鲁西地区中生代碳酸岩类的微量元素和锶、钕同位素组成特征

对鲁西地区早白垩纪的碳酸岩岩体的稀土、微量元素和同位素组成的研究表明 ,鲁西碳酸岩不同于任何沉积成因的灰岩和变质成因的大理岩 ,而与世界典型的幔源碳酸岩具有相似的稀土元素组成 ,说明其为幔源成因 ,碳酸岩极度富集轻稀土元素。鲁西碳酸岩的锶、钕同位素组成表明其地幔源区为具有EMI和EMII端元混合特征的富集地幔。     

Implications of εNd—La／Nb,Ba／Nb,Nb／Th Diagrams to Mantle Heterogeneity—Classification of Island—arc Basalts and Decomposition of EMII Component

A group of εNd/Nb,Ba/Nb,Nb/Th diagrams are used to study mantle heterogeneity.Island-arc basalts(IAB) are distributed in a triangle of these diagrams. Three end-member components (the MORB-type depleted mantle, the fluid released from subducted oceanic crust and the sediments from the continental crust) of the source of IAB may be displayed in these diagrams. Two types of IAB are identified .They are of the two-component type (with little continental sediments), such as the basalts from Aletians and New Britain ,and the three-compeonent type, such as those from Sunda, Lesser Antilles and Andes. In addition ,the EMII type mantle-derived rocks may also be divided into two groups. One is exemplified by continental flood basalts and some peridotite xenoliths, similar to IAB, with high La/Nb and Ba/Nb and low Nb/Th ratios, The other includes the Samoa-type oceanic island basalts, with low La/Nb and Ba/Nb and high Nb/Th ratios. The corresponding two sub-components of EMII are EMIIM, which is related to the metasomatism of lithosphere mantle by fluids released from the subducted oceanic crust, and EMIISR, related to the intervention of recycling continental sediments into the convective mantle.     

The mafic-ultramafic complex near Finero (Ivrea-Verbano Zone), I. Chemistry of MORB-like magmas

Geochemical data are presented for the meta-igneous, mafic-ultramafic complex near Finero. This complex is in contact with a phlogopite-bearing mantle peridotite and is subdivided into the Internal Gabbro unit, the Amphibole Peridotite unit, and the External Gabbro unit. The Internal Gabbro and the Amphibole Peridotite units consist of coarse-grained, chemically heterogeneous cumulates, whereas the External Gabbro unit is generally massive, chemically more uniform and approximately representative of the residual melt with MgO contents between 6.6 and 9.1% and Mg numbers between 38 and 58. Both whole-rock and mineral contents of Ni and Cr are significantly higher (at similar Mg numbers) in the Amphibole Peridotite unit than in the Internal Gabbro unit. The most straightforward interpretation of this is that the Amphibole Peridotite unit accumulated after the influx of fresh mafic (or ultramafic) magma into the magma chamber. Major-element chemical trends are continuous from the Amphibole Peridotite unit to the External Gabbro unit and are consistent with closed-system fractionation with no further addition of magma or contamination by wall or roof rock assimilation. In the External Gabbro unit, total FeO and TiO₂ contents are strongly correlated with each other (and with P₂O₅ and Zr) and reach values as high as 19 and 4%, respectively, indicating an advanced degree of crystal fractionation along a tholeftic trend. The External Gabbro samples have generally smooth normalized trace element patterns, which are consistent with being representative of a liquid composition. The residual nature of the External Gabbro magma is also indicated by negative Eu and Sr anomalies, clear evidence for prior feldspar fractionation. REE patterns are otherwise indistinguishable from N-type MORB, but Th and U are significantly more depleted than in MORB. This Th and U depletion is similar to that found in olivine basalts and picrites on Iceland and Hawaii; its origin is not well understood. No evidence is seen for any assimilation of crystal material, in sharp contrast with the situation of the igneous complex in Val Sesia near Balmuccia, where the magma composition is dominated by assimilation of crust. We suggest that the heat provided by at most two injections of magma near Finero was insufficient to induce crystal anatexis, in contrast with the excess heat supplied by multiple magma injections at Balmuccia.     

An examination of the use of the logratio transformation for the testing of endmember hypotheses

Given a compositional dataset in the absence of any prior information on any mixing process which may have formed it, a complete analysis of mixtures determines three distinct types of estimates in order. These are: (i) the estimate of the number of endmembers or fixed source compositions, of which all the sample compositions of the dataset must be approximate mixtures; (ii) the estimated compositions for each of these chosen number of endmembers; and (iii) the estimated contributions of each of these endmember estimates to each sample. Traditionally, the estimate for the number of endmembers has been assessed either by mapping or by inspection of the coefficients of determination between the observed and estimated variables. Mapping entails the plotting on a map of the region from which the samples were taken, either the contours of the contributions of each endmember to each sample, or some other portrayal of the distribution of endmember abundances. Because it requires the complete analysis, assessment by this method is too elaborate except for final confirmation and display. Alternatively, choosing a number of endmembers, which result in suitability high coefficients of determination for all or most variables, may account for elements which are not part of the conjectured mixing process or, worse, may result in the identification of endmembers which may never in fact have existed. Such an error is similar to overspecifying a multiple regression model. So, the obvious starting point from which to assess the validity, or otherwise choice of endmember numbers, is to examine the matrix of residuals. The differences between the logratio-transformed observed and estimated data form an array of residual logratios. A linear combination of these may be formed for each sample, which, under a random perturbation assumption, should follow a univariate normal distribution. Whether or not this scalar is normal can be readily tested. It can also be examined graphically for such desirable qualities as symmetry when the test for normality may be too severe. This procedure is employed to assess the decompositions of the U.S.G.S. Mid-Pacific data and the Nazca Plate Surface sediments.This paper was presented at the 18th Geochautauqua, Newark, Delaware, 13–14 October 1989.     

应用碳、氦、氩同位素探讨济阳拗陷二氧化碳气成因

应用碳、氦、氩同位素和气体组分指标 ,以及流体包裹体测定等手段 ,结合济阳拗陷基本地质条件 ,提出二氧化碳气藏的二氧化碳气主要以幔源成因为主。     

黄铁矿的微量元素及热电性和晶体形态分析

金矿床中黄铁矿的微量元素、热电性、晶体形态等标形特征与其形成的物理化学环境及介质条件密切相关。该标型特征在判别不同矿化类型、揭露金矿床空间的变化规律、评价矿体和预测深部矿体等方面都具有一定的代表性和典型性。同时 ,黄铁矿微量元素的分析方法具有易于采样、易于分析、经济有效、方便实用的特点 ,是金矿找矿矿物学研究及应用中行之有效的方法。     

澳大利亚布朗斯(Browns)Co-Cu-Ni多金属矿床地球化学特征及与中国南方黑色岩系金属矿床对比

黑色岩系中金属元素地球化学特征一直是矿床地质研究的重点.澳大利亚布朗斯Co-Cu-Ni多金属矿产于古元古代黑色岩系中,属典型的层控矿床;该矿床中主要成矿元素为Co、Cu、Ni和Pb,矿化分带不明显,蚀变微弱.δ34S均值范围为-5.21‰～14.78‰,估计生物成因的硫占一定比例,后期有细菌还原硫酸盐成因的高硫同位素组...     

贵州纳雍水东铅锌矿矿床地球化学特征

对贵州纳雍水东乡洗米沟、坟山脚一带灯影组地层中铅锌矿石采样,进行镜下观察和全岩主量、微量元素、稀土元素以及硫同位素地球化学研究。微量元素研究表明,矿床中N i、Mo、As、Sb等成矿元素富集明显,Sr、Ba、V等元素强烈亏损,认为早寒武世热水对铅锌矿源层进行了淋滤和改造;稀土元素研究表明,铅锌矿石稀土配分曲线向右倾斜,...     

河南嵩县香春沟石英脉型钼矿的矿石及地球化学特征

香春沟钼矿床是河南省新发现的唯一中型石英脉型钼矿床.主要矿石类型为石英脉型钼矿石,具有超酸高钾的特点,矿石构造结构简单,矿区有用矿物主要是辉钼矿,其粒度细小,不易与脉石分离.文章通过分析区内元素的地球化学特征,为寻找该类型钼矿床提供参考.     

黑龙江穆棱地区宝石级锆石成因探讨

利用基本的宝石学方法、紫外可见光分光光度计、红外光谱仪、激光拉曼探针和激光剥蚀等离子质谱技术(LA-ICP-MS)分析了黑龙江穆棱玄武岩风化冲积物中宝石级锆石的宝石学性质、谱学特征、包裹体特征、微量元素组成及U-Pb年龄。宝石学性质表明锆石为优质的、可直接加工利用的宝石原料;谱学特征显示锆石为未经历后期改造的高型岩浆锆石,且含有磷灰石、锆石和赤铁矿包裹体;LA-ICP-MS分析表明锆石具有明显的Ce正异常,富集重稀土元素[(Yb/Sm)N=21～63)]和HFSE元素,Th/U均大于1(1个数据例外);ΣREE较高,含量在1765×10-6～2374×10-6,与基性锆石相似;明显的Ce异常和赤铁矿包裹体说明锆石形成于氧化环境;根据Ti-in-Zircon地质温度计计算,锆石结晶的最低温度为646～737℃;U-Pb年龄为9.39±0.4Ma代表锆石的结晶年龄。基于本实验数据和前人研究成果,认为锆石巨晶形成于富集CO2的氧化环境并且与地幔的交代作用有关,是岩石圈减薄作用发展到一定阶段(衰退期)的产物。