比值—特征主成分混合分析提取金矿蚀变信息：以赣南遂川地区为例

在分析与金矿有关的两类蚀变岩的ＴＭ波谱特征的基础上,以赣南遂川地区为实验区,利用比值－特征主成分混合分析进行了金矿蚀变岩信息提取,为找矿预测和野外工作指明了方向。     

海沟金矿区脉岩特征及其与金矿成矿关系

海沟金矿区脉岩发育,主要类型有闪长玢岩、次安山岩、徨绿岩、正长闪长玢岩,按其与矿脉穿切关系划分为矿脉就位前脉岩、就位后脉岩,它们的地球化学特征表明这些脉岩具有良好的同源演化关系,它们不仅与成矿具有密切的时空关系,而且为金矿成矿带来成矿流体和部分成矿物质.     

Alteration and mineralization styles of the orogenic disseminated Zhenyuan gold deposit,southeastern Tibet: Contrast with carlin gold deposit

Orogenic disseminated and Carlin gold deposits share much similarity in alteration and mineralization.The disseminated orogenic Zhenyuan Au deposit along the Ailaoshan shear zone,southeastern Tibet,was selected to clarify their difference.The alteration and mineralization from the different lithologies,including meta-quartz sandstone,carbonaceous slate,meta-(ultra)mafic rock,quartz porphyry and lamprophyre were researched.According to the mineral assemblage and replacement relationship in all types of host rocks,two reactions show general control on gold deposition:(1)replacement of earlier magnetite by pyrite and carbonaceous material;(2)alteration of biotite and phlogopite phenocrysts in quartz porphyry and lamprophyre into dolomite/ankerite and sericite.Despite the lamprophyre is volumetrically minor and much less fractured than other host rocks,it contains a large portion of Au reserve,indicating that the chemically active lithology has played a more important role in gold precipitation compared to structure.LA-ICP-MS analysis shows that Au mainly occurs as invisible gold in fine-grained pyrite disseminated in the host rocks,with Au content reaching to 258.95 ppm.The diagenetic core of pyrite in meta-quartz sandstone enriched in Co,Ni,Mo,Ag and Hg is wrapped by hydrothermal pyrite enriched in Cu,As,Sb,Au,Tl,Pb and Bi.Different host rock lithology has much impact on the alteration and mineralization features.Carbonate and sericite in altered lamprophyre show they have higher Mg than those developed in other of host rocks denoting that the carbonate and sericite incorporated Mg from phlogopite phenocrysts in the primary lamprophyre during alteration.The ore fluid activated the diagenetic pyrite in meta-quartz sandstone leading the hydrothermal pyrite enriched in Cu,Mo,Ag,Sb,Te,Hg,Tl,Pb and Bi,but the hydrothermal pyrite in meta-(ultra)mafic rock is enriched in Co and Ni as the meta-(ultra)mafic rock host rock contain high content of Co and Ni.However,Au and As shear similar range in both types of host rocks indicating that these two elements most likely come from the deep source fluid rather than the host rocks.It was shown in the disseminated orogenic gold deposit that similar hydrothermal alteration with mineral assemblage of carbonate(mainly dolomite and ankerite),sericite,pyrite and arsenopyrite develops in all types of host rocks.This is different from the Nevada Carlin type,in which alteration is mainly dissolution and silicification of carbonate host rock.On the other hand,Au mainly occur as invisible gold in both disseminated orogenic and Carlin gold deposits.     

新疆西南天山阿万达金矿区赋矿围岩物源及形成时代:碎屑锆石U-Pb年代学制约

阿万达金矿位于西南天山造山带内。此次研究在简要总结其矿床地质特征基础上,对与阿万达金矿成矿密切相关的阿克苏群中硅质片岩围岩分别进行了岩石地球化学分析和LA-ICP-MS碎屑锆石U-Pb定年研究,以期对围岩的沉积环境、物源及形成时代进行讨论。岩石地球化学分析结果显示,阿万达金矿赋矿围岩中硅质片岩的原岩可能为一套成熟度较低的泥岩或砂岩,物源主要为石英岩质沉积物,沉积环境可能处于活动大陆弧内的沉积盆地内。U-Pb定年结果显示,其碎屑锆石定年数据主要形成了加权平均年龄值为405 Ma或406 Ma的年龄峰,其谐和年龄最小峰值即405 Ma可以作为其最大沉积年龄。因此笔者认为阿克苏群中硅质片岩的沉积时代并不是前人所定的长城纪,而是不老于早泥盆世。另外,这一地层的物源组成具有多样性,～405 Ma碎屑锆石占主体,可能与哈尔克山北缘火山弧内的早泥盆世岩浆活动有关;～745Ma的碎屑锆石的出现,表明其物源有少部分来自新元古代岩石;极少数～2.50 Ga的碎屑锆石的出现,反映了华北地台对本地层有物源上的贡献。     

云南东川区播卡金矿地球化学分带模式及深部隐伏矿体预测

为了探索播卡深部的找矿空间及找矿方向,本文在播卡矿区钻孔样品分析数据的基础上,研究了播卡金矿床的元素富集规律、元素组合、元素异常在地表及空间的分布特征,建立了播卡金矿的原生晕分带模型、地球化学勘查模式,提出了不同深度的原生晕判别指标,在此基础上对播卡金矿的深部隐伏矿体进行了预测。结果显示播卡金矿的深部及邻区具有寻找隐伏矿体的良好前景。     

LA-ICP-MS in situ analyses of the pyrites in Dongyang gold deposit,Southeast China: Implications to the gold mineralization

The Dongyang gold deposit is a newly discovered epithermal deposit in Fujian Province, Southeast China, along the Circum-Pacific metallogenic belt. Herewith, the authors present mineralogical, scanning electron microscope, and laser ablation inductively coupled clasma mass spectrometry analysis to reveal the relations between Au and Te, As, S, Fe, etc., and discuss the gold precipitation process. The pyrites in this deposit are Fe-deficient, and are enriched in Te and As. The authors infer that As was mainly in form of As-complexes, and Te-Au-Ag inclusions/solid solution also exsits in the Py I. Along with the depletion of Te and As, they were less active chemically in the Py II, and Au may be incorporated into As-rich and Fe-deficient surface sites by chemisorption onto As-rich growth surfaces. Because of the incorporation of new fluid, Te and As became the most active chemically in the Py III, which was the main elements precipitation stage, and As dominantly substituted for S in the lattice of pyrite, due to the more reducing condition. The authors propose Au was in form of invisible gold, and the incorporation of gold can be considered as post-pyrite event, while the Au-bearing minerals were result of post incorporation of gold in arsenian pyrite.     

湘、黔下寒武统黑色岩系型Ni、Mo矿床中有机质与PGE成矿作用研究

湘、黔地区张家界、遵义一带分布有黑色岩系型Ni-Mo-PGE矿床,测试分析表明黑色页岩样品铂族元素含量特征参数∑PGE、Ln(Pd/Pt)、(Ru/Ir)×(Pd/Pt)、Ln[(Ru/Ir)×(Pd/Pt)]均与有机质含量特征参数有较好的相关性.趋势分析显示,铂族元素含量特征参数Ln[(Ru/Ir)×(Pd/Pt)]与总有机碳含量特征参数Ln(Corg)有很好的线性相关,线性相关公式为y=0.4762x-1.1316,相关系数R为0.7584,说明该参数为一稳定性参数,主要受有机质总量决定,集中反映了生物制约性.而与湖南张家界样品有机碳含量Ln(Corg)与铂族元素含量∑PGE同步正消长关系不一样,即贵州遵义地区铂族元素总量∑PGE与有机碳含量的相关性表现出的不一致的规律,可以解释为后生期的热事件(印支海西期,Rb-Sr等时线年龄277±37Ma)导致有机质干酪根的高成熟化、大量生过气(C>2%)和石墨化趋势,或者说是芳构化效应改变了源岩有机质而导致了有机质的损耗.     

湖南宝山矿床花岗岩类硫-铅同位素和流体包裹体研究及其成因意义

宝山铜铅锌多金属矿床是湖南重要的铅锌生产基地。矿床内矽卡岩型铜(钼)矿化受侏罗纪花岗闪长斑岩的控制,而主要的铅锌矿体则产于远离岩体的碳酸盐地层中,且缺乏可靠的矿化年龄限制。为了查明宝山铅锌矿体与花岗闪长斑岩之间的成因关系,文章对宝山花岗岩类中浸染状黄铁矿的硫同位素和钾长石的铅同位素,以及铅锌矿石萤石脉石的流体包裹体进行了测试和研究,并与前人报道的铅锌硫化物矿石的硫、铅同位素进行了对比,尝试为宝山铅锌矿化的物质来源及成因提供依据。研究表明,花岗闪长斑岩中浸染状黄铁矿的δ34S值为+1.5‰~+3.5‰,与铅锌矿石硫化物(方铅矿、闪锌矿及黄铁矿)相一致;同时,花岗岩类中钾长石的铅同位素组成206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别为18.4789~18.7668、15.6835~15.7220和38.7903~39.1035,具有壳源的特征,且与铅锌矿石硫化物的铅同位素分布范围相吻合。宝山矿床的硫、铅同位素特征表明,花岗闪长斑岩应是铅锌矿化的主要硫源及金属来源。宝山矿床铅锌矿石萤石中的流体包裹体具有低温(130~150℃)、低盐度(8%)的特征,可能是岩浆热液演化到晚期的产物。结合已有的有关资料加以对比和分析,研究认为,宝山铅锌矿床的成矿物质应来源于花岗闪长岩的岩浆期后热液,在热液演化晚期迁移到远端地层中沉淀,形成了宝山的主要铅锌矿体。     

长江中下游成矿带钨矿床

长江中下游成矿带是我国重要的铜-铁-金多金属成矿带,近年来在长江中下游成矿带内发现多处白钨矿床和矿化点,为该成矿带的成矿学研究提供了新的研究课题。相比成矿带铜铁金多金属矿床研究程度,钨矿床成矿作用研究明显薄弱,尚未进行系统的成矿作用和成矿规律总结。成矿带内发育的钨矿床主要为北亚带的东顾山矿床、主带(中亚带)的阮家湾矿床和南亚带的桂林郑矿床和高家塝矿床。本文对这四个钨矿床及几个含钨矿床的地质和地球化学特征、成岩成矿时代、成矿岩体地球化学特征等方面的研究资料和成果进行了总结,讨论和试图阐明长江中下游成矿带钨矿床的成矿作用。研究显示,长江中下游成矿带存在三期钨成矿作用,分别为146～143Ma、127Ma和97Ma,在成矿带的铜主成矿期前和铁成矿期均有钨成矿作业发生。钨矿床中白钨矿的Sr-Nd同位素组成分别落入董岭式基底或江南式基底范围,表明长江中下游成矿带的董岭式和江南式基底是形成原始含矿岩浆的物质基础。长江中下游成矿带的钨矿床成矿岩体为中酸性岩,ε_(Hf)(t)值很低,且Zr/Hf、K/Rb比值小,表明成钨岩浆岩为古老地壳物质重熔并经历了较充分的分异演化,对比成矿带中成铜、成铁岩体,源区性质可能是导致长江中下游成矿带金属成矿差异的根本原因。燕山期的陆内俯冲是造成长江中下游成矿带钨矿床成矿的主导机制。