新疆东天山地区土屋和延东铜矿床斑岩叠加改造成矿作用

土屋和延东铜矿床位于东天山大南湖-头苏泉岛弧带南部,是中亚成矿带的重要组成部分。文章根据脉次穿插关系、蚀变矿物组合及矿物共生关系,将土屋和延东铜矿床均划分为斑岩成矿期、叠加改造期和表生期3个期次。土屋铜矿床的铜矿化形成于斑岩成矿期和叠加改造期,而延东铜矿床的铜矿化主要形成于叠加改造期;土屋和延东铜矿床伴生的钼矿化主要形成于叠加改造期。因此,笔者认为前人获得的辉钼矿Re-Os年龄(326.2~322.7 Ma)代表叠加改造期的成矿年龄,该期矿化与石英钠长斑岩((323.6±2.5)Ma)的侵入相关,而斑岩成矿期的矿化与斜长花岗斑岩(339~332 Ma)相关,成矿年龄为341.2~333.9 Ma。叠加改造期的存在,使得斑岩成矿期的蚀变分带可能受到了叠加和破坏。     

阿尔泰小土尔根铜矿区岩体LA-ICP-MS锆石U-Pb定年及地质意义

小土尔根是近年来阿尔泰诺尔特盆地发现的首例斑岩铜矿床,其成岩成矿年代学的研究可以对矿床模型构建、区域成矿规律的总结提供制约。矿区侵入岩发育,矿化受花岗闪长斑岩控制,少部分赋存在地层中。文章利用LA-ICP-MS锆石U-Pb测年法对矿区岩体进行了成岩年代学研究。含矿花岗闪长斑岩、黑云二长花岗岩和花岗斑岩中锆石的206Pb/238U年龄的加权平均值分别为(401.0±2.9)Ma、(398.1±2.2)Ma和(400.5±2.0)Ma,为早泥盆世同一岩浆侵入活动形成的不同侵入岩。侵入岩年龄结合凝灰岩年龄,将矿区地层划归早泥盆世诺尔特组。含矿花岗闪长斑岩锆石U-Pb年龄限定小土尔根斑岩铜矿床成矿时代略晚于401 Ma,即矿床形成于早泥盆世。     

激发极化法在辽宁本溪某矽卡岩型铜多金属矿勘查中的应用

测区燕山期大面积中酸性岩浆侵入寒武系、奥陶系碳酸盐岩,在岩体外接触带上形成大量的矽卡岩,并伴有较强烈的铜多金属矿化。本次物探工作在1∶5万区调工作基础上,采用激电中梯与激电测深两种方法进行金属矿产勘查,圈定激电异常12个,反演了穿过JD3、JD7、JD8高极化异常体的形态,规模及埋深,并解译隐伏断裂2条。结合区内地质特征与钻孔资料,认为异常区的低阻高极化体是岩体外接触带上矽卡岩化蚀变带的反映,断裂为矿液运移、容矿提供了有利条件。该研究成果表明,激发极化法是寻找矽卡岩型铜多金属矿的有效方法。     

内蒙古二连—东乌旗铜钼多金属成矿带中西段 找矿进展

二连—东乌旗成矿带位于西伯利亚板块和华北板块之间的兴蒙造山带东段,属西伯利亚板块东南南大陆边缘早古生代火山岛弧带、晚古生代二连－贺根山板块对接带。自中生代开始,区内逐渐向滨太平洋构造域发展过渡,并在中生代晚期经历了明显的由挤压构造体系向伸展构造体系的转换过程,在一系列构造演化及其相应的岩浆作用、火山作用和变质作用过程中,分别伴随着金、钼、铜、铅、锌等多金属富集和矿化,该地区具有优越的成矿条件。     

Characterisation of carbonate minerals from hyperspectral TIR scanning using features at 14 000 and 11 300 nm

Rapid characterisation of carbonate phases in hyperspectral reflectance spectra acquired from drill core material has important implications for mineral exploration and resource modelling. Major infrared active features of carbonates lie in the thermal region around 6500 nm, 11 300 nm and 14 000 nm, with the latter two features being most useful for differentiating mineral species. A scatter diagram of the wavelength of the 14 000 nm feature vs that of the 11 300 nm feature, powerfully differentiates carbonates. Although the wavelength of the 11 300 nm peak is easily measured, the 14 000 nm trough and peak are commonly weak and their wavelengths can confidently be used only after filtering the spectra, e.g. selecting only those with the trough and peak separated by 175–230 nm, typical of common carbonates. The method is demonstrated with drillhole 120R from the Rosebery polymetallic VHMS deposit in western Tasmania, which has been scanned with the HyLogger-3 system. A 14 000–11 300 plot shows a high degree of clustering of the drillhole 120R data close to the library spectra of calcite, dolomite, Fe-dolomite, ankerite, kutnohorite, rhodochrosite, Fe-rhodochrosite and siderite. The interpreted compositions of the carbonate spectral populations strongly correlate with the chemical populations of 144 analysed carbonates and provide a highly resolved spatial framework for interpreting carbonate alteration.     

Hydrogen sulfide measurements in air by passive/diffusive samplers and high-frequency analyzer: A critical comparison

In this study, hydrogen sulfide (H₂S) measurements in air carried out using (a) passive/diffusive samplers (Radiello^® traps) and (b) a high-frequency (60 s) real-time analyzer (Thermo^® 450i) were compared in order to evaluate advantages and limitations of the two techniques. Four different sites in urban environments (Florence, Italy) and two volcanic areas characterized by intense degassing of H₂S-rich fluids (Campi Flegrei and Vulcano Island, Italy) were selected for such measurements. The concentrations of H₂S generally varied over 5 orders of magnitude (from 10⁻¹–10³ μg/m³), the H₂S values measured with the Radiello^® traps (H₂S_R) being significantly higher than the average values measured by the Thermo^® 450i during the trap exposure (H₂S_Ta), especially when H₂S was <30 μg/m³. To test the reproducibility of the Radiello^® traps, 8 passive/diffusive samplers were contemporaneously deployed within an 0.2 m² area in an H₂S-contaminated site at Mt. Amiata (Tuscany, Italy), revealing that the precision of the H₂S_R values was ±49%. This large uncertainty, whose cause was not recognizable, is to be added to that related to the environmental conditions (wind speed and direction, humidity, temperature), which are known to strongly affect passive measurements. The Thermo^® 450i analyzer measurements highlighted the occurrence of short-term temporal variations of the H₂S concentrations, with peak values (up to 5732 μg/m³) potentially harmful to the human health. The Radiello^® traps were not able to detect such temporal variability due to their large exposure time. The disagreement between the H₂S_R and H₂S_Ta values poses severe concerns for the selection of an appropriate methodological approach aimed to provide an accurate measurement of this highly toxic air pollutant in compliance with the WHO air quality guidelines. Although passive samplers may offer the opportunity to carry out low-cost preliminary surveys, the use of the high-frequency H₂S analyzer is preferred when an accurate assessment of air quality is required. In fact, the latter provides precise real-time measurements for a reliable estimation of the effective exposure to hazardous H₂S concentrations, giving insights into the mechanisms regulating the dispersion of this air pollutant in relation to the meteorological parameters.     

云南会泽铅锌矿床分散元素的富集机制——兼论浅色闪锌矿富集Cd的原因

文章对云南会泽铅锌矿床的黄铁矿、方铅矿和闪锌矿中的分散元素进行了电子探针分析(EMPA),探讨了分散元素的富集机制.结果表明,分散元素含量已达到综合利用指标,且富集规律为:分散元素以类质同象的形式赋存,黄铁矿中分散元素含量较低,而方铅矿中分散元素的含量稍高于闪锌矿.闪锌矿中:Cd富集顺序为红色＞杂色＞黑色,在高温阶段Cd置换Fe,低温阶段Cd置换Zn;Ga通过置换Zn进入闪锌矿,Ge可能主要替代Fe而进入闪锌矿晶格.方铅矿中:Cd和Ga元素置换Fe或Pb先进入方铅矿晶格内,Ge则富集较晚,具体表现为:当Ga含量较低时,元素进入方铅矿品格顺序为Fe,Zn→Cd→Ga,Ge,当Ga含量较高时,元素进入方铅矿品格的顺序依次为Cd,Ga→Ge.     

江西瑞昌戏子洞铜多金属矿地质特征与控矿因素

戏子洞铜多金属矿主要产于燕山期花岗闪长斑岩及其接触带附近,赋存于花岗闪长斑岩、矽卡岩内,具有典型岩浆热液矿床成因特点。在详细分析戏子洞铜多金属矿地质特征的基础上,认为矿体主要受花岗闪长斑岩、奥陶系与志留系之间岩性差异界面及北东向层滑断层等因素综合控制。     

金川铜镍矿床中新生代抬升冷却过程：来自裂变径迹的证据

本文基于热年代学理论,利用锆石和磷灰石裂变径迹测年数据及对磷灰石热史的模拟,分析探讨金川铜镍矿床在中新生代的抬升冷却过程,认为金川超基性岩体自中生代以来一直处于持续的冷却抬升阶段,且在中侏罗世和晚白垩世早期经历了两期快速的抬升冷却事件,推断此事件与青藏高原后期活动时间相对应,证明金川岩体受到该事件的远程效应波及,致使该矿床遭受了一定的改造。     

东昆北成矿带冰沟南铜镍矿辉长岩地球化学特征

通过对东昆北成矿带冰沟南铜镍矿辉长岩的全岩地球化学进行分析,以确定该岩体的岩石成因及其形成的构造环境。冰沟南辉长岩SiO_2的含量为49.72%~51.58%,岩石系列为钙碱性。稀土元素球粒陨石分配模式为轻稀土略富集型,δEu为1.26~1.54,轻微正Eu异常。岩石富集大离子亲石元素(LILE)Rb、Ba、K,相对亏损P。岩体中的La/Sm、Th/La和Nb/U比值显示在就位过程中经历了一定程度的地壳混染。研究认为,岩体的岩浆源区为亏损地幔。结合区域演化,认为岩体形成于碰撞后伸展的背景。