三塘湖盆地马朗凹陷石炭系火山岩系油气成藏主控因素及模式

三塘湖盆地马朗凹陷石炭系主要发育两套烃源岩,分别为哈尔加乌组上段和哈尔加乌组下段,油气藏形成的源控作用十分明显。通过烃源岩和原油地球化学的分析以及油源对比,发现不同类型原油的形成与分布严格受控于对应源岩的分布范围。分析表明,马朗凹陷石炭系火山岩系油气成藏的主控因素是优质烃源岩、强充注油源断裂和有利火山岩相带的合理配置。根据烃源岩与储层的配置关系,石炭系油气藏的形成可以概括为两种模式:一种为风化壳型成藏模式,油气聚集在石炭系火山岩顶部受风化淋漓作用改造的优质储层中,其中的油气来自下部烃源岩,运移通道为与烃源岩相沟通的油源断裂;另一种模式为内幕型成藏模式,储层为流体溶蚀改造的储层,其中聚集的油气来自邻近火山喷发间歇期沉积的炭质泥岩。     

The genetic relationship between hydrocarbon systems and Mississippi Valley-type Zn–Pb deposits along the SW margin of Sichuan Basin,China

The Chipu Mississippi Valley-type (MVT) deposit is located on the southwest (SW) margin of the Sichuan Basin. Occurrence of plentiful organic matter (bitumen) at this deposit and abundant hydrocarbon reservoirs in the SW Sichuan Basin implies a link between lead–zinc mineralization and hydrocarbon systems in this area. The high δ³⁴S values of most metal sulphides from the different ore stages suggest that H₂S-bearing gases and/or thermochemical sulphate reduction (TSR) by organic matter could have been the source of reduced sulphur involved in ore formation. Sulphides with small positive to negative δ³⁴S values can be attributed to organically bound sulphur at the Chipu deposit. Carbon and oxygen isotopic compositions from sparry carbonates suggest mixing of organic carbon with seawater-derived carbon in the mineralization process. From the early to the later ore stages, δ¹³C_PDB values of ore-hosting carbonates are increasingly more negative, which indicates strengthening of the TSR role during mineralization. Hydrogen and oxygen isotopes in fluid inclusions in the quartz gangue indicate the provenance of the ore-forming fluids in the hydrocarbons. Moreover, some extremely low hydrogen isotope values suggest the addition of hydrogen from the same source. The low H/C ratios and high non-hydrocarbon component of the bitumen (Zhang et al. 2010 Zhang, C.Q., Yu, J.J., Mao, J.W., Yu, H. and Li, H.M. 2010. Research on the biomarker from Chipu Pb-Zn Deposit, Sichuan. Acta Sedimentologica Sinica, 28: 832–844. v.p.in Chinese with English abstract [Google Scholar]) also suggest that the organic matter may have been involved in TSR and subjected to a strong oxidation by ore-bearing fluids. This study attempts to explain the lead–zinc mineralization process and the role of organic matter in it. As there is a demonstrable relationship between the evolution of the hydrocarbons and regional lead–zinc mineralization along the SW edge of the Sichuan Basin, we propose a possible model in which the MVT mineralization coincided with the degradation of hydrocarbon reservoirs due to the large-scale migration of basinal fluids, most likely driven by the late Indosinian orogeny in response to the closure of the Palaeo-Tethys Ocean.     

含有不整合面的钻井剖面中酸解烃的垂向分布规律

系统测量了不同时代、不同埋深的不整合面钻井剖面中酸解烃的分布,发现不整合面之下发育有总烃、甲烷浓度低而大分子烃类相对富集的烃类异常带,分析认为此异常带是风化脱气作用形成的脱气带,其厚度与下伏地层成岩程度有关。该发现对评价含油气盆地剥蚀与气藏保存、破坏的关系,不整合面对油气运聚的影响等有重要意义,也为解决剥蚀量恢复问题提供了新的科学线索。     

酒泉盆地营尔凹陷异常高压形成机理

酒泉盆地营尔凹陷下白垩统砂泥岩普遍发育超压。通过对地层压实特征、黏土矿物转化及有机质演化特征的分析,揭示了凹陷超压形成的机理。结果表明:①营尔凹陷纵向上发育常压带、浅层超压带、过渡带和深层超压带4个压力带,超压带内具有明显的泥岩密度降低、电阻率减小和声波时差增大的欠压实特征,表明不均衡压实作用是形成该区超压的主要原因;②凹陷内发育3个蒙脱石向伊利石转化带,第一迅速转化带对应于浅层超压带,第二迅速转化带对应于深层超压带,反映黏土矿物转化与凹陷超压有一定的联系;③深层有机质演化程度较高(镜质体反射率Ro>0.6%),与浅层超压带相比,生烃作用对深层超压带的超压贡献更大。由此认为,营尔凹陷的下白垩统地层超压是不均衡压实作用、黏土矿物脱水作用和生烃作用共同影响的结果,并且隆起带和洼陷带的成因机理有所差异。     

Hydrodynamic Evolution and Hydrocarbon Accumulation in the Dabashan Foreland Thrust Belt,China

There are two plays in the Dabashan foreland tectonic belt: the upper and the lower plays. The lower play experienced one sedimentary hydrodynamic stage, two burial hydrodynamic stages, two tectonic hydrodynamic stages and two infiltration hydrodynamic stages from the Sinian to the Cenozoic, while the upper play had one sedimentary hydrodynamic stage, one burial hydrodynamic stage, two tectonic hydrodynamic stages and one infiltration hydrodynamic stage from the Permian to the Cenozoic. Extensive flows of both sedimentary water, including hydrocarbons, and deep mantle fluid occurred in the Chengkou faults during collision orogeny in the Middle-Late Triassic Indosinian orogeny, and fluid flow was complicated during intracontinental orogeny in the Middle-Late Jurassic. In addition to these movements, infiltration and movement of meteoric water took place in the Chengkou faults, whereas in the covering-strata decollement tectonic belt, extensive sedimentary water flow (including hydrocarbons) occurred mainly in the Zhenba and Pingba faults. During the stage of rapid uplift and exhumation from the Cretaceous to the Cenozoic, the fluid flow was characterized mainly by infiltration of meteoric water and gravity-induced flow caused by altitude difference, whereas sedimentary water flow caused by tectonic processes was relatively less significant. Sedimentary water flow was more significant to the lower play in hydrocarbon migration and accumulation during collision orogeny in the Middle-Late Triassic Indosinian orogeny, but its influence is relatively slight on the upper play. On one hand, hydrodynamics during intracontinental orogeny in the Middle-Late Jurassic adjusted, reformed or oven destroyed oil reservoirs in the lower play; on the other hand, it drove large amounts of hydrocarbons to migrate laterally and vertically and is favorable for hydrocarbon accumulation. Infiltration hydrodynamics mainly adjusted and destroyed oil reservoirs from the Cretaceous to the Cenozoic.     

Control Factors and Diversities of Phase State of Oil and Gas Pools in the Kuqa Petroleum System

Based on the analysis of the hydrocarbon geochemical characteristics in the Kuqa petroleum system of the Tarim Basin, this study discusses the causes and controlling factors of the phase diversities and their differences in geochemical features. According to the characteristics and differences in oil and gas phase, the petroleum system can be divided into five categories: oil reservoir, wet gas reservoir, condensate gas-rich reservoir, condensate gas-poor reservoir and dry gas reservoir. The causes for the diversities in oil and gas phases include diversities of the sources of parent material, maturity of natural gas and the process of hydrocarbon accumulation of different hydrocarbon phases. On the whole, the Jurassic and Triassic terrestrial source rocks are the main sources for the hydrocarbon in the Kuqa Depression. The small differences in parent material may cause diversities in oil and gas amount, but the impact is small. The differences in oil and gas phase are mainly affected by maturity and the accumulation process, which closely relates with each other. Oil and gas at different thermal evolution stage can be captured in different accumulation process.     

Orderliness of Hydrocarbon Accumulation Distribution in Rift Basins of Eastern China

The Cenozoic rift basins in eastern China show a clear temporal and spatial zonation and episodic tectonic evolution, which control their episodic hydrocarbon generation and zonal accumulation. In this paper, based on the study of depositional architecture, hydrocarbon migration system and dynamic evolution in the rift basins, combinations of hydrocarbon accumulation elements were analyzed using sequence stratigraphy. Hydrocarbon distribution in system tracts with different sequence orders was further studied. And we summarized stacking patterns and horizontal combination relationships for different types of reservoirs, such as lithological, tectonic-lithological, tectonic and stratigraphical reservoirs which can be observed from depression center to basin margin. The result reveals that various scales of pools exhibit significant distribution and evolution orderliness in different pool-forming units, i.e., depositional systems, plays and depressions. The regular distribution of various scales of pools is closely related to tectonic evolution and depositional filling in the rift basins. The result can be applied to the fine petroleum exploration in rift basins in eastern China. It will promote the scientific prediction and evaluation of reservoir types and their spatial distribution, lead to the active shifts of exploration targets in different zones, and thus support the stable progress of fine exploration in mature exploration areas.     

准噶尔盆地南缘中段下组合储层特征及控制因素分析

准噶尔盆地南缘中段下部成藏组合主要包括侏罗系和下白垩统.通过对研究区已有的探井取心及野外露头资料的研究,对下白垩统清水河组、上侏罗统喀拉扎组和齐古组3套储层的沉积特征及其控制因素进行了分析研究,认为研究区储层具有较低成分成熟度、低-中等及中等-较好的结构成熟度,压实作用和胶结作用是原生孔隙损失的主要因素.     

成烃贡献值及其在烃源岩评价中的应用

烃源岩评价是油气勘探的关键工作之一。为了更加合理、直观和有效地评价烃源岩,以辽东湾地区为例,通过对烃源岩常规评价参数的分析,提出了考虑有机质丰度、类型和热演化程度的综合指标——成烃贡献值,并利用该指标对辽东湾地区烃源岩进行了评价。从个体评价和整体评价两方面,与常规评价方法的结论进行对比研究。结果表明,辽东湾地区辽中凹陷沙河街组烃源岩对成烃的贡献比东营组大,中洼烃源岩比北洼好。由此可见,用成烃贡献值评价烃源岩,不仅可以达到常规评价的要求,而且比常规方法更加合理和直观。     

Atmospheric Concentrations and Phase Partitioning of Polycyclic Aromatic Hydrocarbons in Izmir,Turkey

Ambient air polycyclic aromatic hydrocarbon (PAH) samples were collected at a suburban (n = 63) and at an urban site (n = 14) in Izmir, Turkey. Average gas‐phase total PAH (∑₁₄PAH) concentrations were 23.5 ng m^?3 for suburban and 109.7 ng m^?3 for urban sites while average particle‐phase total PAH concentrations were 12.3 and 34.5 ng m^?3 for suburban and urban sites, respectively. Higher ambient PAH concentrations were measured in the gas‐phase and ∑₁₄PAH concentrations were dominated by lower molecular weight PAHs. Multiple linear regression analysis indicated that the meteorological parameters were effective on ambient PAH concentrations. Emission sources of particle‐phase PAHs were investigated using a diagnostic plot of fluorene (FLN)/(fluorine + pyrene; PY) versus indeno[1,2,3‐cd]PY/(indeno[1,2,3‐cd]PY + benzo[g,h,i]perylene) and several diagnostic ratios. These approaches have indicated that traffic emissions (petroleum combustion) were the dominant PAH sources at both sites for summer and winter seasons. Experimental gas–particle partition coefficients (K_P) were compared to the predictions of octanol–air (K_OA) and soot–air (K_SA) partition coefficient models. The correlations between experimental and modeled K_P values were significant (r² = 0.79 and 0.94 for suburban and urban sites, respectively, p < 0.01). Octanol‐based absorptive partitioning model predicted lower partition coefficients especially for relatively volatile PAHs. However, overall there was a relatively good agreement between the measured K_P and soot‐based model predictions.