鄂尔多斯盆地东南缘延长组地层热演化史研究： 镜质体反射率和磷灰石裂变径迹证据

对鄂尔多斯盆地东南缘韩城和洛南地区的晚三叠世延长组地层的6件样品进行了煤线和碳质泥岩的镜质组反射率测定,同时测定了同组地层6件砂岩样品的磷灰石裂变径迹.结果表明鄂尔多斯盆地东南缘晚三叠世延长组热演化程度较高,韩城地区R0值在0.65％～0.78％之间.洛南地区由于受秦岭中生代陆内造山作用的影响,三叠系延长组Ro值高达2.67％～3.71％.实际测得的裂变径迹年龄,随深度增加裂变径迹年龄减小,根据裂变径迹年龄及长度恢复出每个样品所经历的热历史.研究结果表明鄂尔多斯盆地东南缘中生代晚期存在一期约100 Ma的重要构造热事件,东南缘韩城地区与洛南地区属于不同的热演化史类型,韩城地区属于埋藏增温型,而洛南地区属于受构造岩浆活动控制类型.这一认识与野外地质证据一致.     

新疆艾维尔沟煤变质作用研究

新疆艾维尔沟矿区是侏罗纪天山褶皱带中的一个小型山间含煤盆地。多项煤变质指标的分析结果表明:该区煤级在横向上分带明显,垂向上煤级突变,煤岩组份中出现热变显微组份,煤晶核指标(La/Lc)大于1,矿区广泛发育热液石英脉和方解石脉,煤层围岩也具有中低温热液蚀变现象。所有这些特征都充分表明,艾维尔沟的煤变质属区域热变质类型。推测其附加热源位于该煤盆地西部,地下水热液的对流为主要热传导方式。矿区及其外围的构造、地层结构、地势、水文等条件均有利于地下水热液循环。     

磷灰石裂变径迹在确定造山带隆升速率中的应用

矿物裂变径迹技术是一种低温热史及年代学测定技术,广泛应用于含油气盆地热史分析、沉积物来源、造山带隆升剥蚀、地质年代学测定等方面的研究。近年来,磷灰石裂变径迹在研究造山带构造隆升速率方面取得了大量成果。笔者在结合前人研究成果基础上,分别介绍了利用裂变径迹反演热史、裂变年龄和矿物对-封闭温度法确定构造隆升速率的原理、方法和应用,并分析其优缺点,指出应用磷灰石裂变径迹研究构造隆升速率时应该注意的问题。     

现场测试地层平均热物性参数方法初探——以北京某工程地源热泵系统地层热物性测试评价工程为例

地层热物性参数是地源热泵系统地下换热器设计所需要的非常重要的参数,热物性参数的大小对钻孔的数量及钻孔的深度均有显著的影响,进而影响地源热泵系统的初投资。笔者以北京某工程地源热泵系统地层热物性测试评价工程为例,阐述了现场测试获取平均热物性参数的测试方法和原理,并通过建立传热模型,利用参数估算法计算了工程场区的热物性参数。为验证结果的可靠性,又采用了线源理论对测试数据进行计算并将计算结果与参数估算法进行了分析比较。最后,笔者对两种计算方法的求解方法和适用条件进行了归纳总结。由于目前地层热物性参数确定方法还很不成熟,可借鉴的经验不多,所以笔者提出的热物性参数确定方法只是尝试性的探索,还有待今后的实践检验和进一步的理论研究工作。     

青藏高原天然气水合物遥感探测研究

介绍了天然气水合物的遥感探测方法,即:首先选择适当的ETM+、ASTER以及Quickbird等遥感图像,分析可见光、短波红外、热红外波段的影像特征,反演地表温度;然后结合野外调查和前人资料,寻找天然气水合物的直接和间接遥感解译标志,进行遥感解译。研究结果表明,青藏高原天然气远景区出现的几种遥感解译标志包括:地表上空高温异常(尤其是水体上空)、泥火山、沼泽地水体中大量气泡和棕黄色沉淀物,以及碳酸盐化、粘土化等指示信息。本研究为进一步开展大规模天然气水合物遥感调查和圈定靶区提供了基础方法。      

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.     

GGR Biennial Critical Review: Analytical Developments Since 2014

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.     

鄂尔多斯盆地渭北隆起西南缘奥陶系热演化史恢复与生烃史——以麟游-旬邑地区为例

本文应用古地温恢复法及盆地模拟法,恢复鄂尔多斯盆地渭北隆起西南缘奥陶系最大古地温梯度、热演化史和生烃史。根据钻孔测温曲线求得渭北隆起现今地温梯度为3.12℃/100m。该区在二叠纪和三叠纪进入快速沉降阶段,早侏罗世早白垩世进入缓慢沉降阶段,晚白垩世以来进入抬升剥蚀阶段,剥蚀厚度在1100~1300 m。旬邑地区奥陶系烃源岩在早二叠世约270 Ma进入生油窗,晚三叠世约210 Ma进入成熟生油阶段。晚侏罗世约150 Ma开始大量生气,在早白垩世末期96 Ma左右,地层达到最大埋深及最高古地温,达到生气高峰。热史恢复及模拟结果表明旬邑地区早白垩世地温梯度最高可达到5.0℃/100 m,是主要生气期。     

中国近海富烃凹陷油气成藏特征

富烃凹陷是当今油气勘探的主战场,中国近海已发现的油气储量主要集中在14个富烃凹陷中。利用钻井、测井、地震及化验测试等资料,结合最新油气勘探成果,从温压系统、储盖组合、热流体活动及油气输导与聚集等方面分析、总结了中国近海典型已证实富烃凹陷的油气成藏特征。研究表明:中国近海富烃凹陷深层超压普遍发育,地温梯度高,复合型温压系统构成,为油气成藏提供了充足的动力;主力储层物性好,发育1～2套优质的区域性盖层,至少存在2套有利的储盖组合;发育多种类型的烃类包裹体,油气主成藏期集中,并存在快速幕式充注现象;发育高效优势输导体系、多种圈闭与油气藏类型,存在多种油气成藏模式,油气呈带状差异富集与分布。     

Structures of the Bohai Petroliferous Area, Bohai Bay Basin

This paper, for the first time, deals with a more systematic study of the structures in the Bohaipetroliferous area that covers nearly one third of the Bohai Bay basin. The study mainly involves the effects of preexisting basement faults on the basin formation, the characteristics of basin geometry and kinetics, the modelling of the tectonic-thermal history, the polycyclicity and heterogeneity in the structural evolution and the natural seismic tomographic images of the crust and upper mantle. The authors analyze the features of the dynamic evolution of the basin in the paper and point out that the basin in the Bohai petroliferous area is an extensional pull-apart basin.