中条山胡-篦铜矿区富硼气液脉岩的地质特征及有关问题

对中条山胡-篦铜矿区电气石(岩)的地质特征及有关问题进行研究的结果表明:电气石(岩)是与中元古代西阳河期中-基性火山喷溢作用有关的、主要以脉体形式普遍存在的中(偏低)温富硼气液活动的产物;“条纹状电气石岩”发育于矿区内所有具先存透入性面理岩石中,是变形变质期后富硼气液在此类面理化岩石中拟态定向充填交代所成的脉岩。     

电气石对成岩成矿环境的示踪性及应用条件

本文在系统查阅国内外文献的基础上，结合对我国部分地区电气石的研究，讨论了电气石在不同成岩成矿环境中的鉴别特征及应用条件。在以火山岩和以沉积岩为含矿岩石的块状硫化物矿床中，电气石通常为富镁的镁电气石－黑电气石固溶体系列。在花岗岩、伟晶岩和细晶岩中，电气石有镁电气石－黑电气石固溶体系列→黑电气石－锂电气石固溶体系列→锂电气石和镁电气石－黑电气石固溶体系列→黑电气石电两个方向。此外，还提出了应用电气石指     

TiO2/电气石复合物的光催化性能

采用溶胶-凝胶法制备TiO2/电气石复合光催化剂,通过光降解甲基橙实验考察复合光催化剂的活性,发现复合物中2%电气石的制备比例就可以显著提升TiO2降解有机物活性,降解率(0.5h)达99.87%,明显优于纯TiO2(0.5h)83.64%,提高了约20%。经XRD、BET、SEM等手段对样品进行分析得知:经800℃以下长时间热处理,电气石的结晶构造不变;900℃热处理使电气石结构破坏。SEM分析显示复合物中TiO2颗粒呈球簇状,均匀包覆在电气石表面形成颗粒膜层。     

江西相山铀矿田含铀碎斑熔岩中电气石化学成分及硼同位素组成特征

相山铀矿田是我国最大的火山岩型铀矿田,其赋矿围岩主要为流纹英安岩、碎斑熔岩和部分前寒武纪变质岩和中生代花岗斑岩。碎斑熔岩的边缘亚相中发育直径10~20 cm的球形电气石囊包,其主要的矿物组合为电气石、石英以及少量长石、萤石,伴生少量晶质铀矿,另可见电气石交代早期的长石。利用显微镜、电子探针、激光剥蚀多接收等离子质谱仪等分析仪器,对相山如意亭地区碎斑熔岩中电气石囊包进行了详细的矿物学研究工作。电子探针成分分析显示,碎斑熔岩中电气石为典型的黑电气石,以富含Na、Fe等元素为特征,电气石中挥发性组分较高;其中,B₂O₃质量分数为9.38%~10.04%,F质量分数为0.10%~1.77%。成矿流体中高质量分数的B、F等挥发性组分及岩浆早期阶段的较高氧逸度环境使得U元素更易形成络合物,更利于U的迁移与富集。利用LA-MC-ICP-MS硼同位素微区原位分析法对碎斑熔岩中电气石的硼同位素进行分析测试,结果显示,电气石中的δ¹¹ B质量分数为（-13.15±0.72）‰~（-12.28±0.63）‰,均值为（-12.72±0.94）‰,指示相山火山-侵入杂岩体主要来源于相山底部地壳基底岩石的部分熔融。     

西藏西南普兰错果弄巴电气石二云母花岗岩SHRIMP锆石U-Pb定年

采用SHRIMP定年方法,测得错果弄巴花岗岩206Pb/238U年龄为(16±0.5)Ma。定年结果反映了岩浆从地壳深部快速上升的绝热降压变质事件形成于印度板块与欧亚板块挤压碰撞后的构造隆升环境,与喜马拉雅造山带大规模的逆冲推覆构造作用、伸展拆离作用和淡色花岗岩侵位同步,说明该区花岗岩经历了多期变质和复杂的地质演化过程。作者认为(16±0.5)Ma可以定为错果弄巴花岗岩体的最终侵位时间。     

DiamondView^TM在有机充填碧玺鉴定中的应用

目前主要通过放大检查和红外光谱分析等测试方法对有机充填碧玺进行鉴定,但它们在准确性和直观性方面还存在一些问题。为弥补现有方法的不足,利用DiamondView^TM荧光成像技术对有机充填处理的碧玺样品进行研究。结果显示,在DiamondView^TM下碧玺样品呈绿色或蓝色荧光,部分样品可观察到生长结构特征。分布于碧玺裂隙及凹坑内的有机充填物呈较强的蓝白色荧光,并与碧玺的荧光具有明显的差异和界限。利用DiamondView荧光图像分析,可以快速准确地识别充填物的位置及分布,也为碧玺在充填程度等方面的研究提供了新的思路。     

电气石硼肥制作技术的试验研究

硼元素是农作物生长所需的七种微量元素之一。目前给土壤补充硼元素的主要方式是施硼肥(来自硼砂矿),随着硼砂矿资源的日益减少,寻找硼替代资源日渐紧迫。笔者认为,电气石是可替代硼砂的主要矿物之一。利用电气石中硼的关键是将电气石中的硼变为可溶性硼。实验表明,高温焙烧法对电气石中硼的溶出非常有限,而用添加HF等助剂的化学法将电气石中的硼活化溶出的方法,效果较好。因此,可通过化学法先将电气石中的硼元素溶出,然后再加入部分电气石及辅料来制作电气石硼肥。     

电气石红外光谱和红外辐射特性的研究

精确测试和研究了不同种属电气石的红外光谱特征及不同种属、不同温度条件下热处理电气石的红外辐射特性。结果表明：电气石具有高红外发射率的本质在于其晶体结构中的分子振动具红外活性;铁、镁电气石红外发射率相近,且都大于锂电气石的红外发射率;电气石热处理的温度与红外发射率之间存在一定的对应关系,随着热处理的温度的增加,红外发射率减小,当温度增大到800℃红外发射率达到最大值,超过900℃,电气石开始分解,红外发射率开始下降;电气石在室温下最大单色辐出度相应的波长为9~10μm 与绝对黑体9.72 μm 吻合较好,为良好的红外吸收与发射材料。     

Provenance of the Ordovician–lower Silurian Tumblagooda Sandstone,Western Australia

Detrital zircon U–Pb ages and heavy mineral assemblages provide conflicting evidence of the provenance of the Ordovician–lower Silurian Tumblagooda Sandstone, a fluvial to shallow marine, red-bed succession over 2000 m thick, within the northern Perth and Southern Carnarvon basins in Western Australia. Tourmaline composition indicates a main provenance from interior continental terranes dominated by ‘Li-poor granitoids, pegmatites and aplites’ and ‘Ca-poor metapelites, metapsammites and quartz-tourmaline rocks,’ akin to the Yilgarn Craton to the east of outcrop of the Tumblagooda Sandstone. Other possible source areas include orogens mostly to the south but lack tourmaline analyses for comparison. Taking into account the lack of garnets—a conspicuous component of the adjacent Proterozoic Northampton Inlier—the limited zircon data are compatible with the Albany–Fraser and Pinjarra orogens along the southern and western margins of Australia and/or terranes in or adjacent to East Africa and/or Antarctica, as ultimate source regions with a minor contribution from the Yilgarn Craton, as with other Phanerozoic strata in Western Australia. Whereas the textural and mineralogical maturity of the sandstone could be explained by derivation from such regions, it is more likely that the source was relatively local and that the sediment passed through several phases of reworking. The main source of ilmenite and hematite, by comparison, may have been mafic–ultramafic rocks and/or banded iron formations within the Archean Yilgarn Craton to the east or the Pilbara Craton to the northeast, mobilised by acidic meteoric waters. Iron oxides forming the earliest cements may have been derived from the oxidation of detrital hematite and ilmenite grains concentrated along some bedding laminae or transported in solution from beyond the zone of deposition. Whereas the detrital iron oxides most likely come from the craton to the east of outcrop of the Tumblagooda Sandstone, the sand grains appear to have originally come from a relatively local orogenic source.     

Geochemical and Boron Isotopic Evidence that Tourmaline Records Country Rock Assimilation of Leucogranites in the Himalayan Orogen

Tourmaline geochemical and boron(B)isotopic compositions in two-mica granites(TMG),tourmaline-bearing leucogranites(Tou-LG),tourmalites and metapelites from the Gyirong-Malashan areas of the Himalayan orogen provide evidence for country rock assimilation during the intrusion of Himalayan leucogranite.The schorls in Gyirong leucogranitic plutons show low contents of MgO(0.238%-1.160%)and δ¹¹B values(-12.1‰--11.2‰),while dravites gathered in the contact zone between the leucogranitic veins and metapelites show high contents of MgO(4.815%-6.755%)and δ¹¹B values(-10.7‰--9.3‰).This geochemical and isotopic variation of tourmalines can also be identified in the Malashan gneiss dome.As a result,three types of tourmaline were identified in the Himalayan orogen:(1)Tou-Ⅰ in the TMG and Tou-LG,which is the most common tourmaline type of schorl;(2)Tou-Ⅱ(dravite and high-Mg schorl)in the Tou-LG and tourmalite at the margins of the leucogranite;and(3)Tou-Ⅲ(mainly dravite,with minor high-Mg schorl)in metapelites of the High Himalayan Crystalline Sequence.The lenses and veins of Tou-LG may have experienced metasomatism and assimilation as a result of interaction with the High Himalayan Crystalline Sequence metasedimentary country rocks,which can be traced by the geochemical and isotopic characteristics of the tourmaline therein.