Sediment Hosted Primary Tin Deposit Associated with Biotite Granite and Fault Zone at Gunung Paku, Klian Intan, Upper Perak, Malaysia

Gunung Paku near Klian Intan, Perak, is a primary tin deposit in Malaysia mined since 200 years ago, contributing 3–5% of tin ore concentrates previously, and recently over 70% of the Malaysian tin. Gunung Paku is located within the western Tin belt of Peninsular Malaysia associated with biotite granite (184–230 Ma) of the Main Range Granitoid which extends up to the southern part of Peninsular and Central Thailand. The primary tin mineralization style at the Gunung Paku is mainly associated with widespread occurrence of sheet-like quartz veining systems parallel to the strike of the host rocks and confined within a narrow N–S trending fault zone. The mineralization formed within a thick sequence of metasedimentry rock that belongs to the Baling Formation of Palaeozoic age. The host rock of weakly metamorphosed argillite generally experienced strong tropical weathering that resulted in a thick sequence of light grey to light brown oxidized profile. The mineralized veins range from simple quartz-cassiterite, quartz-tourmaline-cassiterite to complex quartz-cassiterite-polymetallic sulfide veins. Wall rock alterations at Gunung Paku are mainly characterized by the hypogene type alteration consisting of silicification, tourmalinization, chloritization, sericitization and kaolinization normally adjacent to mineralized quartz veins and brecciated-fault gouge zones. Pyrite, arsenopyrite, cassiterite, rutile, chalcopyrite, trippkeite (CuAsO4), scorodite, covellite and other secondary iron-oxyhydroxide are the common metallic minerals that accompanied the tin mineralization. Other minor occurrences include trace amounts of complex lead-bismuth-antimony-molybdenum bearing minerals.     

安徽亳县陨石中宇宙成因矿物学研究

详细地研究了亳县陨石中的主要标型特征。亳县陨石是一块不平衡的普通球粒陨石 ,球粒结构齐全 ,保持原始信息多。对球粒中出现的 2 6种结构类型进行了合理的解释 ,为讨论球粒成因提供了科学依据。对亳县陨石中的几种特殊的标型矿物——指示强还原环境生成的标型矿物张衡矿、指示高压的标型矿物 Wadsleyite和指示高温凝聚产物的标型矿物亚铁尖晶石及 CAI包体的发现均作了详细的研究与讨论。     

The impact of climate change on the bulk and clay geochemistry of fluvial residual channel infillings: the late Weichselian and Early Holocene River Meuse sediments (The Netherlands)

Fine-grained fluvial residual channel infillings are likely to reflect systematic compositional changes in response to climate change, owing to changing weathering and geomorphological conditions in the upstream drainage basin. Our research focuses on the bulk sediment and clay geochemistry, laser granulometry and clay mineralogy of Late-glacial and Early Holocene River Meuse (Maas) unexposed residual channel infillings in northern Limburg (The Netherlands). We demonstrate that residual channel infillings register a systematic bulk and clay compositional change related to climate change on a 1–10 k-yr time-scale. Late-glacial and Holocene climatic amelioration stabilised the landscape and facilitated prolonged and intense chemical weathering of phyllosilicates and clay minerals due to soil formation. Clay translocation and subsequent erosion of topsoils on Palaeozoic bedrock and loess deposits increased the supply of smectite and vermiculite within River Meuse sediments. Smectite plus vermiculite contents rose from 30–40% in the Pleniglacial to 60% in the Late Allerød and to 70–80% in the Holocene. Younger Dryas cooling and landscape instability caused almost immediate return to low smectite and vermiculite contents. Following an Early Holocene rise, within about 5000 yr, a steady state supply is reached before 5 ka (Mid-Holocene). Holocene sediments therefore contain higher amounts of clay that are richer in high-Al, low-K and low-Mg vermiculites and smectites compared with Late (Pleni-)glacial sediments. The importance of clay mineral provenance and loess admixture in the River Meuse fluvial sediments is discussed. © 1998 John Wiley & Sons, Ltd.     

Mineralogical and geochemical indicators of anoxic sedimentation conditions in local depressions within the Sea of Okhotsk in the late Pleistocene-Holocene

This paper reports specific mineralogical and geochemical characteristics of deposits from the local depressions of the Derugin Basin. They were formed in an environment with periodic changes from oxic to anoxic conditions and show evidence for the presence of hydrogen sulfide in bottom waters. The deposits of this type can be considered as a modern model for ancient ore-bearing black shale associations. Compared with typical metalliferous black shale sequences, which are characterized by high contents of organic matter, the sediments described here are depleted in the elements of the organophilic association (Mo, Ni, Cu, Zn, V, and U) but have higher Mn contents.     

Weathering, mineralogical evolution and soil organic matter along a Holocene soil toposequence developed on carbonate-rich materials

A toposequence of Holocene soils located between 1100–2400 m asl in the Italian Alps served as the basis for the following analyses: the weathering of limestone and dolomite, the calculation of mass balances, understanding the formation of pedogenic Fe and Al, the determination of soil mineral and clay mineral reactions and transformation and the measurement of accumulation and stabilisation mechanisms of soil organic matter. Leaching of carbonates is most intense at the lower elevations, although calcite and dolomite have a higher solubility at low temperatures. The pCO₂ in the soil is higher at lower elevations and weathering is driven mainly by carbonic acids. At higher elevations, organic acids appear to determine the mineral transformations and weathering reactions to a greater extent. This suggests that two very different weathering regimes (carbonic and organic acid weathering) exist along the toposequence. The transformation of mica into vermiculite is the main process in both the clay and fine-earth fraction. Weathering of silicate minerals started even before the carbonates had been completely removed from the soils. The transformation mechanisms of silicate minerals in the A and O horizon at higher elevations was at least as intensive as that at the climatically warmer sites. The neoformation of pedogenetic clays at climatically cooler sites was slightly greater than that at the warmer sites. However, the formation rate of secondary Fe and Al phases was more pronounced at lower elevation, which means that this process seemed to be driven dominantly by carbonic acid (weathering of primary minerals). Soil organic matter (SOM) abundance in the mineral soil is nearly 15 kg/m² at all sites and, surprisingly, no climate-driven effect could be detected. In general, the preservation and stabilisation of SOM was due to poorly crystalline Al and Fe phases and vermiculite, regardless of some variations in the composition of the parent material (varying calcite/dolomite ratio).     

Tectonic and climatic control of the changes in the sedimentary record of the Karnali River section (Siwaliks of western Nepal)

Abstract A multidisciplinary study was conducted on the section of the Siwalik Group sediments, approximately 5000 m thick, exposed along the Karnali River. Analysis of facies, clay mineralogy and neodymium isotope compositions revealed significant changes in the sedimentary record, allowing discussion of their tectonic or climatic origin. Two major changes within the sedimentary fill were detected: the change from a meandering to a braided river system at ca 9.5 Ma and the change from a deep sandy braided to a shallow sandy braided river system at ca 6.5 Ma. The 9.5‐Ma change in fluvial style is contemporaneous with an abrupt increase of ?_Nd(0) values following a ?_Nd(0) minimum. This evolution indicates a change in source material and erosion of Lesser Himalayan rocks within the Karnali catchment basin between 13 and 10 Ma. The tectonic activity along the Ramgarh thrust caused this local exhumation. By changing the proximity and morphology of relief, the forward propagation of the basal detachment to the main boundary thrust was responsible for the high gradient and sediment load required for the development of the braided river system. The change from a deep sandy braided to a shallow sandy braided river system at approximately 6.5 Ma was contemporaneous with a change in clay mineralogy towards smectite‐/kaolinite‐dominant assemblages. As no source rock change and no burial effect are detected at that time, the change in clay mineralogy is interpreted as resulting from differences in environmental conditions. The facies analysis shows abruptly and frequently increasing discharges by 6.5 Ma, and could be linked to an increase in seasonality, induced by intensification of the monsoon climate. The major fluvial changes deciphered along the Karnali section have been recognized from central to western Nepal, although they are diachronous. The change in clay mineralogy towards smectite‐/kaolinite‐rich assemblages and the slight decrease of ?_Nd(0) have also been detected in the Bengal Fan sedimentary record, showing the extent and importance of the two major events recorded along the Karnali section.     

Flow direction and magnetic mineralogy of lava flows from the central parts of the Peninsula of Baja California,Mexico

Magnetic properties of two apparently unrelated lava suites (one tholeiitic and the other alkalic) coexisting in the central parts of the Peninsula of Baja California, Mexico, were measured in this study. Macroscopic indicators and measurements of anisotropy of magnetic susceptibility (AMS) were combined to infer the flow direction on those lavas. These measurements were used to investigate the likelihood of the existence of an abnormally long tholeiitic lava flow in this part of the Peninsula. The obtained results indicate that the tholeiitic flows in the region constitute regular length flows, and are likely to have been issued through vents located within the area of study. Additionally, comparison of the magnetic signature of tholeiitic and alkalic lavas reveals a systematic difference in some of the magnetic parameters (bulk susceptibility and Curie temperatures). In particular, it is proposed that the narrow range of Curie temperatures characteristic of each lava type can be used as a reliable proxy for the identification of each lava type in the region. All of these findings show that the alkalic and tholeiitic lavas of the region are more closely related to each other than previously suspected.Editorial responsibility: R. Cioni     

下地幔矿物研究及其进展

文中综述了20世纪90年代以来对下地幔矿物高温高压研究的进展,详细评论了下地幔温压下(Mg,Fe)SiO3钙钛矿的稳定性、(Mg, Fe)SiO3 钙钛矿和(Mg, Fe)O镁方铁矿的高压状态方程和热弹性及高压熔化、核幔边界温压下铁和硅酸盐的化学反应等几个热点问题;探讨了下地幔的矿物学组成,对下地幔的地震波速异常给出了可能的矿物学解释;介绍了国内同领域的研究工作;展望了下地幔矿物研究的发展方向。     

湖南锡田钨锡多金属矿田燕山期NE向断层演化历史及其成矿意义

为了确定湖南锡田矿田燕山期NE向断层演化历史、蚀变特征及与钨锡成矿关系本文调查了矿田内燕山期断层野外宏观特征,对断层中充填石英脉进行了显微鉴定、阴极发光、含矿元素分析,结果显示:(1)断层以NE60°～70°平行分布于茶汉盆地南北两侧,均倾向茶汉盆地,断层的陡倾、棱角状角砾及梳状石英等指示了断层的张性性质;(2)断层经...     

Complex interplay between depositional and petrophysical environments in Holocene tidal carbonates (Al Ruwais,Qatar)

Carbonate rocks can be classified in terms of those properties relating to the pore system of lithified sediments, so‐called ‘petrophysical rock types’, or ‘depositional rock types’ which are categorized based on characteristics directly reflecting their original depositional environment. Whereas petrophysical rock types are typically used to identify and distribute rock bodies within a reservoir with similar flow characteristics, depositional rock types ignore pore types and capture sedimentary structures, lithology and fossils. Both classification systems are extensively used to describe reservoir rocks, but the degree of plurality between them remains poorly understood and is the motivation for this study. To examine the degree of congruency between the two classification schemes, a field assessment was conducted for a 175 km² area situated offshore Al Ruwais, northern Qatar, encompassing depositional environments spanning supratidal, intertidal, shallow subtidal and open marine conditions. A total of 350 surficial sediment samples were collected along 24 shore‐normal transects. Each sample was assigned a ‘petrophysical rock type’ class based on analysis of sedimentary texture (grain size and sorting). ‘Depositional rock type’ classes, by contrast, were defined with reference to faunal content and, in turn, classes of mineralogy were delimited by weighting this content against the mineralogy of each faunal category. Of course, the samples studied correspond to unconsolidated sediments and not to indurated rocks. However, considering only primary porosity and permeability preservation, it is reasonable to assume that the classified sediments would become petrophysical rock types and depositional rock types when consolidated, following their primary grain size, sorting and grain type distribution. Therefore, the term ‘rock type’ is retained here for ease of terminology but, for clarity, these are sediment samples. The discrete samples were interpolated into continuous surfaces describing the distribution of depositional rock types, petrophysical rock types and mineralogy, and spatial correspondence between those surfaces was statistically evaluated. In order to link these parameters with environment of deposition, their correlation with water depth (as audited from airborne light detection and ranging) and ecological habitat (mapped from DigitalGlobe satellite imagery) was also assessed. The data reveal that spatial distributions of sedimentary faunal, petrographic and mineralogical properties do not show exactly congruent patterns. Other meaningful trends do exist, however. For example, the occurrence of certain depositional rock types is indicative of particular petrophysical rock types, and vice versa. Further, connections between petrophysical rock types and mineralogy are emphasized and offer insight as to how the evolution of matrix porosity might be predicted via diagenetic models tuned to specific sediment textures. Useful relationships are also identified between the occurrence of petrophysical rock types and depositional rock types, and both ecological habitat and water depth. The potential of such dualities is two‐fold. Firstly, they can be applied to more realistically distribute petrophysical rock types and depositional rock types by environment of deposition in reservoir models and, secondly, the use of modern carbonate systems as subsurface analogues might be enhanced.