Sedimentary cycles of trace elements in Salawusu River Valley since 150 ka BP

The paper makes some analyses on 11 trace elements in the Milanggouwan stratigraphical section in the Salawusu River valley, which is regarded as a prototype geology-palaeoclimate record since 150 ka BP. The results show that the content and variation of trace elements has experienced remarkably regular changes in the pace with coarse and fine sedimentary cycles of palaeo-aeolian sands to its overlying fluvio-lacustrine facies or/and palaeosols. The trace elements with chemical properties of relatively active (V, Sr, Cu, Ni, As) and relatively stable (P, Pb, Rb, Mn, Nb, Zr) are a manifestation of the corresponding 27 changeable cycles between peak and valley values, appearing a multi-fiuctuational process line of relative gathering and migration since then. The low numerical value distribution of these two types of trace elements in the aeolian sand facies represents erosion and accumulation under wind force during the cold-dry climate. Whereas their enrichments in both fluvio-lacustrine facies and palaeosols are related to the valley’s special low-lying physiognomic position between the Ordos Plateau and the Loess Plateau under the warm and humid climate conditions. The above relatively migrated and gathered change of the trace elements is the result of 27 climatic cycles of cold-dry and warm-humid, which is probably caused by repeated alternations of winter monsoon and summer monsoon in the Mu Us Sandy Land influenced by the climate vicissitudes in northern hemisphere during glacial and interglacial periods since 150 ka BP.     

The property, age and formation environment of the palaeokarst in Qinghai-Xizang Plateau

The karst landforms distributed on the Qinghai-Xizang (Tibet) Plateau can be genetically classed with the Tertiary underground karst, which were gradually exhumed to the surface with the uplift of the plateau during Quaternary period. The relative deposits of the Tertiary palaeokarst processes, such as the residuum and speleothem, were discovered recently in the southern and southeastern fringe areas of the plateau, where has geological-currently been disintegrated by the headward erosion processes of the modern river systems. The major chemical components of the clay portion of the residuum consist mainly of SiO2C, Al2CO3 and Fe2O3. The clay minerals composition of the clay portion belongs to illite-kaolinite pattern for most of the residuum samples, and kaolinite-illite pattern for a few of the samples. It can be judged from the silicic acid index and the clay minerals composition that the formation of the residuum of the Plateau was in its initial phase. However, such a lower chemical weathering index only reflected the weathering degree in the bottom or lower parts of the lateritic weathering crust. The relatively intensive chemical weathering processes of the surface layers of the lateritic weathering crust could be logically speculated. The surface feature textures of quartz grains in the residuum were formed mainly by the chemical erosion, which revealed a long-term humid-tropical environment when the residuum and the palaeokarst formed.     

塔里木河下游地下水位与水化学成分关联度排序分析

根据2001年塔里木河下游第四次生态输水前后地下水位、水质变化的监测和取样分析资料。运用灰色关联分析法。对塔里木河下游地表生态输水前、后的地下水位与地下水化学成分进行了关联分析。分析研究表明，生态输水对地下水质的影响比较明显。在关联排序中。阴离子的SO4^2-、Cl^-以及阳离子的Ca^2 、Mg^2 与地下水位变化的关联性较强；pH值与地下水位的关联度最低。仅为0．534；矿化度与地下水位关联度最高,达到0．863。     

某地平板玻璃原料用石英砂的提纯研究

某地石英矿砂通过磁选分离法、稀酸浸泡法处理后，矿砂不同程度地降低了铁、铝、钙镁的含量；采用磁选分离 稀酸浸泡法联合处理后，使该地石英砂的化学成分达到了优质的生产平板玻璃用硅质原料的国家标准。     

醋酸丁酯萃取-无火焰原子吸收法测定化探样品中痕量金

在KBr存在下,用小体积醋酸丁酯萃取金后,用无火焰原子吸收法测定化探样品中痕量金的分析方法较化学富集光谱法具灵敏度高(检出下限可达0.05×10-9)、精度好、简便快速、成本低等优点.通过批量化探样的检验,证明该方法足已满足化探样品对金的测定要求.     

青海锡铁山热水沉积型铅锌矿床的地球化学特征

通过对锡铁山铅锌矿床的围岩(矿石)化学成分、稀土及微量元素特征的研究，发现矿区地层普遍具有铈负异常(δCe=0．47～0．90)，为海相沉积岩，近矿围岩中Ag、Hg、As、Sb、Ba等热水沉积指示元素偏高，显示成矿流体性质为热卤水，矿区火山岩不发育，矿床类型可以划为Sedex型。     

不对称抽道集共反射面元叠加方法探讨

总结不对称抽道集共反射面元叠加方法的工作经验，提出自由观测面自由反射界面不对称抽道集共反射面元叠加方法的处理思路和计算方法。在自由观测面的条件下，反射界面可分为简单倾斜平面、规则曲面和自由反射界面三种情况，针对不同情况讨论共反射面元的叠加方法。综合一般情况下的共反射面元叠加方法，提出了“鳞片法”的处理思路。     

用双孔热解石墨管原子吸收法测定微量金

石墨炉原子吸收法在对化探样品微量金的测试过程中存在因载气进入而使待测样品溅出的问题。利用自制的双孔热解石墨管代替普通石墨管可解决上述问题。通过大量的实验证明,仪器在最佳工作条件下,硫脲介质浓度10g·l-1、解脱时间40min时,获得检出限0 10×10-9、加标回收率为98 4%～103 7%的分析结果。     

单道扫描电感耦合等离子体发射光谱法测定珊瑚礁中主量和微量元素

建立了用单道扫描电感耦合等离子体发射光谱法测定珊瑚礁中主量和微量元素的方法。珊瑚礁样品经酸溶解后,直接进行Ca、Mg、K、Na、V、Sr、Ba、Co、Ni、Pb、Li、Rb的测定,方法检出限为0.0004～0.1mg/L,精密度RSD<5%(n=6),样品的加标回收率为97%～105%。测定w(CaO)为50%的样品,结果与传统的EDTA容量法相符。方法经碳酸盐岩石国家一级标准物质验证可行,已用于大批量的珊瑚礁样品的测定。