渤海湾盆地盖层对天然气富集的影响初探

根据渤海湾盆地部分天然气藏的统计资料,分析了盖层的空间展布,厚度和类型对其封闭能力和天然气分布的影响,提出了盖层临界厚度的概念,研究认为,不同地区或同一地区不同层系天然气富集程度的差异主要是由于盖层的效应造成的。气藏直接盖层厚度与天然气富集程度有一定关系,对于成藏条件相似的众多天然气藏,直接盖层厚度与气柱高度及储量之间不同简单的直线关系,而是存在一个变化范围。     

高温高压条件下铁岭灰岩晶包有机质的饱和烃演化特征

对铁岭灰岩抽提除去沥青“Ａ”后的残渣进行高温高压模拟实验,模拟实验研究表明,晶包有机质的释放与温度与温度和压力有关,高压有利于晶包有机质释放。晶包有机质和干酪根主要释放出低碳数烷烃,Ｐｒ／ｎＣ１７、Ｐｈ－ｎＣ１８在热演化过程中变化不大,Ｐｒ／Ｐｈ则波动较大。     

Early Cenozoic paleontological assemblages and provenance evolution of the Lishui Sag,East China Sea

The East China Sea Shelf Basin generated a series of back-arc basins with thick successions of marine- and terrestrial-facies sediments during Cenozoic. It is enriched with abundant oil and gas resources and is of great significance to the petroleum exploration undertakings. Therein, the Lishui Sag formed fan delta, fluvial delta and littoral-to-neritic facies sediments during Paleocene–Eocene, and the research on its sedimentary environment and sediment source was controversial. This study analyzed the paleontological combination characteristics, and conducted a source-to-sink comparative analysis to restore the sedimentary environment and provenance evolution of the Lishui Sag during Paleocene–Eocene based on the integration of detrital zircon U-Pb age spectra patterns with paleontological assemblages. The results indicated that Lishui Sag was dominated by littoral and neritic-facies environment during time corroborated by large abundance of foraminifera, calcareous nannofossils and dinoflagellates. Chronological analysis of detrital zircon U-Pb revealed that there were significant differences in sediment sources between the east and west area of the Lishui Sag. The western area was featured by deeper water depths in the Paleocene–Eocene, and the sediment was characterized by a single Yanshanian peak of zircon U-Pb age spectra, and mainly influenced from Yanshanian magmatic rocks of South China Coast and the surrounding paleo-uplifts. However, its eastern area partly showed Indosinian populations. In particular, the upper Eocene Wenzhou sediments were featured by increasingly plentiful Precambrian zircons in addition to the large Indosinian-Yanshanian peaks, indicating a possible impact from the Yushan Low Uplift to the east. Therefore, it is likely that the eastern Lishui Sag generated large river systems as well as deltas during time. Due to the Yuquan Movement, the Lishui Sag experienced uplifting and exhumation in the late stage of the late Eocene and was not deposited with sediments until Miocene. Featured by transitional-facies depositions of Paleocene–Eocene, the Lishui Sag thus beared significant potential for source rock and oil-gas reservoir accumulation.     

冀中坳陷束鹿凹陷潜山不整合特征与油气运聚模式

本文从冀中坳陷束鹿凹陷潜山顶面不整合接触类型及分布规律、结构特征及输导类型出发,精细刻画了不整合面之下半风化岩石层的垂向岩溶分带特征。在此基础上对典型剖面烃源岩热演化、油气运移进行模拟,建立了研究区潜山油气的运聚模式。结果表明,束鹿凹陷潜山顶面不整合包括4种接触类型、5种结构模式,具有3种输导类型,其中斜坡区和洼槽区西部以侧向型为主,斜坡区局部构造高点与洼中隆为侧向+圈闭型,凸起区以侧向+垂向型为主。不整合面之下半风化岩石孔缝洞体系发育,垂向上可划分为表层岩溶带、垂直渗流带以及三个水平潜流带,具有多期岩溶旋回特征。潜山顶部发育的垂直渗流带是油气沿不整合面运移的主力输导层,而内幕发育的多期水平潜流带是油气向内幕运移的潜在通道。深、浅部烃源岩热演化的差异以及与薄层砾岩是否接触导致了斜坡区与洼中隆潜山油气充注的差异,形成了斜坡区晚期薄层砾岩高效中转、不整合侧向运移、水平潜流带向内幕输导、顺向断层向上输导、反向断层圈闭成藏的油气运聚模式。     

微生物勘探技术在潮汕坳陷油气勘探中的应用初探

东沙海域潮汕坳陷中生界研究程度相对较低,油气分布规律不明,为了加强对该区油气分布和富集规律的研究,针对潮汕坳陷西部地质目标首次应用微生物地球化学勘探技术(MGCE),探讨其含油气性。MGCE技术以轻烃微渗漏理论为基础,采用地质微生物学方法和地球化学方法检测研究区海底表层的微生物异常和吸附烃异常,预测研究区下伏地层中油气的富集区及其油气性质。检测结果显示研究区西部凹陷的斜坡区微生物异常呈块状发育,轻烃微渗漏强度变化大,可能为潜在油气富集区,酸解吸附烃成果显示可能的油气性质为干气和凝析油气。     

准噶尔盆地吉木萨尔凹陷二叠系芦草沟组优质烃源岩特征及其生烃机制研究

准噶尔盆地吉木萨尔凹陷芦草沟组发育凝灰物质,凝灰物质在页岩油形成过程中具有的重要作用,其发育层段也是页岩油分布最好的层段,凝灰物质的分布及与有机质生烃关系的研究对于吉木萨尔页岩油油气成藏规律的认识和深入研究具有重要意义。本文通过对吉木萨尔芦草沟组烃源岩精细评价及沉积环境分析,与烃类活动具有成因关系的成岩矿物解剖,探讨了形成优质页岩油源岩的控制因素和生烃机制。烃源岩定性评价结果表明,泥晶白云岩是吉木萨尔凹陷芦草沟组主要生油岩,烃源岩有机质丰度高,有机质类型以Ⅰ型和Ⅱ_1型为主,生烃潜力较好,R_o值分布在0.6%～1.1%,C_(29)αααS/(S+R)值范围在0.3～0.5,显示烃源岩处于成熟阶段;芦草沟组烃源岩中规则甾烷C_(27)、C_(28)、C_(29)分布为C_(27)C_(28)C_(29),结合微观分析认为其生烃母质以藻类和超微生物为主,Ts/Tm值较低,分布在0.05～0.18,具有高含量的β-胡萝卜烷,反映其母质处于半咸水的弱氧化—弱还原的沉积环境之中,而这一时期火山活动提供的凝灰物质对烃源岩的生烃环境及热演化进程都有重要影响,热演化突然增大的层段与有机质成熟的"甜点段"的分布深度一致。凝灰物质与含超微生物及藻类的泥晶白云岩的混合是导致生烃和早期生烃的重要原因,两者混合的不均一性导致页岩油分布与成熟度的不均匀性。     

The origin of magnetization and geochemical alteration in a fault zone,Kilve, England

The origin of an apparently syndeformational chemical remanent magnetization (CRM) and geochemical alteration in a fault zone in the Bristol Channel Basin, southwest England, was investigated. Deformation in the fault zone occurs in Jurassic aged, organic-rich limestones and consists of numerous normal and oblique-slip faults and associated folds. Migration of basinal, radiogenic fluids is indicated by elevated ⁸⁷Sr/⁸⁶Sr values for calcite veins that occur throughout the fault zone. Some of the calcite veins contain hydrocarbons sourced from deeper strata. Elevated ⁸⁷Sr/⁸⁶Sr values in the host Jurassic limestones indicate that they were also extensively altered by radiogenic fluids that migrated through microfractures in addition to major fault and fracture planes. Folded and tilted host limestones contain a pervasive secondary CRM residing in magnetite that was acquired during deformation in the Tertiary. The association between this pervasive CRM and the pervasive geochemical alteration is consistent with a genetic connection between the orogenic fluids and the CRM although the timing of CRM acquisition (Tertiary) is not consistent with structural interpretations for the timing of most veining. An alternative remagnetization mechanism which is not triggered by externally derived fluids, such as diagenesis of hydrocarbons, might account for the CRM. Hydrocarbon-bearing veins also contain a CRM that resides in magnetite, although the time for remanence acquisition is not well constrained by field tests. © 1998 John Wiley & Sons, Ltd.     

中国陆相油页岩含油率与总有机碳的响应机理

为了建立稳定可靠的利用油页岩总有机碳预测含油率的模型,揭示中国陆相不同成因类型油页岩含油率与总有机碳的内在关系极其重要。通过不同类型盆地油页岩钻井取心测试的关键参数,结合沉积学、有机地球化学、热模拟等学科技术,探讨油页岩含油率与总有机碳的响应机理。结果表明：不同盆地类型与沉积背景下发育的油页岩含油率与总有机碳质量分数均呈现良好的正相关性（R²=0.81~0.97）;中国陆相油页岩的成因类型进一步划分为5种类型,制约着含油率与总有机碳的内在关系;油页岩的升温加热模拟呈现3个失重阶段（温度<150、300~550、600~750℃）,明确了含油率与总有机碳参数的物理意义;相同类型盆地与沉积背景下形成的油页岩具有相近的母质生源组合,从而具有大致相当的再生烃效率。中国陆相油页岩成因类型的细划、含油率与总有机碳物理意义的明确、油页岩再生烃能力的分析,有助于理解中国陆相油页岩含油率与总有机碳的内在响应关系。     

渤东凹陷东营组烃源岩评价

渤东凹陷是渤海海域下一步油气勘探的重点地区之一。本文通过对渤东凹陷单井烃源岩的有机地球化学分析和与渤中凹陷烃源岩的对比研究,结合渤东凹陷盆地模拟成果,得出以下认识：渤东凹陷南部东营组半深湖深湖相泥岩的有机质丰度高,有机质类型好,有机质演化已处于成熟阶段,因而东营组暗色泥岩具有较高的生烃潜力,是一套良好的烃源岩层。     

大气气溶胶中若干有机物的含量和季节变化

研究、探讨青岛近岸大气气溶胶中多芳烃类化合物的浓度水平、变化特征及影响因素。用高效液相色谱荧光检测法分析了青岛近岸大气气溶胶中的多环芳烃(PAHs)的含量水平,共检出13种多环芳烃化合物。结果表明该类化合物总量(∑PAHs)具有明显的季节特征,呈现春季<秋季<冬季的特征,人类活动可能是其主要来源。