江西省会昌县淘锡坝大型锡矿床构造控矿机制探讨

淘锡坝锡矿床是近年探明储量达大型的锡矿床,是一种新的锡矿类型-隐爆层间裂隙带型。文章介绍了该矿床的地质特征和矿化特征,对矿区的构造进行了重点解剖,对构造控矿机理进行了探讨,提出火山机构及北东向断裂是矿区的控岩构造,控制了白垩纪成矿花岗岩体的侵入就位。而火山岩中大范围的隐爆层间裂隙带是良好的容矿构造,矿体赋存其中呈似层状,局部膨大形成厚达数十米的＂锡矿包＂。通过研究构造与矿化富集的内在联系,总结了该矿床的成矿规律。     

水浴消解-顺序注射-氢化物发生原子荧光光谱法测定铁矿石中砷和汞

采用水浴加热低温消解浸取铁矿石样品,顺序注射-氢化物发生原子荧光光谱法测定铁矿石样品中砷和汞的含量.选择了消解试剂,研究了硼氢化钾浓度、载气流量、屏蔽气流量、溶液酸介质、载流、溶液酸碱比例、样品中的主要基体元素等因素对砷和汞测定的干扰,并确立了适宜的测定条件.砷浓度在0～100 μg/L与荧光强度呈良好的线性关系,砷的...     

长江三角洲表层土壤Sn元素的空间分布特征 及影响因素

对长江三角洲地区表层土壤Sn含量的空间分布特征进行分析,发现土壤平均含Sn量为8.35mg/kg,远远高于全国A层土壤Sn的背景值2.6mg/kg,表层土壤中Sn空间分布不均匀,呈现由苏锡常、宁镇扬、杭嘉湖、宁绍等经济带增高的趋势。各种沉积环境、土壤类型中Sn的含量也较全国类似或同类沉积环境、土壤类型中Sn的含量高,显示了高背景的特点。人类活动影响强烈区表层土壤中Sn元素富集明显,90.39%的面积区表现出富集的特征,富集系数大于2的强富集区面积占44.03%。另外,Ag、Bi、Hg、P、Pb、Sb、Se、TOC等也与土壤Sn呈相关性,可能与土壤Sn的富集有成因联系。     

The origin of tin deposits in the Mount Wells region,Pine Creek Geosyncline,Northern Territory

Tabular steeply dipping cassiterite‐bearing lodes in the Mount Wells region are hosted by lower greenschist fades metasediment of the Pine Creek Geosyncline within the contact aureole of late orogenic granitoids. The latter are predominantly I‐type, but S‐type phases are developed near the sediment‐granitoid contact.

Quartz, cassiterite, pyrite, arsenopyrite, chalcopyrite and pyrrhotite are the main minerals. Two types of lodes are present: (i) Sn‐quartz lodes containing 5–10 vol% sulphide minerals; and (ii) Sn‐sulphide lodes containing ～ 70 vol% sulphide minerals. At the surface, the former appear as normal quartz veins and the latter as hematite‐quartz breccia resulting from the collapse of original sulphide‐rich lodes as a consequence of volume reduction due to oxidation and leaching.

Two stages of quartz veining are recognized in both types of lodes. Cassiterite is present in stage I while stage II is composed of barren quartz with minor pyrite. Late stage III carbonate veinlets are present in Sn‐sulphide lodes. The lode‐wallrock contact is sharp with weak alteration effects confined to the fringe of the lodes. The alteration minerals include sericite, quartz, tourmaline, chlorite, pyrite and minor K‐feldspar.

Four types of fluid inclusions are present in vein quartz and cassiterite: Type A (CO₂ ± H₂O ± CH₄); Type B (H₂O+～ 20% vapour); Type C (H₂O+ < 15% vapour) and Type D (H₂O+ < 15% vapour + NaCl). Early ‘primary’ inclusions represented by Types A and B are present in stage I only and have a well‐defined temperature mode at ～300°C and a salinity range of 1–20 wt% eq NaCl. Types C and D inclusions are ‘secondary’ in stage I and primary in stage II and have a temperature mode at 120–160°C and salinities from about 1 to more than 26 wt% eq NaCl. Variable H₂O‐CO₂ ratios of Type A inclusions and homogenization in CO₂ or H₂O phase at near identical temperature indicate entrapment at the H₂O‐CO₂ solvus and define a pressure of ～ 100 MPa. The melting sequence of frozen inclusions suggests that the ore fluids were mainly H₂O‐CO₂‐CH₄‐Na‐Ca‐Cl brines. This is also confirmed by Raman Laser Spectrometry.

Oxygen and sulphur isotope data are consistent with a magmatic origin of the ore fluids. The δD values are up to 20%0 higher than those expected for magmatic fluids and probably resulted from interaction of the latter with the carbonaceous strata. This interpretation is supported by δ¹³C data on the fluid inclusion CO₂.

Fluid inclusions, stable isotope and mineralogical data are used to approximate the physico‐chemical parameters of the ore fluids which are as follows: T 300°C, m Cl～2, fO₂ ～ 10^‐35, mSS ～ 0.01, Sn ～ 1 ppm, Cu ～ 1 ppm and pH ～ 5.5.

It is suggested that fluids of granitic parentage interacted with the enclosing sediment and picked up CO₂, CH₄ and possibly Ca. The granitic phases became reduced due to this interaction and developed S‐type characteristics. Tin was probably partitioned into the CH₄‐bearing reduced fluids. At some stage the fluid overpressure exceeded the lithostatic lode enforcing failure of the carapace and the intruded rocks by hydraulic fracturing causing CH₄ and CO₂ loss resulting in the precipitation of the ore minerals.     

南岭锡矿调查评价主要进展及找矿前景分析

南岭地区是我国南方有色、稀有、稀土和贵金属矿产的重要资源基地,是“十五”期间国土资源大调查矿产资源调查评价工作重点部署区之一。通过中国地质调查局的精心组织和各项目承担单位的共同努力,取得了较好的找矿成果：已初步控制(333 3341)锡资源量150万吨：新发现矿产地22处,其中大型锡1处,中小型锡18处,大型铅锌1处,中小型金2处。     

云南个旧锡矿的玄武岩成矿

个旧锡矿产于个旧东区,是一个以锡铜为主的超大型多金属矿床,具有火山沉积成矿的某些特征。因遭受燕山期花岗岩的叠加改造,区内个旧组卡房段中玄武岩遭受强烈的变质,它又具有花岗岩热液成矿的特征。区内玄武岩的地质地球化学特征表明,印支期玄武岩中的Sn、Cu、Pb、Zn、Ag和Au的质量分数大多数高于世界玄武岩平均值的若干倍;矿石硫化物的硫同位素δ³⁴S为-1.5‰~4.0‰,平均+0.207‰,在幔源硫附近;铅同位素模式年龄分为两组：第一组为180~240 Ma,反映了印支期的火山沉积成矿作用;第二组为80~140 Ma,反映了燕山期花岗岩的叠加改造成矿作用。区内印支期玄武岩为个旧锡铜多金属矿床的形成提供了主要的成矿物质,与成矿有直接联系。     

氢化物原子荧光光谱法测定富马酸中的砷

用氢氧化钠溶液分解富马酸使其转化为水溶性富马酸钠 ,然后用氢化物发生 -原子荧光光谱法测定了试样中的砷。方法的检出限为 0 .2 μg/L ,对富马酸中As的测定结果与国标法结果相符 ,对w(As) =1 .5× 1 0 - 6的试样测定 1 2次 ,RSD为 4.8% ,加标回收率为 97.9%～ 1 0 7.5%。     

辉钼矿中微量锡的分离与测定

报道了在强碱性介质中用钡盐以钼酸钡形式沉淀大量Ｍｏ（Ⅵ）,使微量锡与大量钼分离,过量钡用碳酸盐清除。深液中残余的少量钼用Ｈ２Ｏ２掩蔽,从而实现了大量钼存在下微量锡的光度法测定。方法已用于辉钼矿中微量锡的测定,结果与国标法杆符,加标回收率在９４％～１０５％,８次测定的ＲＳＤ≤３．３％。     

块金成因新见及其分级

本文描述了块金的形成新机制。在热液中呈金氢化物、金羰基化合物及纳料金粒子、纳米金合金粒子活化迁移。在表生条件下,金硫代硫酸盐配合物、金粒子、金合金粒子是金迁移的主要形式。块金是地质的、化学的、物理的、生物化学的综合作用的结果。按块金成因分为内生块金和次生块金。按单块块金质量分为４级。     

分形理论在云南个旧锡矿遥感信息定量化分析中的应用

应用分形理论和方法对个旧锡矿遥感信息进行了定量化研究.结果显示,在格子边长为1.4～4.5 km的标度范围内,其遥感蚀变和断裂构造进入的总格子数的对数与格子边长的对数均具有很好的线性相关性,表明在研究标度范围内,各子区遥感线性与蚀变信息具有良好的统计自相似性和分形特征.在此基础上,以19号区和26号区为例,分析并进一步探讨了遥感信息分形特征的成矿意义.