the surface sediments of only three of the lakes, mostly since the 1980's, and presumably in response to the phasing out of leaded gasoline. However, significant declines in lead concentrations were not observed in the remaining cores, possibly due to increased motor vehicle use within the airshed of the lakes and/or changes in the export of lead to the lakes from their watersheds.     

On the Retrieval of Volcanic Sulfur Dioxide Emissions from GOME Backscatter Measurements

We focus on the retrieval of volcanic sulfur dioxide (SO₂) emissions from an analysis of atmospheric UV backscatter spectra obtained by the Global Ozone Monitoring Experiment (GOME) spectrometer on board the ESA European Remote Sensing Satellite (ERS-2). Here, the last major eruptions of Mt. Etna on Sicily (Italy) in July/August 2001 and October/November 2002 provided an excellent opportunity to study the retrieval of SO₂ columnar amounts from ground-based, LIDAR and satellite measurements. Our study shows that the bulk of emitted SO₂ was confined in the troposphere, mainly between 700 hPa and 400 hPa which is confirmed by trajectory analysis, by LIDAR observations and AVHRR observations. The area of influence of Mt. Etna eruptions ranges from the Western Saharan Desert to Greece and the near east states and even down to the basin of Tschad, Africa. Our analysis revealed that information about the plume height of volcanic eruptions and aerosol parameters is necessary for a reliable quantitative retrieval of SO₂ from space-borne sensor data at periods perturbed by volcanic eruptions.     

Metallogeny of the Baiyangping Lead‐Zinc Polymetallic Ore Concentration Area,Northern Lanping Basin of Yunnan Province,China

The Lanping Basin in the Nujiang‐Lancangjiang‐Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of large unique sediment‐hosted Pb‐Zn polymetallic deposits or ore districts, such as the Baiyangping ore concentration area which is one of the representative ore district. The Baiyangping ore concentration area can be divided into the east and west ore belts, which were formed in a folded tectogene of the India‐Asia continental collisional setting and was controlled by a large reverse fault. Field observations reveal that the Mesozoic and Cenozoic sedimentary strata were outcropped in the mining area, and that the orebodies are obviously controlled by faults and hosted in sandstone and carbonate rocks. However, the ore‐forming elements in the east ore belt are mainly Pb‐Zn‐Sr‐Ag, while Pb‐Zn‐Ag‐Cu‐Co elements are dominant in the west ore belt. Comparative analysis of the C‐O‐Sr‐S‐Pb isotopic compositions suggest that both ore belts had a homogeneous carbon source, and the carbon in hydrothermal calcite is derived from the dissolution of carbonate rock strata; the ore‐forming fluids were originated from formation water and precipitate water, which belonged to basin brine fluid system; sulfur was from organic thermal chemical sulfate reduction and biological sulfate reduction; the metal mineralization material was from sedimentary strata and basement, but the difference of the material source of the basement and the strata and the superimposed mineralization of the west ore belt resulted in the difference of metallogenic elements between the eastern and western metallogenic belts. The Pb‐Zn mineralization age of both ore belts was contemporary and formed in the same metallogenetic event. Both thrust formed at the same time and occurred at the Early Oligocene, which is consistent with the age constrained by field geological relationship.