Distribution of cadmium, chromium, copper, lead and zinc in marine sediments in Hong Kong waters

Partitioning of heavy metals (Cd, Cr, Cu, Pb, Zn) in marine sediments collected from various sites in Hong Kong waters were determined using sequential extraction method. Sediments from Kellette Bank, located in Victoria Harbour, had higher metal concentrations especially Cu and Zn than most other sites. Slightly over 20% of total Cu and Cr existed as readily available forms in Peng Chau and Kellette Bank. At most sampling sites, over 15% of the Cu existed as the exchangeable form indicating that Cu could be readily released into the aqueous phase from sediments. A significantly higher percentage of Pb and Zn was associated with the three non-residual fractions. Hence, there is a greater environmental concern for remobilization of Pb and Zn compared with Cr. The high amount of residual Cd (>50%) and the relatively lower Cd content indicate that little environmental concern is warranted for the remobilization of Cd. Distribution of metals in sediments collected from different depth at Kellette Bank shows that metal concentrations decreased with profile depth. The levels of Pb and Zn associated with the two readily available fractions increased sharply in the surface sediment. These metals represented the pollutants, which were introduced into the area in the mid-eighties through early nineties as a result of rapid economic and industrial development in the territory. As significant portions of these metals were bound to the readily available phases in the surface sediments, metal remobilization could be a concern. An erratum to this article can be found at     

Retrieval of stratospheric O3 and NO2 vertical profiles using zenith scattered light observations

Daily zenith scattered light intensity observations were carried out in the morning twilight hours using home-made UV-visible spectrometer over the tropical station Pune (18‡31′, 73‡51′) for the years 2000–2003. These observations are obtained in the spectral range 462–498 nm for the solar zenith angles (SZAs) varying from 87‡ to 91.5‡. An algorithm has been developed to retrieve vertical profiles of ozone (O₃) and nitrogen dioxide (NO₂) from ground-based measurements using the Chahine iteration method. This retrieval method has been checked using measured and recalculated slant column densities (SCDs) and they are found to be well matching. O₃ and NO₂ vertical profiles have been retrieved using a set of their air mass factors (AMFs) and SCDs measured over a range of 87–91.5‡ SZA during the morning. The vertical profiles obtained by this method are compared with Umkehr profiles and ozonesondes and they are found to be in good agreement. The bulk of the column density is found near layer 20–25 km. Daily total column densities (TCDs) of O₃ and NO₂ along with their stratospheric and tropospheric counterparts are derived using their vertical profiles for the period 2000–2003. The total column, stratospheric column and tropospheric column amounts of both trace gases are found to be maximum in summer and minimum in the winter season. Increasing trend is found in column density of NO₂ in stratospheric, tropospheric and surface layers, but no trend is observed in O₃ columns for above layers during the period 2000–2003     

基于广义Hough变换的不规则形状目标提取方法

提出了一种基于广义Hough变换的不规则形状目标的提取方法。该方法主要包括目标参数描述和目标提取两部分。实验表明，该方法精度好、效率高。     

基于全站仪的圆形建筑物倾斜观测的方法和精度

随着建筑物的不断增高、增大,其稳定性和可靠性成为人们关注的焦点.其中建筑物的倾斜度是衡量施工技术质量的重要指标之一.而传统的观测方法如经纬仪测小角法、经纬仪投点法,由于受仪器精度和观测条件的限制,观测精度较低.拓普康全站仪独具推出的圆柱偏心测量功能为快速、准确测定圆形建筑物的倾斜量开辟了一条新途径,本文阐述了基于全站仪的圆形建筑物倾斜观测的原理和方法,并对其精度进行分析.     

超声与振荡提取沉积物中松散结合态磷的比较

用超声技术提取沉积物样品中松散结合态磷,并与振荡提取结果进行比较。结果表明,超声提取结果与振荡提取结果大致相当。超声提取耗时短,操作简单易行,测试结果精密度为3.8%(RSD,n=7),可以替代振荡方法提取沉积物中的松散结合态磷。     

吐哈盆地十红滩铀矿床水文地球化学特征

本文根据水化学资料的研究,探讨了十红滩铀矿床含矿含水层高矿化度地下水的成因,分析了高矿化度水对铀溶解迁移的影响及碳酸盐的形成机理.     

条带开采煤柱稳定性的试验模拟与数值分析——以山东省济宁市太平煤矿为例

以山东省济宁市太平煤矿为例，采用煤柱模拟试验和数值分析手段，对薄基岩条带开采时所留设煤柱的应力应变状态、煤柱强度结构及煤柱长期稳定性进行了深入的分析与研究，揭示了煤柱稳定性及煤柱应力分布与条采尺寸、采出率、覆岩特征的相互关系，进行了条带煤柱的稳定性评价，为工程实践提供了理论依据。     

饱和烃经5à分子筛络合前后单体烃碳同位素分析对比研究

通过对自配标准样品(正构烷烃)进行5à分子筛吸附试验,测定了用5分子筛吸附法分离前后正构烷烃、异构烷烃和环烷烃碳同位素值,探讨试验前后碳同位素值的变化。尽管实验过程中样品经过85℃长时间加热回流及吸附样品的5à分子筛用氢氟酸酸化处理,但实验结果经仪器检测,证明该方法对正构烷烃碳同位素值影响因素不大。本文还介绍了原油和煤可溶有机质中饱和烃络合前后的单体烃碳同位素分析方法。并在前人工作的基础上,改进采用微型索氏抽提加热回流实验装置,既提高了样品的回收率,也减少了样品中轻组分的损失。     

Numerical evaluation of the damping‐solvent extraction method in the frequency domain

The damping‐solvent extraction method for the analysis of unbounded visco‐elastic media is evaluated numerically in the frequency domain in order to investigate the influence of the computational parameters—domain size, amount of artificial damping, and mesh density—on the accuracy of results. An analytical estimate of this influence is presented, and specific questions regarding the influence of the parameters on the results are answered using the analytical estimate and numerical results for two classical problems: the rigid strip and rigid disc footings on a visco‐elastic half‐space with constant hysteretic material damping. As the domain size is increased, the results become more accurate only at lower frequencies, but are essentially unaffected at higher frequencies. Choosing the domain size to ensure that the static stiffness is computed accurately leads to an unnecessarily large domain for analysis at higher frequencies. The results improve by increasing artificial damping but at a slower rate as the total (material plus artificial) damping ratio ζ_t gets closer to 0.866. However, the results do not deteriorate significantly for the larger amounts of artificial damping, suggesting that ζ_t≈0.6 is appropriate; a larger value is not likely to influence the accuracy of results. Presented results do not support the earlier suggestion that similar accuracy can be achieved by a large bounded domain with small damping or by a small domain with larger damping. Copyright © 2002 John Wiley & Sons, Ltd.     

厚层覆盖区综合物化探方法找金试验研究——以广西兴安金石金矿为例

在兴安金石金矿外围 4号分散流异常区 ,通过地电化学提取金测量法 ,查明测区存在 5个走向规模小于 5 0 m的金异常区 ,W( Au) 最大值为 72 .4× 10 - 9,高出背景值十几倍 ,并藉综合土壤吸附汞测量 ,高精度磁测和激发极化法等多种物化探方法来确定这些异常区的地质、地球化学和地球物理特征 ,提出金矿成矿的有利部位在金的地电提取高异常区、高汞量异常区、高磁性异常区、低视电阻率异常区和中等视极化率异常区的“三高一低一中”的找矿模式。确定测区的北北东角 (右下角 )一带具备有利的金矿成矿条件