The optical features and hydrocarbon-generating model of “barkinite” from Late Permian coals in South China

Leping coal is known for its high content of “barkinite”, which is a unique liptinite maceral apparently found only in the Late Permian coals of South China. “Barkinite” has previously identified as suberinite, but on the basis of further investigations, most coal petrologists conclude that “barkinite” is not suberinite, but a distinct maceral. The term “barkinite” was introduced by (State Bureau of Technical Supervision of the People's Republic of China, 1991, GB 12937-91 (in Chinese)), but it has not been recognized by ICCP and has not been accepted internationally.In this paper, elemental analyses (EA), pyrolysis-gas chromatography, Rock-Eval pyrolysis and optical techniques were used to study the optical features and the hydrocarbon-generating model of “barkinite”. The results show that “barkinite” with imbricate structure usually occurs in single or multiple layers or in a circular form, and no definite border exists between the cell walls and fillings, but there exist clear aperture among the cells.“Barkinite” is characterized by fluorescing in relatively high rank coals. At low maturity of 0.60–0.80%R_o, “barkinite” shows strong bright orange–yellow fluorescence, and the fluorescent colors of different cells are inhomogeneous in one sample. As vitrinite reflectance increases up to 0.90%R_o, “barkinite” also displays strong yellow or yellow–brown fluorescence; and most of “barkinite” lose fluorescence at the maturity of 1.20–1.30%R_o. However, most of suberinite types lose fluorescence at a vitrinite reflectance of 0.50% Ro, or at the stage of high volatile C bituminous coal. In particular, the cell walls of “barkinite” usually show red color, whereas the cell fillings show yellow color under transmitted light. This character is contrary to suberinite.“Barkinite” is also characterized by late generation of large amounts of liquid oil, which is different from the early generation of large amounts of liquid hydrocarbon. In addition, “barkinite” with high hydrocarbon generation potential, high elemental hydrogen, and low carbon content. The pyrolysis products of “barkinite” are dominated by aliphatic compounds, followed by low molecular-weight aromatic compounds (benzene, toluene, xylene and naphthalene), and a few isoprenoids. The pyrolysis hydrocarbons of “barkinite” are mostly composed of light oil (C₆–C₁₄) and wet gas (C₂–C₅), and that heavy oil (C₁₅⁺) and methane (C₁) are the minor hydrocarbon.In addition, suberinite is defined only as suberinized cell walls—it does not include the cell fillings, and the cell lumens were empty or filled by corpocollinites, which do not show any fluorescence. Whereas, “barkinite” not only includes the cell walls, but also includes the cell fillings, and the cell fillings show bright yellow fluorescence.Since the optical features and the hydrocarbon-generating model of “barkinite” are quite different from suberinite. We suggest that “barkinite” is a new type of maceral.     

交流变频调速CD-2B型岩心钻机的研制

介绍了交流变频调速CD－2B型岩心钻机研制情况，技术参数，主要特点及型式检验，生产试验等情况。     

甘肃小柳沟钨多金属矿地质特征及成矿模式

小柳沟钨多金属矿于 90年代初发现 ,目前已具大型、超大型规模。共有 4个矿床。成矿主要与长城系朱龙关群和隐伏花岗岩有关。该矿床成矿物质来源具双重性 ,成矿温度为中高温 ,成矿流体为中等盐度 ,同位素计算模式年龄确定其成矿于加里东期。矿床成因属于火山喷发沉积—岩浆热液改造矿床。     

Propriétés fractales de la fragmentation et processus stochastiques de fracturation : approche géométrique 3D à l'aide du modèle ObsifracFractal properties of fragmentation and stochastic fracturing processes: geometrical 3D approach by OBSIFRAC model

A numerical rock fragmentation model was elaborated, producing a 3D puzzle of convex polyhedra, geometrically described in a database. In the first scenario, a constant proportion of blocks are fragmented at each step of the process and leads to fractal distribution. In the second scenario, division affects one random block at each stage of the process, and produces a Weibull volume distribution law. Imposing a minimal distance between the fractures, the third scenario reveals a power law. The inhibition of new fractures in the neighbourhood of existing discontinuities could be responsible for fractal properties in rock mass fragmentation. To cite this article: L. Empereur-Mot, T. Villemin, C. R. Geoscience 334 (2002) 127–133.     

可调滞回模型的磁流变阻尼器及其试验

本文在现在磁流变阴尼器性能研究的基础上，提出了可调滞回模型的磁流变阻尼器及其试验方法，并进行理论、试验及算例分析。首先，根据恒定电流下磁流变阻尼器的阻尼力滞力特性，利用磁流变材料特性的电流（即磁场）可控特点，建立了变电流下的阻尼力滞回模型；其次，在中通过电路板控制外加电流与装置变形间的函数关系，实现了变电流调节的阻尼力滞回模型；最后，将磁流变阻尼器与橡胶隔震装置结合，形成智能磁流变隔夺装置，并对一个单自由度隔震结构进行了数值仿真分析。     

2-D viscoelastic FEM simulation on stress state in the deep part of a subducted slab

Introduction It is found that there are some relationships between the thermal structures of subduction zones and the deep seismicity, while the mechanism relates the thermal structure and the deep seismicity is still unsure (Helffrich, Brodholt, 1991; Furukawa, 1994; Kirby, et al, 1996). From 1980s, geoscientists have constituted a series of numerical simulations on the stress states of subduction slabs. Based on the kinetic computation of Sung and Burns (1976a, b), Goto, et al (1983, 1987…     

MODELING THE FATE AND TRANSPORT OF HYDROPHOBIC ORGANIC COMPOUNDS IN AN UNSTEADY RIVER-ESTUARINE SYSTEM

1 INTRODUCTION Extensive literature (Brown et al., 1985; Sawhney et al., 1981; Bierman and Swain, 1982; Connolly, 1980; Lopez-Avila and Hites, 1980; O扖onnor, 1988) described lots of sorbed pollutants or toxic substances in bed sediments of rivers, even after the effluent was halted for a long time. This is particularly true for hydrophobic organic compounds that can be sorbed on the particles and accumulated in the river bed sediments (Karickhoff et al., 1979). Pollution events of…     

Three types of pyroclastic currents and their deposits: examples from the Vulsini Volcanoes, Italy

This paper deals with ground-hugging, gas–pyroclast currents from explosive volcanic eruptions and their deposits. Key field observations and laboratory determinations are proposed to relate specific deposit types with flow regimes and particle concentration in the transport and depositional systems. Three relevant flow scenarios and corresponding deposit types have been recognized from a survey of pyroclastic successions of the Vulsini Volcanic District (central Italy): (1) dilute, turbulent, pyroclastic currents producing normally or multiply graded beds by direct suspension sedimentation; (2) concentrated bedload regions beneath suspension currents, depositing inversely graded beds by traction carpet sedimentation; (3) self-sustained, high particle concentration, laminar, mass flows developing massive, poorly sorted bodies, with opposite grading of coarse lithic and pumice clasts, overlying fine-grained, inversely graded, basal layers. Main distinguishing criteria include the occurrence and pattern of clast grading, clast–thickness relationships, grain size, ash matrix componentry and pyroclast size–density relationships. Downcurrent and temporal transitions among identified flow scenarios are likely to occur for changing energy conditions and gas–pyroclast ratio both on regional and local scales. The nature and efficiency of magma fragmentation, volatile content, conduit geometry (which determine the characteristics of the erupted mixture and possible lateral blast component at the vent), and the angle of incidence of the column collapse, are suggested as the main factors controlling the generation of one type over the other at flow inception. Dilute, fine-grained, overpressured eruption clouds are thought to favor the formation of low particle concentration turbulent currents. Column collapse over slightly inclined volcano slopes, causing a high degree of compression of the collapsing mixture and of gas expulsion, would favor the generation of high particle concentration pyroclastic currents.     

《CT理论与应用研究》杂志新刊标和地幔速度模型的说明

在《ＣＴ理论与应用研究》杂志１９９４~２００１年本杂志“刊标”的基础上,在其上方增加了象征三维体视学成像的三角形四面体的透视图;该刊标的右下侧为医学断面成像扫描仪(包括各种Ｘ－ＣＴ机与核磁共振ＭＲＩ扫描仪等);其左下侧为三维地幔速度模型和地球核的示意图,切出有两个地幔剖面,表示纵波速度二维变化的剖面。该速度剖面系根据赵大鹏教授的理论和计算方法,按照地球上的两个大圆弧做计算和绘制的彩色图,排在本期封４:第一大圆弧,从北极经西巴基斯坦(２８°Ｎ, ６４°Ｅ)到马尔代夫群岛(３°Ｎ,７３°Ｅ);第二大圆弧从马尔代夫群岛点(３°Ｎ,７３°Ｅ)连接巴布新几内亚之南点(１２°Ｓ,１５０°Ｅ),来计算两剖面速度分布并作图的结果,其具体分布参见封４的两条彩色剖面和相应的地理位置图。由于赵教授这篇论文[１]在中国国内只有很少数图书馆收藏,在Ｅｌｓｅｖｉｅｒ Ｓｃｉｅｎｃｅ的ＥＰＳＬ网站上一般人只能查到摘要,本刊对于该地幔速度模型的制作方法和所用数据资料,该模型的优越性和特征进行了叙述,他所用的地震事件数目,多达７１２８个;用于层析反演成像的震相到时数多到近一百万条。该速度如下的特点:在所采用的速度结构中,包含用几个复杂形状的地质速度界面,如莫霍面,以及下沉板块的分界     

A cellular model of Holocene upland river basin and alluvial fan evolution

The CAESAR (Cellular Automaton Evolutionary Slope And River) model is used to simulate the Holocene development of a small upland catchment (4·2 km²) and the alluvial fan at its base. The model operates at a 3 m grid scale and simulates every flood over the last 9200 years, using a rainfall record reconstructed from peat bog wetness indices and land cover history derived from palynological sources. Model results show that the simulated catchment sediment discharge above the alluvial fan closely follows the climate signal, but with an increase in the amplitude of response after deforestation. The important effects of sediment storage and remobilization are shown, and findings suggest that soil creep rates may be an important control on long term (>1000 years) temperate catchment sediment yield. The simulated alluvial fan shows a complex and episodic behaviour, with frequent avulsions across the fan surface. However, there appears to be no clear link between fan response and climate or land use changes suggesting that Holocene alluvial fan dynamics may be the result of phases of sediment storage and remobilization, or instabilities and thresholds within the fan itself. Copyright © 2002 John Wiley & Sons, Ltd.