非平衡热力学在短期灾害性天气预报中的应用

综述了非平衡热力学应用于天气预报的若干进程以及在短期灾害性天气预报应用中的明显效果。     

Theorem of turbulent intensity and macroscopic mechanism of the turbulence development

Turbulence is one of the most common nature phenomena in everyday experience, but that is not adequately understood yet. This article reviews the history and present state of development of the turbulence theory and indicates the necessity to probe into the turbulent features and mechanism with the different methods at different levels. Therefore this article proves a theorem of turbulent transpor- tation and a theorem of turbulent intensity by using the theory of the nonequilibrium thermodynamics, and that the Reynolds turbulence and the Rayleigh-Bénard turbulence are united in the theorems of the turbulent intensity and the turbulent transportation. The macroscopic cause of the development of fluid turbulence is a result from shearing effect of the velocity together with the temperature, which is also the macroscopic cause of the stretch and fold of trajectory in the phase space of turbulent field. And it is proved by the observed data of atmosphere that the phenomenological coefficient of turbulent in- tensity is not only a function of the velocity shear but also a function of temperature shear, viz the sta- bility of temperature stratification, in the atmosphere. Accordingly, authenticity of the theorem, which is proved by the theory of nonequilibrium thermodynamics, of turbulent intensity is testified by the facts of observational experiment.     

C—O—H体系高温高压流体相组成的热力学研究

本文在C－O－H体系流体相平衡基础上,利用现有的热力学数据和新的p－V－T资料,在pT=∑pi假定下,计算了高温、高压条件下流体相组成。结果表明,该体系主要存在五种流体相,在不同温压条件下各流体相所占比例不同。在相对较低的温、压条件下,CH4是体系中占主要的流体相（约占70％）,且随温、压和氧逸度的升高,它所占比例却明显降低,所获结果为探讨无机成因天然气形成的可能性、存在的量比和稳定存在的物理化学条件提供了充分的理论依据。     

中尺度对流复合体的热力学特征分析

用合成分析方法探讨ＭＣＣ热力学结构的演变规律,结果表明：ＭＣＣ整个生命史里,对流层中下部为正涡度区,２００ｈＰａ以上为负涡度区;发展时刻辐合区突然抬升;ＭＣＣ前期的垂直上升速度最大中心高度低于后期的;ＭＣＣ的高低空的冷心、中层暖心的温度结构在成熟期以后不明显     

地形对降水的影响研究概述

简要回顾了近些年来有关地形对降水影响的研究进展。介绍了地形的动力效应和热力效应,详细分析了地形的动力、热力效应引起的降水和云物理变化。重点分析了地形对气候尺度、天气尺度、中尺度及对流性天气系统降水的影响。简单地讨论了在研究地形对降水影响时观测分析、气候统计、理论分析及数值模拟方面存在的问题及其未来发展前景。     

羟基磷灰石对水溶液中Fe3+的吸附动力学及热力学研究

研究了羟基磷灰石(HAP)对水溶液中Fe3+的吸附动力学及热力学。研究表明,HAP对水溶液中Fe3+的吸附符合Langmiur等温吸附,ct/q=0.006 4 ct+0.018 3;该吸附反应符合一级反应动力学方程,ln CR=-0.043 5 t+4.324 4;吸附反应活化能为Ea=36.26 k J/mol;标准摩尔反应焓为正值表明反应过程吸热;当温度大于285.7 K时,吉布斯自由能小于0,反应可自发进行。     

Studies on the Thermodynamics and Thermal Chemistry Properties for Lithium Salts and Their Aqueous Solution Systems

正1 Introduction With the industrial development of lithium battery,nuclear and aerospace industry,the demands of metal lithium and its compounds are increasing significantly.Lithium is called as the energy of the metal in the new century(Zhang et al.2001).The total reserve of lithium resources around the world7     

Gravitational clustering of galaxies in an expanding universe

We inquire the phenomena of clustering of galaxies in an expanding universe from a theoretical point of view on the basis of thermodynamics and correlation functions. The partial differential equation is developed both for the point mass and extended mass structures of a two-point correlation function by using thermodynamic equations in combination with the equation of state taking gravitational interaction between particles into consideration. The unique solution physically satisfies a set of boundary conditions for correlated systems and provides a new insight into the gravitational clustering problem.     

韩山蓝晶石矿床成因研究

通过对韩山蓝晶石的性质、分布、物质来源等因素的分析,结合晶体主长理论,推测其是经过区域变质作用形成第一世代蓝晶石,侧分泌作用形成第二世代蓝晶石。     

Corrections to Solar Thermal Structure when a Turbulent Magnetic Field is Included

Correction of non-ideal effect due to a magnetic fluctuating tensor is derived from the ideal MHD equations. The inclusion of a magnetic turbulent field leads to modifications of the hydrostatic equilibrium equation and thermodynamical variables such as the temperature T, the adiabatic exponent γ, the adiabatic temperature gradient △↓ad and the temperature gradient △↓. In particular, the modifications in the adiabatic and radiative temperature gradients will result in a change in the Schwarzchild criterion, hence in the location of the base of the convective zone. Incorporating the modifications, we construct a modified thermodynamical equilibrium structure of the Sun.