新型环境矿物材料——堇青石质泡沫陶瓷的研制

以聚氨脂泡沫塑料为前驱体，高岭土、铝土矿和滑石为原料，经配方和工艺设计，制备了以堇青石为主晶相的泡沫陶瓷，制成品密度为0．310－0．447g/cm^3，气孔率为81．7％－87．6％，孔径为0．2－0．5mm,平均抗压强度为0．98MPa。探讨了烧成温度对材料气孔率、抗压强度和吸水率等性能的影响。     

Geochronological framework and Pb, Sr isotope geochemistry of the Qingchengzi Pb–Zn–Ag–Au orefield, Northeastern China

The Qingchengzi orefield in northeastern China, is a concentration of several Pb–Zn, Ag, and Au ore deposits. A combination of geochronological and Pb, Sr isotopic investigations was conducted. Zircon SHRIMP U–Pb ages of 225.3 ± 1.8 Ma and 184.5 ± 1.6 Ma were obtained for the Xinling and Yaojiagou granites, respectively. By step-dissolution Rb–Sr dating, ages of 221 ± 12 Ma and 138.7 ± 4.1 Ma were obtained for the sphalerite of the Zhenzigou Zn–Pb deposit and pyrargyrite of the Ag ore in the Gaojiabaozi Ag deposit, respectively. Pb isotopic ratios of the Ag ore at Gaojiabaozi (²⁰⁶Pb/²⁰⁴Pb = 18.38 to 18.53) are higher than those of the Pb–Zn ores (²⁰⁶Pb/²⁰⁴Pb = 17.66 to 17.96; Chen et al. [Chen, J.F., Yu, G., Xue, C.J., Qian, H., He, J.F., Xing, Z., Zhang, X., 2005. Pb isotope geochemistry of lead, zinc, gold and silver deposit clustered region, Liaodong rift zone, northeastern China. Science in China Series D 48, 467–476.]). Triassic granites show low Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb = 17.12 to 17.41, ²⁰⁷Pb/²⁰⁴Pb = 15.47 to 15.54, ²⁰⁸Pb/²⁰⁴Pb = 37.51 to 37.89) and metamorphic rocks of the Liaohe Group have high ratios (²⁰⁶Pb/²⁰⁴Pb = 18.20 to 24.28 and 18.32 to 20.06, ²⁰⁷Pb/²⁰⁴Pb = 15.69 to 16.44 and 15.66 to 15.98, ²⁰⁸Pb/²⁰⁴Pb = 37.29 to 38.61 and 38.69 to 40.00 for the marble of the Dashiqiao Formation and schist of the Gaixian Formation, respectively).Magmatic activities at Qingchengzi and in adjacent regions took place in three stages, and each contained several magmatic pulses: ca. 220 to 225 Ma and 211 to 216 Ma in the Triassic; 179 to 185 Ma, 163 to 168 Ma, 155 Ma and 149 Ma in the Jurassic, as well as ca. 140 to 130 Ma in the Early Cretaceous. The Triassic magmatism was part of the Triassic magmatic belt along the northern margin of the North China Craton produced in a post-collisional extensional setting, and granites in it formed by crustal melting induced by mantle magma. The Jurassic and Early Cretaceous magmatism was related to the lithospheric delamination in eastern China. The Triassic is the most important metallogenic stage at Qingchengzi. The Pb–Zn deposits, the Pb–Zn–Ag ore at Gaojiabaozi, and the gold deposits were all formed in this stage. They are temporally and spatially associated with the Triassic magmatic activity. Mineralization is very weak in the Jurassic. Ag ore at Gaojiabaozi was formed in the Early Cretaceous, which is suggested by the young Rb–Sr isochron age, field relations, and significantly different Pb isotopic ratios between the Pb–Zn–Ag and Ag ores. Pb isotopic compositions of the Pb–Zn ores suggest binary mixing for the source of the deposits. The magmatic end-member is the Triassic granites and the other metamorphic rocks of the Liaohe Group. Slightly different proportions of the two end-members, or an involvement of materials from hidden Cretaceous granites with slightly different Pb isotopic ratios, is postulated to interpret the difference of Pb isotopic compositions between the Pb–Zn–(Ag) and Ag ores. Sr isotopic ratios support this conclusion. At the western part of the Qingchengzi orefield, hydrothermal fluid driven by the heat provided by the now exposed Triassic granites deposited ore-forming materials in the low and middle horizons of the marbles of the Dashiqiao Formation near the intrusions to form mesothermal Zn–Pb deposits. In the eastern part, hydrothermal fluids associated with deep, hidden Triassic intrusions moved upward along a regional fault over a long distance and then deposited the ore-forming materials to form epithermal Au and Pb–Zn–Ag ores. Young magmatic activities are all represented by dykes across the entire orefield, suggesting that the corresponding main intrusion bodies are situated in the deep part of the crust. Among these, only intrusions with age of ca. 140 Ma might have released sufficient amounts of fluid to be responsible for the formation of the Ag ore at Gaojiabaozi.Our age results support previous conclusions that sphalerite can provide a reliable Rb–Sr age as long as the fluid inclusion phase is effectively separated from the “sulfide” phase. Our work suggests that the separation can be achieved by a step-resolution technique. Moreover, we suggest that pyrargyrite is a promising mineral for Rb–Sr isochron dating.     

Iron(II) oxide determination in rocks and minerals

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.     

中国中新生代咸化湖盆烃源岩沉积的问题及相关进展

我国东部断陷湖盆和西部坳陷湖盆第三系均有蒸发岩与烃源岩共生现象。前者水体深、咸化范围小，在氯化盐和碳酸盐沉积环境中形成了优质烃源岩，后者水体浅、咸化范围大，在氯化盐和硫酸盐沉积环境中发育了优质烃源岩，作者认为两种湖盆出现的水体分层是有机质堆积和保存的重要条件。济阳坳陷和柴达木盆地为两类咸化湖盆的典型代表，对它们的研究可以深化蒸发岩-烃源岩共生区油气地质的认识、促进勘探发展。     

论川西炉霍裂谷微细浸染型金矿的矿质来源

扼要介绍了川西炉霍裂谷微细浸染型金矿的地质特征, 通过地层和岩石中元素丰度特征,稀土元素、同位素、微量金的可化性实验等系统分析, 提出炉霍裂谷微细浸染型金矿的成矿物质来自三叠纪地层中的细碎屑质浊积岩建造和裂谷海底火山作用提供的深源物质。并讨论了矿质初始富集的机制。     

云南澜沧老厂深部斑岩钼(铜)矿成矿物质来源的同位素地球化学证据

通过对云南澜沧老厂深部斑岩钼(铜)矿的S、Pb、H、O同位素地球化学特征的综合分析研究,探讨了隐伏斑岩型矿床的成矿物质来源.研究表明:斑岩钼(铜)矿体主要硫化物的δ34S在3.99‰～+1.8‰之间,平均值为- 1.32‰,分布范围较窄,指示硫具有壳-幔混合源特征;隐伏的成矿花岗斑岩和矿石中主要硫化物的铅同位素组成的变化范围和平均值均具明显的相似性,206pb/204pb比值变化于17.863～ 18.701之间(平均值为18.411),207pb/204 Pb值变化于15.448～15.733之间(平均值为15.628),208 Pb/204 pb值变化于37.753～39.104之间(平均值为38.615),指示矿区斑岩型矿体中的原始铅具有壳-幔混合源的特点,深部地幔也是重要源区之一;斑岩型钼(铜)矿体脉石矿物石英的δ18QH2O在-9.51‰～+9.41‰之间,δD在- 93‰～- 46.2‰之间,指示斑岩矿体成矿流体介质水既有岩浆水又有大气降水,其中,在远离主岩体的外接触带大气降水(雨水)参与成矿的程度相对较高.     

东昆仑祁漫塔格地区滩间山群矽卡岩化成矿作用

祁漫塔格地区滩间山群广泛发育,且与成矿关系密切。在该区已发现的尕林格铁矿床、卡尔却卡铜多金属矿床、肯德可克铁钴铋金矿床、虎头崖Ⅵ铜铅锌多金属带、Ⅱ铜铅锌铁锡多金属矿带等均与滩间山群关系密切。通过对区内成矿与滩间山群关系密切的典型矽卡岩型矿床剖析,得出该地区交代滩间山群的矽卡岩型矿化的成矿物源主要受控于滩间山群。在该区要重视寻找与滩间山群有关的矽卡岩型矿床,特别是滩间山群下岩组发育地段是成矿的有利地段。     

A Metallogenic Model of Gold Deposits of the Jiaodong Granite-Greenstone Belt

An analysis of trace elements and isotopic geochemistry suggest that the ore-forming materials of gold deposits in the Jiaodong granite-greenstone belt have multiple sources, especially the mantle source. Seismic wave, magnetic and gravity fields show that the crust-mantle structure and its coupling mechanism are the fundamental dynamic causes for the exchange and accumulation of materials and energy in the metallogenic system. Considering the evolution history of the structural setting, the tectono-metallogenic dynamics model of the area can be summarized as follows: (1) occurrence of the greenstone belt during the Archean-Proterozoic-the embryonic form of Au-source system; (2) stable tectonic setting in the Paleozoic-an intermittence in gold mineralization; (3) intensive activation and reformation of the greenstone belt in the Mesozoic-tectono-mineralization and tectono-diagensis; (4) posthumous structural activity in the Cenozoic-destruction of orebodies in the later stage. In the middle and late Ind     

Chemo‐mechanics of cemented granular solids subjected to precipitation and dissolution of mineral species

This paper studies the chemo‐mechanics of cemented granular solids in the context of continuum thermodynamics for fluid‐saturated porous media. For this purpose, an existing constitutive model formulated in the frame of the Breakage Mechanics theory is augmented to cope with reactive processes. Chemical state variables accounting for the reactions between the solid constituents and the solutes in the pore fluid are introduced to enrich the interactions among the microstructural units simulated by the model (i.e., grains and cement bonds). Two different reactive processes are studied (i.e., grain dissolution and cement precipitation), using the chemical variables to describe the progression of the reactions and track changes in the size of grains and bonds. Finally, a homogenization strategy is used to derive the energy potentials of the solid mixture, adopting probability density functions that depend on both mechanical and chemical indices. It is shown that the connection between the statistics of the micro‐scale attributes and the continuum properties of the solid enables the mathematical capture of numerous mechanical effects of lithification and chemical deterioration, such as changes in stiffness, expansion/contraction of the elastic domain, and development of inelastic strains during reaction. In particular, the model offers an interpretation of the plastic strains generated by aggressive environments, which are here interpreted as an outcome of chemically driven debonding and comminution. As a result, the model explains widely observed macroscopic signatures of geomaterial degradation by reconciling the energetics of the deformation/reaction processes with the evolving geometry of the microstructural attributes. Copyright © 2015 John Wiley & Sons, Ltd.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.