In situ time resolved synchrotron powder diffraction study of thaumasite

Structural changes during dehydration and subsequent decomposition in thaumasite Ca₃Si(SO₄)(CO₃)(OH)₆·12 H₂O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P6₃ space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass.     

基于立体补偿的遥感立体像对压缩方法

提出研究遥感立体像对的压缩问题。主要讨论了左右影像的视差补偿和辐射补偿。针对遥感立体像对视差分布不均以及左右影像存在辐射差的特点,提出了一种基于立体补偿的遥感立体像对压缩算法。该算法以左片为基准图像,采用自适应视差估计计算出右片的视差矢量,结合辐射校正和重叠块视差补偿技术得到平滑的右片的预测图像,以右片减去预测图像得到残差图像,然后采用小波压缩算法对残差图像进行压缩。实验结果表明,该算法能显著提高遥感立体像对的压缩性能。     

五道梁地区总辐射的年际变化

利用实测的太阳总辐射通量密度及地气温差资料，建立了月平均地气温差与月平均太阳总辐射通量密度的回归方程，并用该回归方程计算了五道梁地区1980-1993年共14年的月平均总辐射通量密度，分析了该地区总辐射通量密度的年际变化，发现该地区总辐射通量密度具有较明显的6～7年的振荡周期。20世纪后10年年平均总辐射通量密度有增大的趋势。     

青藏高原云-辐射-加热效应和南亚夏季风--1985年与1987年对比分析

文中首先利用NCEP NCAR再分析的风场资料 ,分析了南亚夏季风的时空特征 ,选取了有代表性的典型强、弱夏季风年 ,继而利用ISCCP C2、ERBE S4卫星观测资料和NCEP NCAR再分析资料 ,对比分析了强、弱夏季风前期青藏高原地区的云—辐射—加热状况及其在海、陆差异中的作用。分析结果表明 ,南亚夏季风强或弱 ,其前期青藏高原地区的云—辐射—加热效应有明显的差异。在强 (弱 )南亚夏季风的前期 ,青藏高原大部分地区为相对少 (多 )云区 ,其云量变化不仅表明了此区的云—辐射—加热效应的不同 ,更重要的是与此同时出现的海、陆之间云量分布的“跷跷板”现象 ,进一步改变了海、陆之间的热力差异。而且 ,在强南亚夏季风年 ,这种热力差异不但开始得早 ,而且持续时间长、作用范围大 ,从而对南亚夏季风的形成和变化产生重要的影响     

ARTIFICIAL NEURAL NETWORK CORRECTION OF ROUGH ERRORS OF OBSERVATIONS

In the context of tower measured radiation datasets.following the correction principle meetinga diagnostic equation in data quality control and in terms of a technique for model construction ondata and ANN(artificial neural network)retrieval for BP correction of radiation measurementswith rough errors available,a BP model is presented.Evidence suggests that the developed modelworks well and is superior to a convenient multivariate linear regression model,indicating its wideapplications.     

PRELIMINARY NUMERICAL STUDY OF TOPOGRAPHIC EFFECTS OF THE TIBETAN PLATEAU ON SURFACE DIRECT RADIATION*

To improve the simulating ability of a model,this paper presents a scheme of calculating direct radiation at land surface with topography in the model.A numerical study is conducted for the topographic effects of the Tibetan Plateau on the direct radiation using NCEP terrain data.Results show that,after taking account into the topographic radiation effect,the regional average of the radiation over the Plateau obviously increases in the local early morning and late afternoon,but changes less around noon.The effect is stronger in winter than that in summer.And heterogeneous topography has also affected the distribution of the radiation in this area.A simple numerical experiment shows that considering the effect will lead ground temperature to increase on the slope having more sunshine,and vice versa.     

ARTIFICIAL NEURAL NETWORK CORRECTION OF ROUGH ERRORS OF OBSERVATIONS*

In the context of tower measured radiation datasets.following the correction principle meeting a diagnostic equation in data quality control and in terms of a technique for model construction on data and ANN (artificial neural network) retrieval for BP correction of radiation measurements with rough errors available,a BP model is presented.Evidence suggests that the developed model works well and is superior to a convenient multivariate linear regression model,indicating its wide applications.     

PRELIMINARY NUMERICAL STUDY OF TOPOGRAPHIC EFFECTS OF THE TIBETAN PLATEAU ON SURFACE DIRECT RADIATION

To improve the simulating ability of a model,this paper presents a scheme of calculatingdirect radiation at land surface with topography in the model.A numerical study is conducted forthe topographic effects of the Tibetan Plateau on the direct radiation using NCEP terrain data.Results show that,after taking account into the topographic radiation effect,the regional averageof the radiation over the Plateau obviously increases in the local early morning and late afternoon,but changes less around noon.The effect is stronger in winter than that in summer.Andheterogeneous topography has also affected the distribution of the radiation in this area.A simplenumerical experiment shows that considering the effect will lead ground temperature to increase onthe slope having more sunshine,and vice versa.     

基于DEM的黄河流域天文辐射空间分布

基于1 km×1 km分辨率的数字高程模型(DEM) 数据,利用建立的起伏地形下天文辐射分布式计算模型,计算了黄河流域1 km×1 km分辨率各月天文辐射的空间分布。结果表明:局部地形对黄河流域年和四季天文辐射的空间分布影响明显;在太阳高度角较低的冬季,地理和地形因子对天文辐射的影响相当强烈,山区天文辐射的空间差异大,1月份向阳山坡(偏南坡) 天文辐射可为背阴山坡(偏北坡) 的2~3倍,极端天文辐射的差异可达10倍以上;而在太阳高度角较高的夏季,天文辐射空间差异较小,7月份不同地形极端天文辐射的差异仅在16%左右;四季中,地形对天文辐射影响的程度为冬季>秋季>春季>夏季。