原油在储层介质中的加水裂解生气模拟实验

采用高温高压热模拟实验方法,开展了原油在砂岩和火成岩储层介质中的加水裂解生气模拟实验研究.结果表明,原油开始大量裂解的温度是400℃,随模拟温度增加,甲烷相对含量增大,乙烷以上重烃气尤其是丙烷相对含量减小.其中砂岩的油水混合物裂解生气主要发生在450～500℃之间,生气窗范围小,对应的烃气产率高,火成岩的油水混合物裂解生气主要发生在450～600℃之间,生气窗范围大,对应的烃气产率小.模拟烃气的组分碳同位素分馏显著,随模拟温度增加呈变重趋势.在裂解生气过程中,水解加氢和催化作用对烃气的组成、产率和碳同位素分布有重要影响。     

Regional Variations in the Mineralogy of Metasomatic Assemblages in Mantle Xenoliths from the West Eifel Volcanic Field, Germany

Xenoliths record two distinct events in the mantle below theQuarternary West Eifel Volcanic Field, Germany. The first, duringthe Hercynian Orogeny, led to widespread formation of secondary,Ti-poor amphibole, clinopyroxene and phlogopite. The signatureof the second event, related to Quaternary volcanism, variesacross the field. At Dreiser Weiher and Meerfelder Maar, thisevent is characterized by amphibole–phlogopite–clinopyroxeneveins, hosted in lherzolite and harzburgite xenoliths broughtto the surface by sodic olivine nephelinite–basanite suitelavas. These veins formed from crystallization of sodic magmathat flowed along fractures in the mantle. At Rockeskyller Kopf,Gees and Baarley, the Quaternary event is characterized by wehrlitexenoliths, many of which have phlogopite–clinopyroxeneveins, that were transported by potassic foid suite lavas. Wehrliteformed by reaction of lherzolite–harzburgite, with a largevolume of potassic magma that flowed along grain boundariesrather than in fractures. During reaction, orthopyroxene wasconsumed and secondary clinopyroxene, olivine and phlogopiteprecipitated. Veins formed in wehrlites only during periodicover-pressure events. The composition of the magmas parentalto the veins is similar to the lavas that carried the xenolithsto surface, indicating that the source of foid and olivine nephelinite–basanitesuite magma is domainal, as was the flow regime and magma flux. KEY WORDS: Eifel; mantle xenoliths; metasomatism; trace elements     

盾构机穿越江河浅覆土层最小埋深的研究

盾构机穿越江、海、湖泊等浅覆土层时,由于隧道衬砌所受浮力作用,上部覆土厚度极为重要。针对传统上覆土层厚度计算方法中没有考虑土体自身剪切强度对抗浮作用发挥的问题,提出了一个新的覆土厚度计算方法,并通过算例对所提的计算方法与简化计算方法进行对比分析。说明了新的计算方法比传统计算方法更符合实际。最后,通过有限元数值计算浅覆土层的应力、应变情况,进一步验证了该计算方法的合理性。     

碳酸盐岩中有机质组成特征分析

对碳酸盐岩有机质组分进行分类时，有两种分类标准，一是主要采用煤岩学方法，二是采用孢粉学研究方法。本文使用煤岩学方法作为标准，对碳酸盐岩有机质的组成特征进行分析。按有机质来源和有机组分光性和形态等方面差别划分为内源有机质、次生有机质和陆源有机质三类。内源有机质类中分腐泥组和动物有机组，前者主要来源于菌藻类，后者则主要来源于浮游动物有机体；次生有机质中区分出微粒体、有机包裹体、沥青；陆源有机质类分类术语仍沿用煤显微组分分类系统和术语。碳酸盐岩烃源岩的有机质主要为腐泥型，有机质来源以低等藻类为主，且有机质组成特征与碳酸盐岩烃源岩的地质年代有关。碳酸盐岩还存在着差异演化的特征。     

地下管网地震反应分析模型

建立了多点地震动激励作用下的地下管网地震反应拟静力分析模型。首先建立基于有限单元模型的地下管网系统刚度方程,接着给出考虑地震动空间相关性及场地条件等诸多因素的地震动场模拟思路及管网系统地震动施加策略,最后通过解析法验证了模型的正确性。采用本文方法对一＂十＂字形管网进行了地震反应分析,结果表明：①管线轴向应力沿着管线长度从管线端部向管线交叉点逐步增大,在管线交叉点处应力达到最大值;②与轴向应力相比,尽管管线的弯曲应力不是控制应力,但在管线端部及管线交叉点处弯曲应力值将会有较大突变。因此,对于地下管网而言,在受到地震作用时,不同布置方向的管线之间的相互影响是不容忽视的。     

春季长江口富营养化水域浮游植物群集对冲淡水和上升流的响应

A comprehensive study on the phytoplankton standing stocks, species composition and dominant species in the eutrophic Changjiang(Yangtze River) Estuary(CE) was conducted to reveal the response of phytoplankton assemblage to Changjiang Diluted Water(CDW) and upwelling in the spring. Phytoplankton presented peak standing stocks(13.03 μg/L of chlorophyll a, 984.5×103 cells/L of phytoplankton abundance) along the surface isohaline of 25. Sixty-six species in 41 genera of Bacillariophyta and 33 species in 19 genera of Pyrrophyta were identified, as well as 5 species in Chlorophyta and Chrysophyta. Karenia mikimotoi was the most dominant species, followed by Prorocentrum dentatum, Paralia sulcata, Pseudo-nitzschia delicatissima and Skeletonema costatum. A bloom of K. mikimotoi was observed in the stratified stations, where the water was characterized by low nitrate, low phosphate, low turbidity, and specific ranges of temperature(18–22 °C) and salinity(27–32). K.mikimotoi and P. dentatum accumulated densely in the upper layers along the isohaline of 25. S. costatum was distributed in the west of the isohaline of 20. Benthonic P. sulcata presented high abundance near the bottom,while spread upward at upwelling stations. CDW resulted in overt gradients of salinity, turbidity and nutritional condition, determining the spatial distribution of phytoplankton species. The restricted upwelling resulted in the upward transport of P. sulcata and exclusion of S. costatum, K. mikimotoi and P. dentatum. The results suggested that CDW and upwelling were of importance in regulating the structure and distribution of phytoplankton assemblage in the CE and the East China Sea.     

中国绿洲化及其研究进展

绿洲化是干旱区人与自然因素共同作用下荒漠向绿洲转变的过程。中国绿洲面积从20世纪50年代初期的20 000 km²扩展到2000年的86 000 km²,扩大了3.3倍。绿洲化过程不仅伴随着景观格局的变化,而且会引发土壤、生物、气象和水文等要素的变化。分析了近2 000 a来中国干旱区绿洲的演变过程,评述了绿洲化过程中景观变化,其对绿洲稳定性的影响及绿洲化过程中土壤要素、气象水文要素变化等诸多方面的研究进展,同时提出未来的研究中应加强绿洲化过程研究框架的建立、绿洲化过程中关键因素变化及绿洲化关键过程研究。     

Indium Enrichment in the Meng'entaolegai Ag-Pb-Zn Deposit, Inner Mongolia, China

Abstract. The Meng'entaolegai In-rich Ag-Pb-Zn deposit is located in the eastern part of Inner Mongolia. It is one of the In-richest deposits in China. Large amounts of quartz and sulfide minerals constitute a hydrothermal quartz-sulfide vein deposit within a Hercynian acidic granite massif, which occupies an area of about 400 km². Thirty-six orebodies, controlled strictly by the E-W trend faults, are found in the orefield of 6 km in length from east to west and 200 to 1,000 m in width from south to north. The ore minerals are mainly galena, sphalerite and pyrite, and subordinate chalcopyrite, arsenopyrite, cassiterite and stannite with many Ag-minerals. The gangue minerals are mainly quartz, calcite, sericite and chlorite. Economic components of the deposit are dominated by Pb andZn (reserves of Pb and Zn are 0.17 Mt and 0.37 Mt, and their grades are 1 % and 2.3 %, respectively), with Ag, Sn, In and Cd (1,800 t Ag, >2,000 t Sn, >500 t In and 1,800 t Cd) as by-products. Indium is highly enriched in ores and its contents are 9 to 295 ppm in ores and 85 to 2,660 ppm in sphalerite. Analytical results show that the ore-forming fluid of this deposit contains 0.8–3.5 ppm In and 4–36 ppm Sn, and the two elements show a very good positive correlation with a correlation coefficient of 0.8672, while the correlation between In and Zn in the ore-forming fluids, with a correlation coefficient of 0.5723, is not as good as that between In and Sn. This indicates that indium has an affinity with tin in the ore-forming fluids. The authors think that this is probably the main reason why those In-rich deposits spread over the world are simultaneously enriched in tin.     

地电化学异常形成机理初探

一直以来,人们都倾向认为地电化学方法取得的异常是由其吸附的金属离子引起,文中通过多个矿区地电化学试验发现,电提取微量元素异常往往与Fe、Al等常量元素异常高度一致,而Fe、Al等常量元素是组成粘土矿物的主要成分. 进一步对地电化学泡塑样品开展扫描电镜观测,发现电提取后泡塑载体样品中存在大量的大小从数微米至数十微米的粘土矿物颗粒. 由此初步推断,当前所使用的地电化学方法取得的异常很大程度上是由土壤中存在的具有电活动性的极细粒粘土矿物颗粒引起,地电化学提取过程对这些粘土矿物颗粒具有选择性吸附.     

拉萨市夏季大气降尘单颗粒矿物组成及其形貌特征

应用带能谱的电子扫描电镜(SEM-EDX)对拉萨市夏季正常天气下收集的大气自然沉降气溶胶样品进行分析,研究了拉萨市大气降尘矿物组成和各种物相形貌特征信息。拉萨市大气颗粒物含有硅酸盐颗粒、富钙颗粒、富铁颗粒、富碳颗粒(燃煤飞灰颗粒和燃油飞灰颗粒)和植物残体颗粒。根据颗粒物数量统计发现拉萨市大气颗粒物以硅酸盐颗粒为主,富钙颗粒和富铁颗粒次之,需要指出的是以燃油飞灰为主的富碳颗粒已占到一定比重,说明以燃油为主的机动车尾气对拉萨大气污染在加强。研究结果表明,大气降尘矿物成分及其形貌特征可以用作判定污染物来源的重要标志,拉萨大气中颗粒来源的多样性决定了治理措施也应综合进行。