鄂尔多斯盆地南部延长组富铀凝灰岩地球化学特征及形成机制

本文系统地研究了鄂尔多斯盆地南部延长组凝灰岩元素和同位素地球化学特征。结果表明：凝灰岩主量元素具有高K、高Al、Si中等至高、低Na的特征; REE总体特征为轻稀土富集、重稀土亏损,∑REE在4857～40212 μg/g 之间变化,Eu呈现出负异常,在034～082内变化,δCe范围在080～208之间; 微量元素中U含量在312～144 μg/g 之间,Ba、U、Th、Hf和Ce呈明显正异常,Nb、P、Ti和Rb呈现负异常。详细的分析表明：U的富集和一些微量元素如Ta、Dy、Lu等相关,Th与∑REE存在明显的正相关性,这些变化可能和盆地中铀矿的富集有关; 凝灰岩的硫同位素总体呈现深源特征。根据以上的研究对凝灰岩的形成原因及形成环境进行了探讨。鄂尔多斯盆地南部延长组凝灰岩来源于秦岭造山带火山作用,其中的铀元素富集是由于砂岩型铀矿中铀向凝灰岩迁移而被还原所致。本研究对盆地砂岩型铀矿的铀运移和富集机理认识具有一定指导意义。     

玲珑金矿黄铁矿热电性与微量元素标型及深部金矿化评价

在前人对玲珑金矿矿体浅部的研究基础之上,通过对矿体深部黄铁矿的热电性测试与分析,得出：西山矿区380m—90m中段,黄铁矿导型以P—N型（空穴型-电子型导电）为主;东山矿区50m—850m标高范围内,黄铁矿导型以P—N或N—P（电子型-空穴型导电）混合型为主。东、西山矿区的P型出现率在垂向上呈高-低-高的韵律式脉冲变化...     

高峰100号矿体硫、铅同位素特征

10 0号矿体的成矿物理化学环境为 :成矿温度 30 0± 30℃ ;成矿压力为 84.2× 10 5Pa ;LogfO2 =- 30 .4～- 35 .6 ,LogfCO2 =- 2 .5 5～ +0 .36 ,LogfS2 =- 8.3～ - 11.0 ,pH =4.2～ 4.9。同位素的分析结果 :硫化物的硫同位素为 6 4‰～ 12 .3‰ ,δ3 4 SΣS 值为 6 6～ 13 8;2 0 6Pb 2 0 4Pb值为 17 4 91～ 18 96 0 ,2 0 7Pb 2 0 4Pb值为 15 5 39～15 940 ,2 0 8Pb 2 0 4Pb值为 37 95 7～ 39 4 90。表明 10 0号矿体的硫源是混合硫 ,铅源是两种异常铅混合的结果。     

大地电场观测深埋铅电极测量系统试验

为使用铅电极替代不极化电极,以解决滨海地区大地电场观测系统稳定性差的问题,先后开展了浅埋的铅电极与不极化电极的大地电场对比观测,以及深埋铅电极与浅埋铅电极的对比观测试验。结果表明:铅电极与固体不极化电极的观测数据在短期内有较好的一致性;深埋铅电极的大地电场观测资料在长期稳定性上优于固体不极化电极;而观测数据的内在观测质量也高于浅埋铅电极。     

Regional Variations in the Mineralogy of Metasomatic Assemblages in Mantle Xenoliths from the West Eifel Volcanic Field, Germany

Xenoliths record two distinct events in the mantle below theQuarternary West Eifel Volcanic Field, Germany. The first, duringthe Hercynian Orogeny, led to widespread formation of secondary,Ti-poor amphibole, clinopyroxene and phlogopite. The signatureof the second event, related to Quaternary volcanism, variesacross the field. At Dreiser Weiher and Meerfelder Maar, thisevent is characterized by amphibole–phlogopite–clinopyroxeneveins, hosted in lherzolite and harzburgite xenoliths broughtto the surface by sodic olivine nephelinite–basanite suitelavas. These veins formed from crystallization of sodic magmathat flowed along fractures in the mantle. At Rockeskyller Kopf,Gees and Baarley, the Quaternary event is characterized by wehrlitexenoliths, many of which have phlogopite–clinopyroxeneveins, that were transported by potassic foid suite lavas. Wehrliteformed by reaction of lherzolite–harzburgite, with a largevolume of potassic magma that flowed along grain boundariesrather than in fractures. During reaction, orthopyroxene wasconsumed and secondary clinopyroxene, olivine and phlogopiteprecipitated. Veins formed in wehrlites only during periodicover-pressure events. The composition of the magmas parentalto the veins is similar to the lavas that carried the xenolithsto surface, indicating that the source of foid and olivine nephelinite–basanitesuite magma is domainal, as was the flow regime and magma flux. KEY WORDS: Eifel; mantle xenoliths; metasomatism; trace elements     

Indium Enrichment in the Meng'entaolegai Ag-Pb-Zn Deposit, Inner Mongolia, China

Abstract. The Meng'entaolegai In-rich Ag-Pb-Zn deposit is located in the eastern part of Inner Mongolia. It is one of the In-richest deposits in China. Large amounts of quartz and sulfide minerals constitute a hydrothermal quartz-sulfide vein deposit within a Hercynian acidic granite massif, which occupies an area of about 400 km². Thirty-six orebodies, controlled strictly by the E-W trend faults, are found in the orefield of 6 km in length from east to west and 200 to 1,000 m in width from south to north. The ore minerals are mainly galena, sphalerite and pyrite, and subordinate chalcopyrite, arsenopyrite, cassiterite and stannite with many Ag-minerals. The gangue minerals are mainly quartz, calcite, sericite and chlorite. Economic components of the deposit are dominated by Pb andZn (reserves of Pb and Zn are 0.17 Mt and 0.37 Mt, and their grades are 1 % and 2.3 %, respectively), with Ag, Sn, In and Cd (1,800 t Ag, >2,000 t Sn, >500 t In and 1,800 t Cd) as by-products. Indium is highly enriched in ores and its contents are 9 to 295 ppm in ores and 85 to 2,660 ppm in sphalerite. Analytical results show that the ore-forming fluid of this deposit contains 0.8–3.5 ppm In and 4–36 ppm Sn, and the two elements show a very good positive correlation with a correlation coefficient of 0.8672, while the correlation between In and Zn in the ore-forming fluids, with a correlation coefficient of 0.5723, is not as good as that between In and Sn. This indicates that indium has an affinity with tin in the ore-forming fluids. The authors think that this is probably the main reason why those In-rich deposits spread over the world are simultaneously enriched in tin.     

地电化学异常形成机理初探

一直以来,人们都倾向认为地电化学方法取得的异常是由其吸附的金属离子引起,文中通过多个矿区地电化学试验发现,电提取微量元素异常往往与Fe、Al等常量元素异常高度一致,而Fe、Al等常量元素是组成粘土矿物的主要成分. 进一步对地电化学泡塑样品开展扫描电镜观测,发现电提取后泡塑载体样品中存在大量的大小从数微米至数十微米的粘土矿物颗粒. 由此初步推断,当前所使用的地电化学方法取得的异常很大程度上是由土壤中存在的具有电活动性的极细粒粘土矿物颗粒引起,地电化学提取过程对这些粘土矿物颗粒具有选择性吸附.     

牙形石微量元素对生物绝灭事件的响应: 以二叠-三叠系全球层型剖面第一幕绝灭事件为例

首次系统地利用浙江长兴煤山剖面牙形石化石, 依托中国地质大学(武汉) 地质过程与矿产资源国家重点实验室激光剥蚀等离子体质谱仪(LA-ICP-MS) 获取牙形石微区原位元素含量信息.结果显示, 牙形石的Ce异常和稀土总量出现快速的波动, 它们均反映出P/T之交环境(氧化-还原、生态条件等) 的不稳定性.这些微量元素特征可以很好地与古海洋环境和生物绝灭事件耦合.这一研究将为系统探索全球古生代末生物大灭绝及其后生物复苏的过程、时限与古海洋化学及古生态变化性质等问题的研究提供新的途径, 并有望对这些重要科学问题提供有效的制约.      

兖州矿区煤中某些微量元素的赋存状态研究

微量元素的赋存状态决定其在煤的加工利用过程中释放的难易程度和毒性，弄清其在煤中的赋存状态，对准确评价元素的工艺性能、环境影响、作为副产品的可能性以及在地质意义上都是十分重要的。分析了微量元素在煤中的有机亲合性，采用数理统计方法，求得了微量元素与煤中有机显微组分、三态硫、灰分之间的相关性，并在浮沉实验的基础上，分析了微量元素的存在状态，通过研究向知，Ge、Ga、U、V、Cu、Th、Pb和Zn主要以无机态存在于煤中，F和Cl可能以有机态存在为主，As无机态和有机态存在的机率相似。     

塔西南缘铅锌矿带典型矿床的矿石组构特征

通过对位于西昆仑北带奥依塔格-库尔良晚古生代(弧后)裂陷盆地塔西南缘铅锌矿带典型矿床矿石结构构造特征进行研究,总结出该矿带各个矿床(点)之间具有相同或相似的矿物共生组合(黄铁矿-方铅矿-闪锌矿-黄铜矿)以及相似的组构特征。主要结构包括草莓状结构、骸晶结构、自形晶结构、固溶体分离结构、交代结构及揉皱结构等;构造包括浸染状构造、流动构造、条带状构造、脉状构造及角砾状构造等,这些组构特征的共性表明成矿作用均具有多期多阶段的特征,并指示出热水沉积成矿兼有后期热液改造的结构构造特征。结合野外地质特征,该区铅锌矿床形成经历了同生沉积与后期改造过程。