Magma evolution and the formation of porphyry Cu–Au ore fluids: evidence from silicate and sulfide melt inclusions

Silicate and sulfide melt inclusions from the andesitic Farallón Negro Volcanic Complex in NW Argentina were analyzed by laser ablation ICPMS to track the behavior of Cu and Au during magma evolution, and to identify the processes in the source of fluids responsible for porphyry-Cu-Au mineralization at the 600 Mt Bajo de la Alumbrera deposit. The combination of silicate and sulfide melt inclusion data with previously published geological and geochemical information indicates that the source of ore metals and water was a mantle-derived mafic magma that contained approximately 6 wt.% H₂O and 200 ppm Cu. This magma and a rhyodacitic magma mixed in an upper-crustal magma chamber, feeding the volcanic systems and associated subvolcanic intrusions over 2.6 million years. Generation of the ore fluid from this magma occurred towards the end of this protracted evolution and probably involved six important steps: (1) Generation of a sulfide melt upon magma mixing in some parts of the magma chamber. (2) Partitioning of Cu and Au into the sulfide melt (enrichment factor of 10,000 for Cu) leading to Cu and Au concentrations of several wt.% or ppm, respectively. (3) A change in the tectonic regime from local extension to compression at the end of protracted volcanism. (4) Intrusion of a dacitic magma stock from the upper part of the layered magma chamber. (5) Volatile exsolution and resorption of the sulfide melt from the lower and more mafic parts of the magma chamber, generating a fluid with a Cu/Au ratio equal to that of the precursor sulfide. (6) Focused fluid transport and precipitation of the two metals in the porphyry, yielding an ore body containing Au and Cu in the proportions dictated by the magmatic fluid source. The Cu/S ratio in the sulfide melt inclusions requires that approximately 4,000 ppm sulfur is extracted from the andesitic magma upon mixing. This exceeds the solubility of sulfide or sulfate in either of the silicate melts and implies an additional source for S. The extra sulfur could be added in the form of anhydrite phenocrysts present in the rhyodacitic magma. It appears, thus, that unusually sulfur-rich, not Cu-rich magmas are the key to the formation of porphyry-type ore deposits. Our observations imply that dacitic intrusions hosting the porphyry–Cu–Au mineralization are not representative of the magma from which the ore-fluid exsolved. The source of the ore fluid is the underlying more mafic magma, and unaltered andesitic dikes emplaced immediately after ore formation are more likely to represent the magma from which the fluids were generated. At Alumbrera, these andesitic dikes carry relicts of the sulfide melt as inclusions in amphibole. Sulfide inclusions in similar dykes of other, less explored magmatic complexes may be used to predict the Au/Cu ratio of potential ore-forming fluids and the expected metal ratio in any undiscovered porphyry deposit.Editorial handling: B. Lehmann     

Diamond in metasedimentary crustal rocks from Pohorje,Eastern Alps: a window to deep continental subduction

We report the first finding of diamond and moissanite in metasedimentary crustal rocks of Pohorje Mountains (Slovenia) in the Austroalpine ultrahigh‐pressure (UHP) metamorphic terrane of the Eastern Alps. Microscopic observations and Raman spectroscopy show that diamond occurs in situ as inclusions in garnet, being heterogeneously distributed. Under the optical microscope, diamond‐bearing inclusions are of cuboidal to rounded shape and of pinkish, yellow to brownish colour. The Raman spectra of the investigated diamond show a sharp, first order peak of sp³‐bonded carbon, in most cases centred between 1332 and 1330 cm^?1, with a full width at half maximum between 3 and 5 cm^?1. Several spectra show Raman bands typical for disordered graphitic (sp²‐bonded) carbon. Detailed observations show that diamond occurs either as a monomineralic, single‐crystal inclusion or it is associated with SiC (moissanite), CO₂ and CH₄ in polyphase inclusions_. This rare record of diamond occurring with moissanite as fluid‐inclusion daughter minerals implies the crystallization of diamond and moissanite from a supercritical fluid at reducing conditions. Thermodynamic modelling suggests that diamond‐bearing gneisses attained P–T conditions of ≥3.5 GPa and 800–850 °C, similar to eclogites and garnet peridotites. We argue that diamond formed when carbonaceous sediment underwent UHP metamorphism at mantle depth exceeding 100 km during continental subduction in the Late Cretaceous (c. 95–92 Ma). The finding of diamond confirms UHP metamorphism in the Pohorje Mountains, the most deeply subducted part of Austroalpine units.     

河南老湾金矿床上上河矿段矿床地质和成矿流体地球化学

河南桐柏老湾金矿床是桐柏-大别山(北坡)金银成矿带内大型造山带型金矿床之一。文章对该矿床的上上河矿段进行了矿床地质和成矿流体地球化学研究,旨在查明该矿段的流体成矿过程。根据矿脉穿插关系、矿石结构构造、矿物共生组合以及黄铁矿的粒度和晶形,将老湾金矿上上河矿段成矿过程划分为:石英粗粒自形黄铁矿(Ⅰ)、石英细粒半自形-他形黄铁矿(Ⅱ)、石英多金属硫化物(Ⅲ)及石英碳酸盐(Ⅳ)4个阶段。镜下观察显示,矿床中的包裹体类型有含CO_2包裹体(LH_2O+LCO_2+VCO_2)、纯CO_2包裹体(LCO_2+VCO_2)、液相包裹体(LH_2O+VH_2O)及少量含子晶包裹体(LH_2O+VH_2O+S)。第Ⅰ阶段、第Ⅱ阶段和第Ⅲ阶段均可见含CO_2包裹体、纯CO_2包裹体和液相包裹体,有时可见含CO_2包裹体与液相包裹体共存。流体包裹体显微测温结果表明,成矿流体可近似看做中温、低盐度、富CO_2的NaCl-H_2O-CO_2体系,纯CO_2包裹体和液相包裹体所代表的流体可能是由含CO_2包裹体所代表的Na Cl-H_2O-CO_2流体经不混溶形成的,三者在寄主矿物沉淀时,被同时捕获而共存。从第Ⅰ阶段到第Ⅳ阶段,成矿流体温度从303~379℃逐渐降低到138~195℃,盐度w(Na Cleq)从4.07%~9.59%逐渐降低到1.06%~2.74%。在成矿的第Ⅰ阶段成矿流体发生了不混溶作用,而在第Ⅱ阶段和第Ⅲ阶段流体中的CO_2起泡分离再次引发了不混溶作用。从第Ⅰ阶段到第Ⅲ阶段,成矿流体的δ18OH_2O从6.56‰~9.71‰经1.89‰~4.01‰变化到0.08‰,δDH_2O从-78.1‰~-64.2‰经-79.5‰~-76.3‰变化到-72.6‰,表明老湾金矿第Ⅰ阶段成矿流体主要为岩浆热液,第Ⅱ阶段成矿流体中有少量大气降水加入,第Ⅲ阶段成矿流体中大气降水的比例明显加大。     

广西栗木钨锡铌钽矿区流体包裹体及氢氧同位素研究

本文通过对广西栗木矿区金竹源矿床和水溪庙矿床的流体包裹体研究,得出该矿区流体包裹体主要有两相H_2O-NaCl和H_2O-NaCl-CO_2两种类型。显微测温结果表明:两相H_2O-NaCl型流体包裹体均一温度主要集中于181.9~258.8℃,盐度w(Na Cleq)主要集中于4.01%~6.87%,密度0.690~0.988 g/cm3;H_2O-NaCl-CO_2型流体包裹体均一温度为178.5~331.1℃,主要集中在两个温度段,分别为高-中温段(265.3~315.5℃)和中-低温段(202.3~264.1℃),盐度w(NaCleq)主要集中在0.21%~5.05%,密度为0.678~0.886 g/cm3。栗木矿区成矿流体有两个温度集中段,且具有低盐度、低密度的特征。氢氧同位素研究结果表明:金竹源矿床钨锡铌钽矿化花岗岩石英δD值为-73.6‰~-62.8‰,δ~(18)OV-SMOW值为7.5‰~8.9‰,计算得δ~(18)OH2O值为6.00‰~7.40‰;水溪庙矿床钨锡铌钽矿化花岗岩石英δD值为-73.8‰~-58.3‰,δ~(18)OV-SMOW值为11.0‰~13.2‰,计算得δ~(18)OH2O值为9.50‰~11.70‰,水溪庙矿床含钨锡石英脉石英δD值为-75.3‰~-56.6‰,δ~(18)OV-SMOW值为11.8‰~14.1‰,计算得δ~(18)OH2O值为2.20‰~4.50‰。栗木矿区钨锡铌钽矿化花岗岩成矿流体来源于岩浆水,含钨锡石英脉成矿流体来源于岩浆水和大气降水的混合流体。     

西藏拿若铜(金)矿床隐爆角砾岩流体包裹体研究

隐爆角砾岩是西藏拿若矿床的重要组成部分,赋存厚大的铜矿体。笔者将隐爆角砾岩中流体分成两个主要期次,并对这两期流体开展包裹体研究。通过包裹体岩相学和显微测温认为:角砾中的石英(早期)包裹体形状均匀呈椭圆形,大小主要在2~5μm;胶结物中石英(晚期)包裹体形状可见椭圆状、长条状和近方形,大小主要在2~7μm。早期流体的包裹体可分为两个阶段,均一温度分别为早阶段280~368℃和晚阶段208~305℃,盐度分布为(4.65~12.73)%Na Cleq。晚期流体的包裹体同样可分为两个阶段,其均一温度分别为早阶段309~588℃和晚阶段232~335℃,盐度变化为(3.55~12.51)%Na Cleq,两个阶段的流体分别属于高温、中低盐度和中高温、中低盐度流体。L-V型包裹体激光拉曼分析显示:包裹体中气泡成分主要为气态H2O和少量CO2。拿若矿床至少经历两次隐爆作用,由晚期沸腾热液引起,并未成矿。成矿作用发生于隐爆角砾岩形成之后。     

浙江省绍兴市平水金矿体流体包裹体研究 与矿床成因

浙江平水铜矿位于钦杭成矿带北东段浙西北地区,是浙江省最大的铜矿床,前人研究表明其为典型的火山成因块状硫化物矿床（Chen 等, 2015）。平水铜矿体在新元古代形成之后,该地区经历了加里东的变质变形作用,在铜矿体的下盘普遍发育千糜岩带（韧性剪切带）,本项目组在研究过程中认为千糜岩带与铜矿无关,但明确提出本区可能存在造山型金矿,继而老矿山接替资源勘查在平水铜矿布置了10个坑内钻孔,其中9个见矿,成功的在平水深部发现两层金矿体和一层铜矿体。金矿体严格的受韧性剪切带的控制;金矿石有明显的宏观和微观韧性变形结构;矿石矿物主要是自然金和少量的黄铁矿,脉石矿物主要有石英、绢云母、绿泥石、碳酸盐和白云石。本文主要对平水金矿体开展流体包裹体研究,结合矿床地质特征,最终确定金矿体成因类型,为平水地区下一轮深边部找矿勘查提供依据。     

SAR图像海岸线检测的区域距离正则化几何主动轮廓模型

合成孔径雷达(SAR)卫星遥感图像可以极大地提高全国海岸线覆盖频率,然而受到海洋波浪所引起的随机海水表面粗糙度的影响,海岸目标与海水背景边界易混淆不清,因此本文提出了基于区域距离正则化几何主动轮廓模型(RDRGAC),引入距离正则项,解决重复初始化水平集函数为符号距离函数的问题,提高了算法收敛速度。此外,将区域面积项系数与SAR图像等效视数(ENL)建立非线性拟合关系,实现RDRGAC模型根据不同SAR遥感图像的自适应调整,改善海岸线自动提取精度。通过河北省北戴河和大连市金州湾SAR数据海岸线提取对比试验,验证了所提方法的有效性。     

声呐合成孔径干涉测量的研究现状与进展

针对合成孔径声呐是一种新型高分辨水下成像声呐,尤其是其干涉测量是一种高精度测量海底地形的先进技术,具有很大的应用前景,但是目前尚还没有得到广泛应用的问题,详细分析了声呐合成孔径干涉测量近期的研究现状与研究进展情况。该文在声呐合成孔径干涉测量原理的基础上,比较了与合成孔径雷达干涉的不同,重点阐述了相关理论和设备的研究现状和进展,同时分析了现在声呐合成孔径干涉测量所存在的主要问题,最后介绍了目前声呐合成孔径干涉测量的研究展望。     

宁波市地下空间开发利用地质环境适宜性评价

随着城市化建设快速推进,地下空间资源开发是解决城市土地资源紧张的合理途径,而地质环境适宜性评价对地下空间的开发利用具有至关重要的作用。本文分析了城市地下空间开发利用地质环境适宜性评价的影响因素,运用层次分析法确定岩土体特征、水文地质条件、环境地质问题、技术经济等指标因素的权重,建立模糊综合评价模型,定量评价宁波东部新城浅层(-15~0m)和中层(-30~-15m)的地下空间开发利用地质环境适宜程度。评价结果显示,东部新城地下空间开发地质环境适宜性等级分为Ⅱ级较适宜和Ⅲ级较不适宜,并根据不同的适宜等级提出了地下空间开发利用方式,为宁波东部新城的地下空间开发利用提供依据。     

一种基于Curvelet变换的合成孔径雷达海洋内波图像的斑点噪声抑制方法

合成孔径雷达是海洋内波研究中最重要的工具之一。雷达图像中的斑点噪声会严重降低图像的质量,这一问题在处理和分析信号较弱的二模态内波信号和上升型内波信号时极为明显。合成孔径雷达图像中的海洋内孤立波的信号具有明显的尺度性和方向性。同时,curvelet变换作为一种同时具备尺度分辨率和方向分辨率的数学变换,能够对一幅雷达图像在不同尺度、不同方向和不同位置上进行分析。本文给出了一个基于curvelet变换的合成孔径雷达海洋内孤立波图像的斑点噪声抑制方法。该方法可简述为：(1)对一幅合成孔径雷达海洋内孤立波图像进行curvelet变换,获得curvelet系数;(2)分别仅仅保留一个尺度的系数,将其它尺度的系数置为零,利用处理之后的系数分别重建图像,得到仅仅用一个尺度的系数重建的图像;(3)分别计算上一步中得到的图像的均方差,根据波浪理论,图像的方差代表能量,方差越大则能量越大,以此可以确定内波信息集中的尺度;(4)在每个尺度下,分别计算每个方向的curvelet系数矩阵的平均值,以此确定内孤立波信号集中的方向;(5)在上两步工作的基础上,仅仅保留内波信号集中的尺度和方向的系数,而将其它尺度和方向的系数置为0,得到一幅提取主波信息的图像;(6)将上一步得到的提取主波信息的图像加回到原始图像中,从而达到增强波浪信息并抑制斑点噪声的目的。大量的实验验证表明,该方法不仅能有效地压制斑点噪声,而且能有效地增强波浪信号。