Chemical forms of heavy metal contaminants in sediments of Miyun reservoir

The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.     

致密砂岩的形成机制及其地质意义——以塔里木盆地英南2井为例

砂质岩的孔隙和喉道被网格状粘土矿物和次生加大矿物充填成微细孔喉状结构时,形成具有较高毛细管压力的致密砂岩。它与地层水发生水锁效应,可大大降低渗透率,成为致密砂岩盖层。当含水饱和度在50%以下时,束缚水饱和度比较低,致密砂岩储层可以产气;当含水饱和度在50%～90%区间时,具有较高的束缚水饱和度,相对渗透率非常低,它既不能产气也不能产水,反映为渗透率瓶颈区(具有盖层性质);当含水饱和度大于90%以上时,致密砂岩储层仅微量产水。塔里木盆地英南2井侏罗系气藏盖层由致密砂岩构成,不含水时的气体渗透率在(0.027～0.081)×10-3μm2,不能构成封堵;当含水饱和度达到60%以上时,相对渗透率几乎为零,构成有效盖层。     

三峡水库区巫山新县城库岸综合治理设计回顾

三峡水库区巫山新县域库岸综合治理工程范围内涉及到滑坡、泥石流、塌岸等多种地质灾害。治理工程综合运用了多种技术与结构措拖，工程的复杂性和典型性在整个三峡库区具有极强的代表意义。笔者对整个治理方案的布置情况进行了归纳总结，并以翔实的第一手资料对治理工程设计过程中出现的几种典型问题一一进行了分析与论述．提出了相应的解决方案与合理化建议。结论认为，库岸综合治理工作，必须根据不同的地形特征，结合城区总体布局及沿线市政工程建设，综合考虑，有机结合，做到治理和利用相结合，最大限度地改善新城建设用地环境和城市生态环境。设计人员必须依照现场实际条件进行动态设计，确保工程方案合理、可靠、经济。文中讨论的问题和实践经检对同类工程具有一定的借鉴意义。     

HOLOCENE CLIMATE VARIABILITY IN THE DENMARK STRAIT REGION - A LAND-SEA CORRELATION OF NEW AND EXISTING CLIMATE PROXY RECORDS

ABSTRACT. Two well dated Holocene sediment records bordering the Denmark Strait region have been used to reconstruct past climate variability. The content of biogenic silica, classic and organic material and moss in a lacustrine record from Lake N14 has been used to infer past variability in precipitation and temperature in southern Greenland. Sedimentologic and petrologic composition of sand in a shelf sediment record from the Djúpáll trough is used to infer past variability in the northwestern storm activity on northwestern Iceland, which probably also affected the inflow of polar waters from the East Greenland Current. Our evaluation of these records with a number of previous studies from the region documents Holocene climatic optimum conditions peaking between 8000 and 6500 calendar years before present (cal yr BP). Mid-Holocene climate deterioration set in around 5000 cal yr BP followed by a further marked setback around 3500 cal yr BP. A stacking of climate variability on a centennial timescale from previous studies in the area shows a fairly good correspondence to the timing of marked cold and warm events as evidenced from the Lake N14 and the Djúpáll trough records. Cooler periods are explained as the response to marked incursions of ice-laden polar water from the Arctic Ocean to the Denmark Strait region. Cool northerly and northwesterly winds along the East Greenland coast in relation to frequent strong atmospheric low pressure in the Barents Sea, coupled with strong high pressure over Greenland, would have favoured southward export of polar waters. A comparison with the proxy records of nuclide production (¹⁴C and ¹⁰Be) suggests that solar activity may have had some influence on the atmospheric pressure distribution in the Denmark Strait region.     

Transport rate of calcareous sand in unidirectional flow

This paper examines the transport of calcareous sand in unidirectional flow and its prediction through existing sediment transport models. A flume experiment of four sand samples collected on Oahu, Hawaii, provides 29 sets of sediment transport data in the bed-form and suspended transport stages. The measured transport data are compared with direct predictions from four energy-based transport models developed for siliceous particles. Corrections for the grain-size, fall velocity, and critical velocity of calcareous sand based on recent research are applied to the models and the results are compared with the direct calculations and measured data. The comparison illustrates the important role particle shape plays in the transport of calcareous sand. All four sediment transport models give consistent predictions and good agreement with the majority of the measured data. Two of the models respond positively to the corrections in both the bed-form and suspended transport stages indicating that such an approach may provide an interim solution for the transport of calcareous sand.     

Influence of vegetation on aeolian sand transport rate from a backshore to a foredune at Hasaki, Japan

The influence of vegetation on aeolian sediment transport rate in the region from a backshore to a foredune was investigated at the Hasaki Coast in Japan, where an onshore wind was predominant and the creeping beach grasses Carex kobomugi and Calystegia soldanella were major species. The comparison of cross-shore distributions of the cross-shore component of aeolian sand transport rate with and without vegetation, which were estimated on the basis of the beach profile changes and a mass conservation equation, showed that the creeping grasses influenced the aeolian sand transport rate. The landward aeolian sand transport rate rapidly decreased landward from the seaward limit of vegetation when the grasses grew. The aeolian sand transport rate reduced by 95% with a vegetation cover of 28%. On the other hand, when the grasses were absent, the landward aeolian sand transport rate did not decrease near the seaward vegetation limit, but near the foot of the foredune.     

Simplified Method for the Assessment of the Stiffness Anisotropy of Rocks at Small Strains

Summary A new, practically applicable method for characterizing the stiffness anisotropy of rocks is presented. The anisotropy of geo-materials is often ignored in engineering applications, with potentially serious ramifications, because of the number of parameters required for characterization. The elastic anisotropy has often been considered to be a function of mathematical symmetry, and the restrictions due to layering, microcracking and granularity of the materials have not been considered in the assessment of the anisotropy. The practicality of the method proposed here is achieved by rationally reducing the number of independent anisotropy parameters, typically 9 for orthotropic anisotropy, to a system of 4 independent parameters through a systematic theoretical and experimental analysis of these structural restrictions. These 4 parameters are shown to be sufficient for describing the anisotropy of some rocks and sands at small strains, and parameter determination by back-analysis is demonstrated to be stable using appropriate measurement systems involving 9 elastic wave velocities even when the directions of anisotropic axes are unknown and the velocity data contains appreciable error.     

利用地震属性研究准噶尔盆地西北缘拐19井区下侏罗统三工河组沉积环境

在准噶尔盆地西北缘，寻找岩性圈闭油气藏已是至关重要的问题。但人们几乎还是用常规的手段来寻找岩性油气藏，没有实质性进展。本文是以利用宽方位角采集的地震数据为基础，对数据进行高保真资料处理和参考标准层的层拉平解释。利用前人的区域地质研究成果和钻井解释成果对侏罗系的沉积环境进行了精细的描述，确定了拐19井区在下侏罗统三工河组的出油层段附近的沉积环境由湖泊相－三角洲前缘相－河流相－湖泊相的演化过程。利用地震属性解释的结果也能较好地反映目标区的沉积环境变迁，并且与区域地质、测井解释结果相吻合，为寻找油气提供了很好的依据。由此得出利用地震属性可以进行沉积环境变迁分析，为油田寻找岩性圈闭及油气藏做出贡献。     

对羟基苯甲酸异丙酯合成的研究

以浓硫酸为催化剂，研究了对羟基苯甲酸和异丙醇合成对羟基苯甲酸异丙酯的工艺条件。对影响产率的因素进行了探讨：实验表明，在以7％的浓硫酸为催化剂，反应温度为120℃，醇酸摩尔比为4：1，反应时间为5h的最佳条件下，合成了羟基苯甲酸异丙脂，通过多次重结晶的方法纯化产品，产率可达85．5％，并通过熔点仪、红外光谱等手段对产品加以表征，验证了产品具有较高的纯度。该法简单、快速、产率高、纯度好，具有较高的实用价值。     

浙江江山石鼓水库除险加固工程技术措施

根据浙江江山石鼓水库大坝的结构构造特点、水库地质条件以及水库病险原因与状况，制定出一套科学完善的病险水库除险加固工程技术措施和施工操作规程，对病险水库进行了全面彻底治理，并取得良好效果。详细介绍了工程病险状况，除险加固方案设计，施工工艺及操作规程，加固效果检测及评价等。