Chemistry and Sulfur Isotopes in a Chert-dominant Sequence around the Stratiform Manganese Deposit of the Noda-Tamagawa Mine, Northern Kitakami Terrane, Northeast Japan: Implication for Paleoceanographic Environmental Setting

Abstract. Chemistry and sulfur isotopes are analyzed for a series of rocks in the chert‐dominant sequence around the stratiform manganese ore deposit of the Noda‐Tamagawa mine in the northern Kitakami Terrane, northeast Japan. The sequence is litholog‐ically classified into six units in ascending order: lower bedded chert, lower black shale, massive chert, manganese ore, upper black shale, and upper bedded chert. The rocks around the manganese ore deposit exhibit anomalous enrichment in Ni (max. 337 ppm), Zn (102) and U (30) in the upper part of lower bedded chert, Mo (122), Tl (79) and Pb (33) in the lower black shale, MnO, Cu (786) and Co (62) in the manganese ore, and As (247) and Sb (17) in the upper black shale. The aluminum‐normalized profiles reveal zonal enrichment of redox‐sensitive elements around the manganese bed: Zn‐Ni‐Fe‐Mo‐U(‐Co), Tl‐Pb(‐Mo), Mn‐Fe‐Cu‐V‐Cr‐Co(‐Zn) and As‐Sb in ascending order. The uppermost part of the lower bedded chert and black shale exhibit negative Ce/Ce* values, whereas the massive chert, manganese ore and lower part of the upper bedded chert display positive values. The isotopic δ³⁴S values are 0±6 % in the lower part of the lower bedded chert, ‐19 to ‐42 % in the upper part of the lower bedded chert, ‐36 to ‐42 % in the lower black shale, ‐28 to ‐35 % in the massive chert, manganese ore and upper black shale, and ‐23±5 % in the upper bedded chert. Thus, there is a marked negative shift in δ³⁴S values in the lower bedded chert, and an upward‐increasing trend in δ³⁴S through the manganese ore horizon. The present data provide evidence for a change in the paleoceanographic environmental resulting from inflow of oxic deepwater into the stagnant anoxic ocean floor below the manganese ore horizon. This event is likely to have triggered the precipitation of manganese oxyhydroxides. The redistribution of redox‐sensitive elements through the formation of metalliferous black shale and manganese carbonate ore may have occurred in association with bacterial decomposition of organic matter during early diagenesis of initial manganese oxyhydroxides.     

Chemical Profiles across a Jurassic Stratiform Manganese Deposit at Katsuyama in the Mino Terrane of Central Japan: Implications for Depositional Environment, Diagenetic Metal Redistribution and Paleoceanography

Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit.     

Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.     

湖南芙蓉锡矿床中萤石的Sr－Nd同位素研究

芙蓉锡矿床是一个新探明的超大型锡矿床，产于湘南的骑田岭花岗岩体中。本次研究测试了该矿床中与锡石硫化物共生的萤石的Sr和Nd同位素组成。各矿脉中萤石的87Sr/86Sr比值并不相同，变化从0.70770～0.71484，反映了成矿流体的初始87Sr/86Sr比值并不均一。萤石的Sm－Nd同位素组成并没有构成很好的等时线，计算的ENd（t）值变化在－6.6～－9.8之间。萤石的Sr－Nd同位素组成并不同于花岗岩，成矿流体中的Sr和Nd有很大一部分来自围岩的碳酸盐岩地层。     

Land degradation in the source region of the Yellow River, northeast Qinghai-Xizang Plateau: classification and evaluation

Land degradation imposes a great threat to the world. It is not merely an environmental issue, but also a social and economic problem. Land desertification is among the main aspects of environment changes in the source region of the Yellow River. Previous studies focused on water resource utilization and soil erosion, but land degradation in the source region of the Yellow River even the whole Qinghai-Xizang Plateau received little attention. Based on the data obtained by field investigation and TM satellite images of 2000, this study provides the classification and evaluation information of the land degradation in the source region of the Yellow River. There are six types of land degradation in this region: water erosion in the northern mountains around the Gonghe Basin, sandy desertification in the Gonghe Basin and Upland Plain Area, aridization in the lower reaches, salinization in the Gonghe Basin, vegetation degradation in the intramontance basin and freezing and thawing erosion in the high mountains. The total degraded area is 34,429.6 km², making up 37.5% of the land in the study area. Finally, land degradation in the source region of the Yellow River was evaluated according to changes in the physical structure and chemical component of soils, land productivity, secondary soil salt and water conditions.     

华北地块东部晚中生代至新生代岩石圈不均一减薄与改造模式

本文综合运用不同时代幔源包体平衡温压对比、玄武岩地球化学性质对岩石圈厚度的反演以及不同时代岩石圈地幔地球化学性质的对比的方法，把华北地块东部岩石圈的减薄时间限定在晚中生代至新生代之间。减薄的机制可能是华北东部地区晚白垩世以来大陆岩石圈的拉张作用。由于机械性拉薄和热、机械和化学侵蚀作用，岩石圈厚度最终减薄到70km以下。但古老的岩石圈地幔并没有完全因减薄而消失，残留部分受到了来自软流圈物质的强烈改造，使其Sr、Nd同位素组成类似于软流圈，但Os同位素没有受到明显的改变。改造后的岩石圈地幔成为华北地块东部新生代岩石圈地幔的主体。在时空上，岩石圈的减薄具有不均一的性质。     

江西修水西部金矿成矿地质条件分析

通过对地层、岩浆岩、构造及化探异常与成矿关系的分析，认为江西修水西部地区具有寻找中一大型金矿床的潜力。     

地质遗迹旅游的可持续发展

从介绍地质遗迹及地质遗迹旅游的概念入手，着重就新时期地质遗迹旅游可持续发展的问题，提出了两种思路和相应的策略。     

“青藏高原南部空白区基础地质调查与研究”计划项目新成果、新进展

通过2 0 0 4年度各相关图幅的大力工作,在基础地质、矿产和资源等方面取得了大量实际材料,综合研究区域构造地层格架、青藏高原地质图和青藏高原南部火山岩及其地球动力学意义等,取得重要进展和新认识,在矿产资源、旅游和人文景观等方面也取得重要阶段性成果。     

西藏自治区乃东县劣布铜矿综合地质特征

文章介绍区域地质背景、矿区地物化特征，对成矿时代、流体包裹体特征进行初步研究，并指出找矿远景，希望对矿区的矿产勘查具有借鉴和指导意义。