大别造山带毛屋岩体的解体及古地幔性质的厘定

根据详细的地球化学 (特别是稀土元素地球化学 )的研究资料 ,提出大别造山带毛屋岩体应该解体。毛屋岩体不是由多幕式镁铁 超镁铁质层状堆晶作用形成的一套岩石系列 ,而是由橄榄岩类、含石榴石方辉岩类、榴辉岩类和绿辉石岩类组成的一个混杂岩体。其中含石榴石方辉岩类与绿辉石岩类之间存在成因上的联系 ,含石榴石方辉岩类的原岩是本区原始地幔经约36 %的部分熔融后剩下的残余 ,而绿辉石岩的原岩是由该熔融体结晶的产物。根据含石榴石方辉岩与绿辉石岩之间的成分制约关系 ,对该区古地幔的稀土元素组成和地幔性质进行了反演 ,结果表明 ,该区原始地幔稀土元素成分与球粒陨石中的相似 ,为轻稀土略亏损的平坦型组成模式 ;该区原始地幔矿物成分为橄榄石 (72 8% )、单斜辉石 (12 4% )和石榴石 (14 8% ) ,属含单辉石榴橄榄岩的地幔。     

Ultrahigh-pressure metamorphism in the forbidden zone: the Xugou garnet peridotite, Sulu terrane, eastern China

The Xugou garnet peridotite body of the southern Sulu ultrahigh‐pressure (UHP) terrane is enclosed in felsic gneiss, bounded by faults, and consists of harzburgite and lenses of garnet clinopyroxenite and eclogite. The peridotite is composed of variable amounts of olivine (Fo₉₁), enstatite (En_92?93), garnet (Alm_20?23Prp_53?58Knr_6?9Grs_12?18), diopside and rare chromite. The ultramafic protolith has a depleted residual mantle composition, indicated by a high‐Mg number, very low CaO, Al₂O₃ and total REE contents compared to primary mantle and other Sulu peridotites. Most garnet (Prp_44?58) clinopyroxenites are foliated. Except for rare kyanite‐bearing eclogitic bands, most eclogites contain a simple assemblage of garnet (Alm_29?34Prp_32?50Grs_15?39) + omphacite (Jd_24?36) + minor rutile. Clinopyroxenite and eclogite exhibit LREE‐depleted and LREE‐enriched patterns, respectively, but both have flat HREE patterns. Normalized La, Sm and Yb contents indicate that both eclogite and garnet clinopyroxenite formed by high‐pressure crystal accumulation (+ variable trapped melt) from melts resulting from two‐stage partial melting of a mantle source. Recrystallized textures and P–T estimates of 780–870 °C, 5–7 GPa and a metamorphic age of 231 ± 11 Ma indicate that both mafic and ultramafic protoliths experienced Triassic UHP metamorphism in the P–T forbidden zone with an extremely low thermal gradient (< 5 °C km^?1), and multistage retrograde recrystallization during exhumation. Develop of prehnite veins in clinopyroxenite, eclogite, felsic blocks and country rock gneiss, and replacements of eclogitic minerals by prehnite, albite, white mica, and K‐feldspar indicate low‐temperature metasomatism.     

New Reference Materials and Assessment of Matrix Effects for SIMS Measurements of Oxygen Isotopes in Garnet

Accurate ion microprobe analysis of oxygen isotope ratios in garnet requires appropriate reference materials to correct for instrumental mass fractionation that partly depends on the garnet chemistry (matrix effect). The matrix effect correlated with grossular, spessartine and andradite components was characterised for the Cameca IMS 1280HR at the SwissSIMS laboratory based on sixteen reference garnet samples. The correlations fit a second‐degree polynomial with maximum bias of ca. 4‰, 2‰ and 8‰, respectively. While the grossular composition range 0–25% is adequately covered by available reference materials, there is a paucity of them for intermediate compositions. We characterise three new garnet reference materials GRS2, GRS‐JH2 and CAP02 with a grossular content of 88.3 ± 1.2% (2s), 83.3 ± 0.8% and 32.5 ± 3.0%, respectively. Their micro scale homogeneity in oxygen isotope composition was evaluated by multiple SIMS sessions. The reference δ¹⁸O value was determined by CO₂ laser fluorination (δ¹⁸O_LF). GRS2 has δ¹⁸O_LF = 8.01 ± 0.10‰ (2s) and repeatability within each SIMS session of 0.30–0.60‰ (2s), GRS‐JH2 has δ¹⁸O_LF = 18.70 ± 0.08‰ and repeatability of 0.24–0.42‰ and CAP02 has δ¹⁸O_LF = 4.64 ± 0.16‰ and repeatability of 0.40–0.46‰.     

P-T Paths Derived from Garnet Growth Zoning in Danba Domal Metamorphic Terrain, Sichuan Province, West China

Danba (丹巴) domal metamorphic terrain belongs to Songpan (松潘)-Ganze (甘孜) orogenic belt, where typical Barrovian and Buchan metamorphic zones are preserved. The former included chlorite, biotite, garnet, staurolite, kyanite and sillimanite zones, while the latter only developed silimanite+muscovite and sillimanite+K-feldspar zones. Integrated study has been carried on metamorphic reactions of garnet production and consumption, P-T paths and P-T-X-M phase relation and thermal tectonic model for Danba metamorphic zones. Petrological textures in thin sections show that garnet production and consumption in kyanite-sillimanite zone is mainly attributed to ChI+Ms+PI+Q=Grt+Bt+H2O and kyanite=sillimanite respectively. Based on mineral compositions, the geothermobarometry gives an average P, T condition of (4.9±0.3)×108 Pa, 543±30℃ for the first growth stage of the garnet and (5.8±0.3)±108 Pa, 534±29 ℃ for the second stage of garnet growth respectively. Anti-counter clockwise P-T paths were drawn using Gibbs method by NCMnKFMASH system for sample G98686 in the kyanite zone. The P-T-X-M modeling for the first mineral assemblages shows that the prediction is similar to the measured values in gossular, almandine and spessartine but mole fraction of pyrope and Fe/(Fe+Mg) deviated far from the contours; while that for the second mineral assemblages exhibits that the prediction is consistent with the measured value of pyrope, grossular content and Fe/(Fe+Mg) of garnet. A thermal tectonic model that there are at least three structure levels across the thrnst-decollement zones is presented according to the P-T paths, metamorphic grades and deformation styles for the staurolite-kyanite zone of the Barroviau type metamorphism, which will provide some constraints for the evolution of the nappe complex.     

徐淮地区镁铁质岩石捕虏体单斜辉石中石榴石和石英的出溶

徐淮地区早侏罗世侵入杂岩中榴辉岩,石榴辉石岩和单斜辉石岩捕虏体单斜辉石中可以观察丰富的出溶石英针和石榴石,黝帘石及角闪石的出溶叶片,榴辉岩中出溶石英针的绿辉石核部比其边部相对富含FeO和MgO,贫SiO2,Al2O3和CaO。在石榴辉石岩和单斜辉石岩捕虏体中具有出溶石榴石的单斜辉石。从靠近出溶石榴石的一侧向其核部,Al2O3,Na2O和TiO2含量降低,MgO,SiO2和CaO含量增加,单斜辉石中定向石英针的出溶表明曾经存在有超高压条件下（≥25×10^8Pa)稳定的过硅质绿辉石。单斜辉石中出溶石榴石表明温压条件的降低可能是引起出溶的一个主要原因,捕虏体中的矿物组合和岩相学特征表明它们曾经遭受了榴辉岩相和角闪岩相退化变质作用,这与因压力和温度降低引起矿物出溶的结果相吻合。     

赣中周潭群变质沉积岩的微量元素地球化学研究

对赣中周潭群变质沉积岩及其石榴子石等造岩矿物的稀土元素地球化学进行了详细研究.结果表明:造岩矿物只携载了岩石中少部分稀土元素,而大部分稀土元素赋存在副矿物的晶格中;变质过程中稀土元素在石榴子石变斑晶与岩石间达到了分配平衡,石榴子石/岩石间的稀土元素分配明显受体系化学组成所制约;变质岩脉及其矿物的稀土元素组成显示清楚的四重效应,其Zr-Hf,U-Th和Y-Ho等元素对也与变质岩发生了一定程度的分异,它们可作为周潭群在变质过程中流体作用存在的判别标志.     

郯庐断裂带(安徽段)内磁铁石榴角闪岩的形成条件、年代学及构造归属的探究

通过对肥东群南缘特征性岩石——磁铁石榴角闪岩的构造地质学和岩相学研究表明,磁铁石榴角闪岩及其围岩以构造透镜体形式产出,该变质岩具有两个阶段变质矿物组合,热力学评价显示①阶段的温压范围为：T=616~700℃和P=0.66~0.85GPa,平均温压为T=653±35℃和P=0.75±0.09GPa。②阶段的温压范围为：T=597~643℃和P=0.51~0.94GPa,平均温压为T=620±15℃和P=0.73±0.15GPa,并表现出一个快速等压降温P-T演化特征。锆石U-Pb定年和拉曼光谱分析表明,该磁铁石榴角闪岩的变质年龄为2469±49Ma。结合地质背景和前人的研究,可以判定该类岩石可能源于华北板块。由于郯庐断裂的左旋走滑作用被构造并置与扬子板块中。从而进一步推测,郯庐断裂（安徽段）横向宽度可达到10~15km。     

Petrochemical constraints for dual origin of garnet peridotites from the Dabie-Sulu UHP terrane, eastern-central China

Garnet peridotites occur as lenses, blocks or layers within granulite–amphibolite facies gneiss in the Dabie-Sulu ultra-high-pressure (UHP) terrane and contain coesite-bearing eclogite. Two distinct types of garnet peridotite were identified based on mode of occurrence and petrochemical characteristics. Type A mantle-derived peridotites originated from either: (1) the mantle wedge above a subduction zone, (2) the footwall mantle of the subducted slab, or (3) were ancient mantle fragments emplaced at crustal depths prior to UHP metamorphism, whereas type B crustal peridotite and pyroxenite are a portion of mafic–ultramafic complexes that were intruded into the continental crust as magmas prior to subduction. Most type A peridotites were derived from a depleted mantle and exhibit petrochemical characteristics of mantle rocks; however, Sr and Nd isotope compositions of some peridotites have been modified by crustal contamination during subduction and/or exhumation. Type B peridotite and pyroxenite show cumulate structure, and some have experienced crustal metasomatism and contamination documented by high ⁸⁷Sr/⁸⁶Sr ratios (0.707–0.708), low ε_Nd( t ) values (−6 to −9) and low δ¹⁸O values of minerals (+2.92 to +4.52). Garnet peridotites of both types experienced multi-stage recrystallization; some of them record prograde histories. High- P–T  estimates (760–970 °C and 4.0–6.5±0.2 GPa) of peak metamorphism indicate that both mantle-derived and crustal ultramafic rocks were subducted to profound depths >100 km (the deepest may be ≥180–200 km) and experienced UHP metamorphism in a subduction zone with an extremely low geothermal gradient of <5 °C km⁻¹.     

云南个旧锡铜矿集区石榴子石地球化学特征及成矿指示

云南高松矿床中高峰山矿段和老厂矿床中竹叶山矿段分别是个旧超大型锡铜多金属矿集区发育的典型矽卡岩型锡、铜矿段。为查明个旧矿集区锡铜成矿环境的差异,文章选取上述2个矿段矽卡岩中的石榴子石为研究对象,根据产状和矿物共生关系将石榴子石分为与高峰山花岗岩有关早期（Grt-GS1）、晚期（Grt-GS2）、与竹叶山花岗岩有关（Grt-ZS）和与玄武岩有关（Grt-ZX）共4类。电子探针（EPMA）和激光剥蚀等离子质谱（LA-ICP-MS）分析表明：Grt-GS1(Adr_10.58-20.27Grs_38.62-48.28Spe_21.06-32.37Alm_11.88-18.03)成分复杂且变化范围较大,而Grt-GS2(Adr_48.09-69.73Grs_23.84-48.87Spe_3.29-9.58)和Grt-ZS (Adr_13.97-16.06Grs_78.08-79.71Spe_2.15-2.60)成分简单且变化小;稀土元素配分曲线均呈HREE富集、LREE亏损的“左倾型”,并具明显的负Eu异常。Grt-ZX成分简单且较均一(Adr_20.12-21.99Grs_70.84-71.44Pyr_6.29-7.92),稀土元素配分曲线呈HREE亏损、LREE富集的“右倾型”,呈明显的正Eu异常,且F、Cl、U、Th、Pb、V、Cr、Co、Ni、Zn、Ti等元素含量均高于其余3类石榴子石。所有石榴子石REE³⁺与Mg²⁺的正相关性表明,REE³⁺受[X²⁺]Ⅷ-1[REE³⁺]Ⅷ+1[Y³⁺]Ⅳ-1[Y²⁺]Ⅳ+1替换机制的控制,REE³⁺主要替代Mg²⁺进入石榴子石晶格。石榴子石的U、Sn含量及稀土元素配分特征指示：高峰山石榴子石（Grt-GS1和Grt-GS2）在演化过程中氧逸度明显升高、竹叶山石榴子石（Grt-ZS和Grt-ZX）形成的氧逸度总体高于高峰山,但Grt-ZX形成时氧逸度低于Grt-ZS。稀土元素特征显示：Grt-GS1、Grt-GS2与Grt-ZS均形成于弱酸性环境,而Grt-ZX形成于近中性且富F、Cl的环境下。∑REE³⁺与Y呈良好的正相关性和REE含量变化指示4类石榴子石均形成于封闭或近封闭的体系中,在接近平衡和低水岩比的条件中受扩散交代作用缓慢生长而形成。综合研究表明,玄武岩对成矿的影响在于改变了流体性质,为成矿提供了大量微量元素（如Co、Ni、V、Cr等）和有利于成矿离子运移和富集的卤族元素（如F、Cl）,而高峰山矿段锡富集的原因可能是在演化过程中水岩反应的加强和氧逸度的升高。     

Metamorphism of the Amdo metamorphic complex,Tibet: implications for the Jurassic tectonic evolution of the Bangong suture zone

Tibet consists of several terranes that progressively collided with the southern margin of Asia during the Mesozoic following the closure of intervening ocean basins. This Mesozoic amalgamation history, as well as the extent to which it may have contributed to crustal thickening prior to the Cenozoic Indo‐Asia collision, remains poorly constrained and strongly debated. Here, we present a metamorphic petrological and U‐Pb zircon geochronological study of the Amdo metamorphic complex, one of the few exposures of high‐grade metamorphic rocks in central Tibet, located along the Bangong suture between the Qiangtang terrane to the north and the Lhasa terrane to the south. U‐Pb ages of metamorphic zircon in gneiss constrain the timing of peak metamorphism at c. 178 Ma, prior to the Early Cretaceous collision between the two terranes. Peak P–T conditions of gneiss within the metamorphic complex are constrained by conventional as well as multi‐equilibrium (THERMOCALC v.3.21 and v.3.33) geothermobarometry of two samples of garnet‐amphibolite. Whereas THERMOCALC v.3.21 yields similar results as conventional geothermobarometry, THERMOCALC v. 3.33 yields dramatically lower pressures, mostly due to the change in the amphibole activity model used. Using THERMOCALC v.3.21, the two garnet‐amphibolite samples yield similar P–T conditions of 0.83 ± 0.06 GPa at 646 ± 33 °C and 0.97 ± 0.06 GPa at 704 ± 35 °C. Plagioclase coronas on the garnet‐amphibolite sample with lower peak P–T conditions indicate a period of isothermal decompression. Additional geothermometry on two garnet‐free amphibolites yielded similar temperatures of 700–750 °C and suggests similar P–T conditions across most of the complex. However, two exposures of garnet‐kyanite schist located along the southern edge of the metamorphic complex yielded slightly lower peak conditions of 0.75–0.85 GPa and 550–610 °C. Petrographic and field relations suggest the difference in metamorphic grade between the schist and gneiss is due to an intervening thrust fault. The existence of the thrust fault indicates that at least part of the exhumation of the complex was due to contractional deformation, possibly during the Lhasa‐Qiangtang collision. Our P–T–t results indicate the occurrence of a significant Early Jurassic tectonothermal event along the southern, active margin of the Qiangtang terrane that deeply buried the Amdo rocks. We suggest that the metamorphism is a result of arc‐related tectonism that may have been regionally extensive along the southern Qiangtang terrane; geological records of this tectonism may be rarely exposed along strike because of a lack of exhumation or subsequent depositional and structural burial.