新疆阿尔泰彩色电气石的颜色成因研究

彩色碧玺（彩色电气石）是新疆阿尔泰花岗伟晶岩中富有特色的一种名贵宝石，主要有碧绿、黑绿、黄绿、红色和玫瑰色碧玺。通过对彩色电气石的岩石化学分析、Ｘ－衍射、紫外可见光吸收光谱和穆斯鲍尔谱测试分析，结合宏观地质观察，认为阿尔泰宝石级彩色电气石Ａｌ２Ｏ３含量高（＞４０％）而铁（锰）含量低，形成于碱性介质环境，多出现在钠锂型伟晶岩或钠长石富集地段。彩色电气石的颜色与晶体格架中配位金属离子种类、含量、物理特征及其生长阶段等因素有密切关系。铁、锰和锂离子是致色原因之一；微量元素，过渡性致色离子的存在与含量的高低也是造成电气石多色的原因之一     

云南大丫口祖母绿矿床中电气石的地球化学特征及其对成矿的指示意义

祖母绿是由微量Cr和/或V致色的绿色绿柱石.位于云南省麻栗坡县的大丫口祖母绿矿床是中国重要的祖母绿矿床,近年来取得了一系列的研究进展,但与祖母绿相关的电气石的研究工作还未展开.本文以大丫口矿床含祖母绿矿脉和非矿脉中的电气石为研究对象,在详细的野外调查和岩相学研究基础上,对电气石进行成分测试,旨在探讨电气石成因、查明物质...     

云南个旧锡多金属矿集区电气石地球化学组成和硼同位素特征——对成矿流体性质和演化的约束

个旧锡矿集区发育与晚白垩世髙分异花岗岩有关的世界级Sn-Cu多金属矿床, 其成矿物质的来源及流体演化过程一直是研究的热点和难点。个旧地区电气石广泛发育于碳酸盐岩、花岗岩及矽卡岩中, 但对电气石尚未进行系统研究, 电气石与成矿之间的关系尚未明确。本文对不同类型电气石开展了系统的岩相学观察和电子探针(EPMA)、LA-ICP-MS微量元素和硼同位素分析。结果表明, 所有电气石都属于碱性电气石, TurⅠ、TurⅡ、TurⅣ为热液成因, TurⅢ为岩浆成因。岩浆电气石相比于热液电气石具有更低的Mg、Ca等元素, TurⅠ电气石高含量的Sr表明受到了围岩的混染。电气石的微量元素变化表明, 从似斑状花岗岩到等粒花岗岩, 随着岩浆分异程度逐渐增加, Sn在岩浆中逐渐富集, 在似斑状花岗岩和接触带矽卡岩中沉淀卸载。个旧不同类型电气石具有均一的δ11B值(?15.2‰ ~ ?12.8‰), 与花岗岩的组成范围一致, 表明成矿物质来源均来源于花岗质岩浆。     

南极中山站区电气石及其与变质作用的关系

南极中山站区的巨晶“电气石”实际上是柱晶石。电气石的确存在,但颗粒细小,含量较低。根据其颜色、成分和产出特征,至少可分为三种类型,不同的电气石与变质作用发展的不同阶段有关。电气石在麻粒岩相变质作用条件下能够稳定存在,与其它硼硅酸盐矿物（即硅硼镁铝矿和柱晶石）的缓冲作用有关。     

青海尕林格铁矿床电气石矿物学、元素地球化学及成因研究

尕林格矽卡岩型铁多金属矿床位于青海东昆仑祁漫塔格造山带与柴达木盆地结合带中部。电气石作为矿区内普遍出现的矿物,部分呈半自形-自形粒状出现在正接触带矽卡岩化蚀变火山岩中(Tour-Ⅰ),也有呈他形粒状形式出现在外接触带变质砂岩中(Tour-Ⅱ)。因其生长化学行为与寄主岩石和流体的化学属性强烈相关,所以电气石的主、微量元素成分为研究热液体系背景下的流体演化及成矿物质来源提供了渠道。尕林格电气石的化学成分包括富Na-Mg的镁电气石和富Ca-Mg的钙镁电气石。Tour-Ⅰ中的环带电气石存在早期核部(Gen-1)被晚期边部(Gen-2)交代的不连续反应边特征。Gen-1为钙镁电气石,而Gen-2为镁电气石。由于镁铁质火山岩的缓冲作用,Gen-1更多地显示出原地寄主岩石的化学成分。随着流体的持续补充,Gen-2则更多地与流体成分保持平衡,显示出较窄的变化范围,与成矿密切相关。Gen-1比Gen-2更加富Fe,意味着流体中Fe浓度降低;而Na含量逐渐上升则暗示流体p H值的升高。尕林格绝大部分矽卡岩电气石都是在早期成核阶段结晶生长的,因为电气石在酸性和中酸性溶液中更加稳定。除此之外,部分Tour-I中还存在沿早期电气石颗粒边缘生长的增生边结构(Gen-3)。Gen-3比Gen-1更加富Ca,推测Gen-3是在相对封闭环境下颗粒间隙溶液作用下的产物。Tour-Ⅱ则既包括钙镁电气石,又含有镁电气石。在Tour-Ⅰ中,Fe和Mg的含量变化范围较大,这与实际观测的Tour-Ⅰ围岩为镁铁质中-基性火山岩密不可分。Tour-Ⅱ比Tour-Ⅰ更加富集B、Ti、Sc、V、Cr、Ga、LREE等元素,这与B的溶解度随流体p H值的升高而升高有关。随着岩浆演化流体p H值的升高,B在相对碱性溶液中大量富集,而大部分微量元素和LREE易与挥发分结合成络合物的形式迁移,因此,B含量高的溶液中部分微量元素和稀土元素含量也会升高。     

The nature and origin of brecdation and mineralization at the White Crystal ore deposit,Ardlethan tin mine,New South Wales

The White Crystal ore zone consists of an ovoid mass of fine grained quartz‐tourmaline topaz rock containing disseminated cassiterite together with prominent vughs of quartz and/or tourmaline, cassiterite, and sulphides. Toward the margins of the ore zone the decreasing intensity of alteration illustrates formation via a process of brecciation, infill, and alteration. The rectangular slab‐like fragments are commonly aligned and their plunge indicates a dip towards a common epicentre. The tourmalinized ore zone is surrounded by successive zones of sericitization and argillization. The brecciation is of large scale tensional origin which is suggestive of collapse. Beneath the ore zone mineralization/alteration continues at subeconomic grades and limited data suggests an intrusive hydrothermal style of brecciation. The entire system is a form of breccia pipe and has yielded some 1.5 Mt of ore at around 0.64% Sn.     

碧玺自发极化效应的环境应用以及人体保健作用

碧玺是一种色彩丰富倍受青睐的宝石,同时也可以作为环境矿物用来治理环境.碧玺具独特的自发极化现象,具有表面电场,可以电解水、吸附带电离子、释放空气负离子.这些独特的性质赋予碧玺治理环境的用途,例如吸附污水中重金属离子、降解有极大分子污染物等.人体佩戴碧玺时,这种自发极化现象也会带来一定的保健功效,具有一定的电磁屏蔽效果,促进人体新陈代谢.     

六块地—厢房硫铁矿地质特征及找隐盲矿方法探讨

六块地—厢房矿区的硫铁矿矿体,受下元古界辽河群里尔峪组二段:浅粒岩、变粒岩控制,以电气变粒岩为顶底标志。绿帘石化和绿泥石化为矿体是近矿蚀变,范围较小。电气石化范围广,是较好的找矿标志。利用黄铁矿的热电性确定矿体部位和矿化富集趋势。     

电气石中硼的溶出机制初探

电气石是一种以含硼为特征的硅酸盐矿物,矿物中硼含量在2.78%~3.4%之间,但电气石中的硼被束缚在稳定的晶体结构中难以溶出而被植物吸收,从而影响电气石中硼在农业上的应用。本文通过一系列实验与检测分析,对电气石中硼的溶出机制进行了研究,发现＂高温煅烧十活化剂＂相结合的方法能有效地将电气石中硼的溶出,并初步选定Na2CO3为理想的活化剂,为开发电气石硼肥奠定了理论基础。     

Tourmaline breakdown in the migmatite zone of the Ryoke metamorphic belt,SW Japan

A sharp line delimitating the distribution of tourmaline (termed as a ‘tourmaline‐out isograd’) is defined in the migmatite zone of the Ryoke metamorphic belt, Japan. The trend of the tourmaline‐out isograd closely matches that of the isograds formed through the regional metamorphism, suggesting that it represents the breakdown front of tourmaline during regional metamorphism. This is confirmed by the presence of the reaction textures of tourmaline to sillimanite and cordierite near the tourmaline‐out isograd. The breakdown of tourmaline would release boron into associated melts or fluids and be an important factor in controlling the behaviour of boron in tourmaline‐bearing high‐temperature metamorphic rocks. Near the tourmaline‐out isograd, large tourmaline crystals occur in the centre of interboudin partitions containing leucosome. In the melanosome of the intervening matrix, reaction textures involving tourmaline are locally observed. These observations imply that tourmaline breakdown is related to a melting reaction and that the boron in the leucosome is derived from the breakdown of tourmaline in the melanosome during prograde metamorphism. Boron released by tourmaline breakdown lowers both the solidus temperature of the rock and the viscosity of any associated melt. Considering that the tourmaline‐out isograd lies close to the schist–migmatite boundary, these effects might have enhanced melt generation and segregation in the migmatite zone of the Ryoke belt. The evidence for the breakdown of tourmaline and the almost complete absence of any borosilicates throughout the migmatite zone suggest that boron was effectively removed from this region by the movement of melt and/or fluid. This implies that the tourmaline‐out isograd can reflect a significant amount of mass transfer in the anatectic zones.