岩浆型Cu-Ni-PGE硫化物矿床研究的几个问题探讨

文章简述了岩浆型Cu—Ni—PGE硫化物矿床的主要特点和研究现状,探讨了矿床的成矿机制,认为其成矿的首要条件是岩浆中硫达到饱和而使硅酸盐岩浆与硫化物熔体发生熔离。综述了如何利用同位素方法确定其成矿物质来源,介绍了如何判别硫饱和度的方法。     

深海6000 m拖曳式瞬变电磁系统及其应用

针对我国西南印度洋合同区热液硫化物矿快速、有效以及便捷地质勘探装备的要求,研发了由甲板控制系统、万米光电复合缆、仪器舱拖体和天线拖体组成的深海6000 m拖曳式瞬变电磁系统.为了便于拖体布放和快速发现异常,选择重叠回线收发装置类型;采用理论数值计算确定了在拖曳高度不大于50 m的前提下,观测1～100ms窗范围内的二次场响应,可以发现近海底深海热液硫化物矿堆;另外,通过不同拖延深度海上试验,研究了拖曳深度对瞬变电磁的影响规律及仪器性能.大洋第30航次第二航段在西南印度洋脊热液区,应用该系统发现了明显的瞬变电磁异常.印证了系统的有效性.     

New high-resolution 2D seismic imaging of fluid escape structures in the Makran subduction zone,Arabian Sea

Seabed fluid escape is active in the Makran subduction zone, Arabian Sea. Based on the new high-resolution 2D seismic data, acoustic blanking zones and seafloor mounds are identified. Acoustic blanking zones include three kinds of geometries: Bell-shaped, vertically columnar and tilted zones. The bell-shaped blanking zone is characterized by weak and discontinuous reflections in the interior and up-bending reflections on the top, interpreted as gas chimneys. Vertically columnar blanking zone is interpreted as side-imaged gas chimneys associated with focused fluid flow and topped by a seafloor anomaly expressed as a localized reflection discontinuity, which may together serve as a vent structure. Tilted acoustic blanking zone could be induced by accretionary thrust activity and rapid sedimentation surrounding slope. Seafloor mounds occur at the sites of bell-shaped acoustic blanking zone and may be associated with the material intrusion. Bottom simulating refectors (BSRs) are widely distributed and exhibit a series of characteristics including diminished amplitude, low continuity as well as local shoaling overlapping with these acoustic blanking zones. The large amount of gases dissociated from the gas hydrates migrated upwards and then arrived at the near-seafloor sediments, followed by the formation of the gas hydrates and hence the seafloor mound.     

水草腐烂引发的黑臭水体应急处置技术研究

水草腐烂加速水体耗氧和水体还原性物质的溶出进程,在夏、秋季高温条件下极易引发局部水体黑臭.以太湖沉水植物优势种马来眼子菜(Potamogeton malaianus)、苦草(Vallisneria natans)及浮叶植物优势种莕菜(Nymphoides peltatum)为受试材料,利用太湖原位底泥培养模拟水草腐烂形成的黑臭水体,考察不同的环境材料处置方式(壳聚糖(CTS)、聚合氯化铝(PAC)、聚丙烯酰胺(PAM)、CTS+PAC和PAC+PAM)对黑臭水体浊度、溶解氧浓度、挥发性硫化物等黑臭水体特征污染物的絮凝沉降规律及去除机理.结果表明:(1)絮凝处理24 h后,CTS+PAC组合对黑臭水体的浊度去除效果最佳,浊度去除率达70.3%,上覆水溶解氧浓度明显提高,增加率为261.5%;(2)加石英砂悬浊液加速絮体沉淀,形成絮体之后加石英砂使水体浊度稳步下降,4 h之后,浊度去除率达74.9%,显著高于与絮凝剂一起加入的处理组(29.8%);(3)植物腐烂释放的含硫特征嗅味物质主要为硫化氢(H_2S)、甲硫醚和二甲基三硫醚.不同植物体腐烂释放的含硫挥发性有机物浓度差异显著,马来眼子菜释放的4种含硫有机物总和分别为莕菜和苦草释放的319.8%和252.2%;(4)CTS+PAC处理后苦草及马来眼子菜腐烂水体中挥发性有机硫化物浓度较对照组分别降低了18.6%和44.5%.PAC+PAM组合絮凝处理组对莕菜腐烂水体中H2S有较好的去除效果,去除率达到52.4%.CTS+PAC絮凝剂组合处理的H2S浓度均低于对照组,苦草、马来眼子菜和莕菜腐烂后黑臭水体中H2S浓度分别降低了27.4%、41.0%和28.6%.CTS+PAC组合对H2S和二甲基硫醚类物质等致臭物释放的抑制效果优于PAC+PAM组合絮凝处理.     

基于Markov链的金川铜镍矿床超基性岩体侵位过程模拟及找矿启示

金川铜镍矿床是世界第三大铜镍硫化物岩浆矿床,现有研究表明其成矿模式为岩浆通道成矿,但是对于金川超基性岩体的侵位过程存在较大争议。为探索岩体的侵位过程,将岩浆侵位描述为马尔可夫(Markov)过程,提出一种基于Markov链的岩体侵位模拟算法,实现对金川超基性岩体侵位过程的模拟。以金川Ⅱ矿区为例,探讨了侵位过程与矿化的关联及岩浆通道骨架,为在矿床深部寻找第二成矿空间提供方向和线索。     

富硫型水库沉积物AVS和SEM空间分布特征及重金属风险评价

随着湖库外源性污染的有效控制,沉积物污染特征成为影响湖库水环境质量的关键因素。本文以富硫型水库——汤河水库为研究对象,分析探讨水库沉积物的理化性质、重金属总量、酸可挥发性硫化物(acid volatile sulfide,AVS)和同步提取重金属(simultaneously extracted metals,SEM)的空间分布特征,采用沉积物基准法(sediment quality guidelines, SQGs)和AVS与SEM关系法对重金属可能诱发的生态风险和毒性效应进行评估。结果表明:汤河水库沉积物中AVS含量在0.03~51.75 μmol/g之间,并呈现坝前深水区>东支流库区>西支流库区的空间分布特征。根据Pearson相关性分析可知,汤河水库沉积物AVS含量与间隙水中SO₄^2-浓度、沉积物烧失量(LOI)含量呈显著正相关,与沉积物间隙水中NO₃^-浓度和沉积物pH呈现显著负相关。间隙水中SO₄^2-浓度和沉积物LOI含量是控制AVS产量的重要因素。水库沉积物中ΣSEM变化范围为0.52~2.75 μmol/g,呈现出东支流库区>坝前深水区>西支流库区的分布规律。水库沉积物中ΣSEM/AVS和ΣSEM-AVS的变化范围分别为0.06~22.73和-49.18~2.44 μmol/g,显示出水库坝前深水区表层0~10 cm沉积物不具有生态风险,而东、西支流库区沉积物中的SEM因为不能完全被AVS所固定而存在潜在生态风险。就单一重金属而言,汤河水库坝前深水区和东西支流中部区域沉积物Ni、Cu、Pb和Zn含量均介于临界效应含量(threshold effects level, TEL)值和可能效应含量(probable effect level, PEL)值之间,可产生低级风险毒性效应,但Ni的毒性效应风险接近中级,今后应予以重点关注。富硫型水库沉积物中容易出现高含量AVS,沉积物间隙水中SO₄^2-和NO₃^-的浓度是决定沉积物AVS净产量的重要因素。流域内重金属土壤背景值以及工业、采矿产业排放的废水类型直接影响着诱发生态风险的重金属种类。     

Pressure significance of gas chimneys

Analysis was carried out of part of the northern North Sea to test what the presence and style of gas chimneys indicate about fluid pressure (P_f) within hydrocarbon reservoirs. Previous results suggest that broad chimneys above a trap and thin chimneys on the flanks indicate the presence of hydrocarbons, whilst thin chimneys in the crest suggest the hydrocarbons have escaped. Each type of gas chimney is usually associated with overpressure within Mesozoic reservoirs, but the water leg is hydrostatically-pressured in most Cenozoic reservoirs. This indicates: (a) gas leaking from a trap does not necessarily cause P_f to become hydrostatic; (b) overpressure may not be necessary for the expulsion of gasses through seal units to create the chimneys; (c) although gas chimneys indicate the existence of an active hydrocarbon system, their presence does not appear to indicate anything significant about present-day P_f.     

Tectonic Settings and Geological Implications of Neoproterozoic Liujiaping VMS Deposit,Northwestern Yangtze Block,China

Liujiaping VMS (volcanic massive sulfide) deposit contains mainly copper and zinc, which is located at the Longmenshan orogenic belt of the northwestern margin of Yangtze block. The deposit is hosted in Neoproterozoic Datan terrane (composed of Datan granitoids and Liujiaping group) and is a typical, and the biggest, VMS deposit in this area. The Datan granitoids and Liujiaping group are contemporary and both parental magmas have the same genesis. The tectonic evolution history of Northwestern Yangtze is complicated. Chronology, isotope and geochemistry of the Liujiaping VMS ores and wall rocks (especially the Datan granitoids) are analyzed to restrict the tectonic progress. High‐precision secondary ion mass spectrometry (SIMS) analysis of the Datan granitoids resulted in two concordant ages, 815.5 ± 3.2 Ma and 835.5 ± 2.6 Ma, which are contemporary with the Liujiaping Cu–Zn ore and volcanics. The wall rocks are characterized by enrichment in LREE and with a weak negative anomaly of Eu. The Pb isotope data of sulfide and volcanics from the Liujiaping deposit indicate that the material source is lower crust. Together with variable negative anomalies of high strength field elements HFSE (Th, Nb, Ta, Zr, Hf, P and Ti), positive ε_Nd (825 Ma) values (+1.8 to +3.1) and the Nd model age T_2DM = 1.2–1.3 Ga, it shows that the Liujiaping deposit and wall rocks were formed by partial melting of Mesoproterozoic lower crust. Geological and geochemical characteristics of Liujiaping deposit indicate that this deposit was formed during subduction of the oceanic crust. This study clarified that that the Liujiaping deposit and the northwestern margin of the Yangtze block were part of an arc setting at ~820 Ma rather than intra‐continental rift.     

The numerical and empirical evaluation of chimneys considering soil structure interaction and high-temperature effects

During the past strong ground motions, chimneys constructed according to international standards are representative of similar structures at industrial areas throughout the world, including those collapsed or moderately damaged in earthquake-prone regions. This is due to the specialty of structural characteristics and the special loads acting on the structure such as earthquakes, wind and differences in the level of temperature, etc. In this context, the researchers and designers should focus on the dynamic behavior of chimneys especially under high temperature and seismic effects. For this purpose, the main focus of this study is to evaluate the dynamic response of a chimney under the above-mentioned effects considering soil-structure interaction (SSI). A 52 m steel chimney in Yeşilyurt township of Samsun City in Turkey was studied. The in-situ model testing and numerical models were compared. Before the commissioning of the chimney, a series of tests was realized to define its dynamic characteristics in case of no-heat and after the fabric got to work, the same tests were repeated for the same sensor locations to understand the heat effect on the dynamic response of the chimney. The ambient vibration tests are proven to be fast and practical procedures to identify the dynamic characteristics of those structures. The dynamic testing of the towers promises a widespread use, as the identification of seismic vulnerability of such structures becomes increasingly important. The data presented in this study are considered to be useful for the researchers and engineers, for whom the temperature and SSI effects on steel chimneys are a concern. Using the modal analysis techniques, presented finite element simulation for the soil/pile foundation-chimney interaction system is verified. The results of modal analyses using numerical solutions are shown to have acceptable accuracy compared with results obtained by in-situ test. The present study also aims to provide designers with material examples about the influence of these on the seismic performance of steel chimneys by means of reflecting the changes in the dynamic behavior.