Preliminary Study on the Chemical Mapping of Individual Fluid Inclusion by Synchrotron X-ray Fluorescence Microprobe

Abstract: Synchrotron X-ray fluorescence analyses on individual hypersaline fluid inclusions were tested to using synchrotron source at Tsukuba (KEK), Japan. The XRF instrumentation at KEK meets the purpose of fluid inclusion analysis, nondestructive, multi–element, ppm detection limits, with micro spatial resolution. In practice, however, the quantitative chemical analysis of fluid inclusion requires further considerable data accumulation. Semi-quantitative distribution of elements (mass number > 25) in single fluid inclusion was obtained.     

In situ time resolved synchrotron powder diffraction study of thaumasite

Structural changes during dehydration and subsequent decomposition in thaumasite Ca₃Si(SO₄)(CO₃)(OH)₆·12 H₂O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P6₃ space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass.     

The Study Internal Structure of the Annual Layers in Lake Sediments Using Synchrotron Radiation with X-ray Focusing Optics

正1 Introduction Annually laminated(varve)sedimentary deposits are considered as one of the most important archives,since they offer precise temporal information(years)in combination with high time resolutions.Bottom sediments of the lakes contain detailed geochemical information on     

南京粉细砂空间孔隙结构表征单元体确定

确定统一的表征单元体(REV)尺寸是研究土体细观孔隙结构时首先需要解决的问题。使用6.5μm分辨率同步辐射显微CT扫描南京粉细砂试样,从土样三维重构模型的5个代表性部位提取5组立方体孔隙REV,对每个REV采用最大球算法分析,建立孔隙网络模型,从中提取孔隙率、单位体积孔隙数、孔隙平均体积、孔隙最小体积、孔隙最大半径、孔隙最小半径、孔隙平均半径、孔隙截面积平均形状因子等8个孔隙结构参数,建立其与REV尺寸间的相关性。利用假设检验T检验和F检验,最终确定样品孔隙结构参数的统一REV边长尺寸为400像素,即2.60mm。该方法可用于砂土、粉土等颗粒土体细观孔隙结构分析。     

北京同步辐射装置准直测量控制网的设计与优化

在北京同步辐射装置升级改造中,为提高元件的安装精度,同时兼顾未来新增光束线的建设需要,在实验大厅建立了准直测量控制网,作为设备定位、调校、安装和变形监测等工作的基础。本文重点介绍该控制网的设计、优化与观测结果分析,特别阐述了激光精密测量技术的应用,以及对点位密度、测量精度及可靠性的控制。     

Gamma暴余辉的相对论流体动力学演化和光变曲线

本文首先对Gamma暴的观测特性和物理过程作了简要的介绍 ,而后 ,对火球模型的相对论流体动力学机制和同步加速辐射机制作了论述。主要工作是 :具体研究火球所抛出壳层的相对论流体动力学演化 ,应用同步加速辐射机制 ,通过由共动坐标系到实验室坐标系的相对论变换 ,得到Gamma暴余辉的光变曲线。对于火球壳层的不同的动力学演化规律 ,各向同性或各向异性的壳层抛出形式 ,以及不同的外部介质环境 ,所得到的光变曲线都各不相同。通过对这些不同的光变曲线的比较 ,明确了Gamma暴余辉的整体的物理演化图象以及各种物理过程在Gamma暴余辉演化过程中所起的作用 ,并从余辉演化的方面进一步理解了Gamma暴的物理本质     

Comparison of Synchrotron Radiation X-Ray Fluorescence with Conventional Techniques for the Analysis of Sedimentary Samples

A comparison is made of elemental analyses of sediment samples (lake bottom sediments and sediments from the petroliferous Bazhenovka Formation) by five competitive methods (synchrotron radiation X-ray fluorescence (SR-XRF), INAA, ICP-MS, AAS and traditional XRF). The object of this study was to identify the most suitable analytical techniques for applications in sedimentary geochemistry. Advantages and shortcomings of the five techniques were considered with respect to applications related to studies of palaeo-climate changes recorded in sedimentary cores from Lake Baikal and the geochemical stratigraphy of the Bazhenovka Formation, which is rich in organic material. We have concluded that SR-XRF was the best technique for producing extensive analytical data series, from the point of view of its speed, ease of application, cost, non-destructive nature and sensitivity, which allowed for the simultaneous determination of more than twenty elements of geochemical interest in small samples of sediments. An additional benefit of the method was demonstrated when used for the independent certification of geological reference materials. International reference samples BIL-1 and SDO-1 were certified by means of this method without use of reference materials. Analyses were based on the physics of the theory of energy transport.     

Multi-Wavelength Synchrotron Radiation XRF Determination of U and Th in Sedimentary Cores from Lake Baikal

A new technique for the determination of uranium and thorium in lacustrine sediments is based on non-destructive synchrotron radiation X-ray fluorescence analysis (SR-XRF) of sediment samples using monochromatic beams of different energies as excitation sources, with the recording and subsequent iterative processing of the X-ray fluorescence spectra. The technique has a multielement capability and enables fast, simultaneous analysis of a few tens of elements. The proposed SR-XRF technique was tested against INAA and ICP-MS methods and showed a number of advantages with a generally good correlation of results by the three methods. Uranium and Th profiles have been measured at a time resolution of 2 kyr in a drill core (BDP-96) from Lake Baikal bottom sediments deposited between 780 and 40 kyr B P. During this time span, peaks in the U and U/Th concentration marked warm climates. Oscillations of U and U/Th in Baikal bottom sediments during the Brunhes chron reflect climate-induced global change in the volume of polar ice, controlled by long-term cyclicity of the Earths orbital parameters. The response of these warm periods is similar to that observed earlier in shorter cores that span the two last interglacials (220-0 kyr BP).     

Electron Probe Microanalysis of Bromine in Minerals and Glasses with Correction for Spectral Interference from Aluminium,and Comparison with Microbeam Synchrotron X‐Ray Fluorescence Spectrometry

The strong spectral interference between Br‐ and Al‐induced X‐ray lines hampers the utilisation of electron probe microanalysis (EPMA) for measuring Br mass fractions in Al‐bearing minerals and glasses. Through measuring Br‐free Al‐bearing materials, we established an EPMA method to quantify the overlap from AlKα on BrLβ, which can be expressed as a linear function of the Al₂O₃ content. The count rate of the BrLβ peak signal was enhanced by high beam currents and long measurement times. Application of this EPMA method to Al‐ and Br‐bearing materials, such as sodalite and scapolite, and to five experimental glasses yielded Br mass fractions (in the range of 250–4000 μg g^?1) that are consistent with those measured by microbeam synchrotron X‐ray fluorescence (μ‐SXRF) spectrometry. The EPMA method has an estimated detection limit of ~ 100–300 μg g^?1. We propose that this method is useful for measuring Br mass fractions (hundreds to thousands of μg g^?1) in Al‐bearing minerals and glasses, including those produced in Br‐doped experiments. In addition, the natural marialitic scapolite (ON70) from Mpwapwa (Tanzania) containing homogeneously distributed high mass fractions of Br (2058 ± 56 μg g^?1) and Cl (1.98 ± 0.03% m/m) is an ideal reference material for future in situ analyses.