The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.     

Y11B航空物探(电/磁)综合站西北找水初步成果

1997年9月23日～10月8日,在甘肃省安西—敦煌地区用Y11B航空物探(电/磁)综合站和GPS导航定位进行了地下水勘查试生产工作。用均匀大地模型,结合已知的水文地质资料,初步圈定了淡水区、过渡类型水区、咸水区和苦水区及泉水湖。所推断的水质和土壤含盐量与大的水文地质单元和1:20万水文地质普查报告都吻合得很好,且细节更为清楚。对差异较大的地方做了分析和解释。     

西藏曲水县达布斑岩铜(钼)矿床成岩成矿年代学研究

本文采用锆石LA-ICP-MS微区U-Pb测年技术,对冈底斯成矿带东段曲水县达布斑岩Cu(Mo)矿床北部达布矿区含矿斑岩体、南部显角囊含矿花岗闪长斑岩岩体进行了年代学研究,通过对3件岩体样品中单颗粒锆石的分析,达布主矿体花岗闪长斑岩样品206Pb/238U年龄加权平均值为16.5±0.05Ma(n=15,MSWD=3),达布主含矿体二长花岗斑岩样品年龄为16.1±0.13Ma(n=15,MSWD=1.03),南部显角囊矿体花岗闪长斑岩年龄为16.2±0.04Ma(n=13,MSWD=0.0064)。对达布矿床斑岩Cu(Mo)矿床主矿体中4件辉钼矿样品,显角囊矿体中6件辉钼矿样品,分别进行了Re-Os同位素测试,等时线年龄分别为14.6±0.50Ma(MSWD=0.35,主矿体)、14.8±0.23Ma(MSWD=1.3,显角囊)。结合前人研究以及本次测年结果认为:1)达布斑岩铜(钼)矿床岩体侵位的年龄应限定在16Ma左右,成矿时代为14Ma左右,成矿时间差小于0.86Ma,与区域上"成矿瞬时发生"的成矿规律是一致的;2)矿床产出于印度-亚洲大陆板块后碰撞伸展环境。     

南京直立人研究的新进展

简单地介绍了“南京直立人（猿人）综合研究专家组”近二年来的部份研究成果，如南京汤山葫芦洞内的地层可以分为4段；洞内的哺乳动物群可以分为时代不同的大洞动物群和小洞动物群；南京直立人的一号头骨与二号头骨层位不同，特征也不一；铀系测年也证明小洞的地层其年代在距今60万年-50万年间，大洞的地层年代在距今24万年-10万年间，大洞被堆石堆砾石层封闭的时间应在13万年-10万年间。从而补充和纠正了前人研究中的不足和错误。     

2000-2018年东亚地区云顶高度的时空变化特征

为了了解区域云顶高度对过去气候变化的响应,基于卫星搭载的MODIS传感器提供的2000年3月至2018年2月MOD03_08_v6.0数据,分析了东亚地区云顶高度2000—2018年的时空变化特征,并探讨其长期变化的原因。研究发现,东亚地区云顶高度呈西南高东北低的特征。云顶高度在东亚地区以0.020 km/a的变率增长,其中大陆东部云顶高度的年际变率为0.035 km/a,东部海域年际变率为0.034 km/a。在东部海域地区云顶高度的变化同海表温度的变化相关性较高,相关系数为0.68,这表明云顶高度的变化受下垫面的影响。在东亚地区30°~40°N区域内,年平均云顶高度的增加较为明显。此外,夏季云顶高度在长江中下游盆地、塔里木盆地、吐鲁番盆地以及四川盆地东北部呈-0.03 km/a的减少趋势,这是由于更多低云的形成降低了云顶高度;冬季云顶高度在东亚地区40°N以北呈下降趋势,而在40°N以南呈增加趋势。     

登陆台风卡努(0515)内核区环流结构特征分析

本文采用地基雷达轨迹显示技术(Ground Based Velocity Track Display,简称GBVTD)反演的雷达风场资料,分析台风卡努(0515)在登陆期间近中心环流结构特征.轴对称环流结构分析表明,登陆前卡努轴对称切向风速最大值出现在眼墙区域2 km高度附近,最大风速半径随高度向外倾斜.轴对称径向入流...     

绿色交通目标下集装箱“公转铁”的CO2减排潜力评估

为提高集装箱“公转铁”减排潜力评估结果的准确性,在分析“公转铁”减排原理的基础上,综合考虑空箱调运和重箱运输“门到门”运输链的干线运输、端点装卸、电力设备作业、集卡短驳、公铁中转等排放,引入反映活动类型、设备结构、能源生命周期排放的参数,对作业活动-方式结构-能耗强度-排放因子（ASIF）方法进行改进,建立“公转铁”减排潜力评估框架。以义乌—宁波港域出口集装箱运输为例,通过实地调研和公开文献获取数据,进行实证研究。结果表明,如果忽略必要因素将会导致每TEU运输需求“公转铁”的CO₂减排率被高估0.50~36.73个百分点;最佳“公转铁”情景可减排3.42万t CO₂,相应减排率为13.58%。研究结果可为政府相关部门客观评估“公转铁”的减排潜力、制定有效的“公转铁”政策措施提供理论支持。     

气象场经验正交函数不同展开方案收敛性问题的探讨

本文从理论上证明EOFs(经验正交函数)用于气象场时,三种不同计算方案特征值的相互关系.指出利用原始场积和矩阵展开的特征值λ_j等于用协方差阵展开的特征值λ_j~*加上平均场方差引起的特征值λ_j.进而论证了收敛速度差舁的原因.最后又以实例表明,不同展开方案的典型场意义及其与时间权重系数的对应关系.     

THERMAL FORCING IMPACTS OF THE EASTERLY VORTEX ON THE EAST-WEST SHIFT OF THE SUBTROPICAL ANTICYCLONE OVER WESTERN PACIFIC OCEAN

By employing the NCEP/NCAR reanalysis data sets(1 000 to 10 hPa,2.5°× 2.5°),the thermal forcing impacts are analyzed of an easterly vortex(shortened as EV) over the tropical upper troposphere on the quasi-horizontal movement of the Western Pacific Subtropical Anticyclone(shortened as WPS A) during 22-25 June 2003.The relevant mechanisms are discussed as well.It is shown that the distribution and intensity of the non-adiabatic effect near the EV result in the anomalous eastward retreat of the WPSA.The WPSA prefers extending to the colder region,i.e.,it moves toward the region in which the non-adiabatic heating is weakening or the cooling is strengthening.During the WPSA retreat,the apparent changes of non-adiabatic heating illustrate the characteristics of enhanced cooling in the east side of the EV.Meanwhile,the cooling in the west side exhibits a weakened eastward trend,most prominently at 300 hPa in the troposphere.The evidence on the factors causing the change in thermal condition is found:the most important contribution to the heating-rate trend is the vertical transport term,followed in turn by the local change in the heating rate term and the horizontal advection term.As a result,the atmospheric non-adiabatic heating generated by the vertical transport and local change discussed above is mainly connected to the retreat of the WPSA.     

海岸线熏烟扩散模式

该文导出一个无需作常涡扩散系数或“面源”假设的海岸线熏烟扩散模式。根据二维理论和观测资料对热力内边界层（TIBL）高度公式进行了简化。分析和预测结果表明:在海岸线附近,应尽可能将高污染源设置在远离海岸或靠近海岸线处,避免设置在有效源高度与当地TIBL高度相等的地点附近。