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11.
H. Hummel C. Amiard-Triquet G. Bachelet M. Desprez J. Marchand B. Sylvand J.C. Amiard H. Rybarczyk R.H. Bogaards J. Sinke Y. De Wit L. De Wolf 《Journal of Sea Research》1996,35(4):315-321
Variation in the sensitivity to stress of Macoma balthica was measured in several French and Dutch estuaries. For adult and juvenile Macoma balthica exposed to copper under conditions of starvation, differences in mortality rate, condition, glycogen, burrowing rate and copper content were assessed. No significant differences were observed between adults and juveniles; the influence of treatment and origin was always evident. Animals from the most southern estuaries, Loire and Gironde, near to the species's southern limit of distribution, showed, in the field, the strongest deviations for the ecophysiological traits measured, and were in the experiments the most sensitive to stress. 相似文献
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Copper complexing ligand concentrations in the Daya Bay, Qingdao coast, Jiaozhou Bay, South China Sea and Huanghe Estuary waters were determined by the anodic stripping voltammetry technique. The distribution regularity and the relationship with other parameters were discussed. The results were as follows: Copper complexing ligand concentrations of the South China Sea were a little higher than those of other sea areas, and they were apparently higher than those of the ocean. Compared with the subsurface layer (SSL) in the sea surface microlayer copper complexing ligand concentrations showed an enrichment phenomenon, of which the mechanism is similar to dissolved organic matter. The metal complexing ligand concentration profiles of the South China Sea showed that the value in the sea surface was the highest, then it decreased with depth accruing, and a higher value appeared at the bottom. Copper complexing ligand concentrations were higher than those of cadmium and lead. Ligands in each sea area exhibited a complicated property. In short, the distribution regularity of copper complexing ligand concentrations in China' s coastal waters was consistent with that of other regions in the world. Meanwhile, the positive relationship between the copper complexing ligand concentrations and biological oxygen demand, chemical oxygen demand, dissolved organic carbon, and viscosity were found clearly. 相似文献
14.
Distribution of dissolved species and suspended particulate copper in an intertidal ecosystem affected by copper mine tailings in Northern Chile 总被引:1,自引:0,他引:1
The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu2+ concentrations in excess of 10− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu2+ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems. 相似文献
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Theconcentrationanddistributionofdimethylsulfideinthemarineatmosphericboundarylayerneartheequator¥LiXingsheng;LiZhe;F.Parungo... 相似文献
16.
利用1989年在大西洋热液活动区采集的块状硫化物样品,采用矿相显微镜、电子显微镜和电子探针等手段,进行了矿物共生组合、矿物形态与成分标型及其演化特征研究。结果表明,大西洋热液成矿作用可以划分为热液期与沉积期两个成矿期,和石英-黄铁矿阶段、黄铁矿阶段、多金属硫化物阶段、胶状黄铁矿阶段和非晶质SiO2阶段等5个成矿阶段;不同成矿阶段黄铁矿的共生矿物和矿物特征不同,在晶体形态上具有从单形晶-聚形晶-胶状 相似文献
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Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry (ICP-OES), thermal analysis (TG-DSC) and Fourier Transform Infrared spectroscopy (FFIR). Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one. 相似文献
18.
竹鸡顶斑岩型铜矿位于西南三江成矿带内,热液蚀变以青磐岩化、泥化为特征。区内现已圈出1个矿带和2个矿化带,并有幅频激电异常、土壤铜异常与之套合。该区具有较好的找矿前景。 相似文献
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在分析河南黄淮平原土壤和小麦籽实中Cu含量分布特征的基础上,利用单项污染指数法对研究区小麦籽实中Cu的污染状况进行评价。其结果为:研究区小麦籽实中Cu的单项污染指数Pi的平均值为0.473,说明研究区小麦籽实未受Cu的污染。Cu的状况良好。进一步讨论了土壤中Cu的含量与小麦籽实中Cu含量间的关系。认为小麦籽实中Cu的积累与土壤中的总Cu无明显的相关关系,而与土壤中的有效态Cu含量具有明显的相关性。据此,将土壤有效态Cu作为土壤Cu生态安全评价的指标。并建立了小麦籽实Cu与土壤有效Cu的响应关系模型,确定了土壤中有效Cu的安全界限值。 相似文献