新疆青河县库布苏破碎蚀变岩型金矿元素迁移特征与规律研究

本文以新疆库布苏金矿北矿带为研究对象,讨论了库布苏金矿床北矿带元素活动特征,成矿及伴生元素、主量元素、微量元素、稀土元素的质量迁移规律;根据稀土元素的质量迁移、地球化学特征,初步探讨了成矿流体的环境条件和来源问题;并依据元素迁移地球化学图研究了库布苏北矿带105勘探线剖面的元素质量迁移程度和范围。研究结果表明,赋矿闪长玢岩脉及围岩的元素发生明显的带入带出作用,元素迁移活动规律明显,成矿阶段发生明显带入有Au、As、Bi、Ag、Sb、K2O、Si O2,说明引起闪长玢岩脉和接触带围岩蚀变的流体中富含Au、As、K2O、Si O2等,导致这些带入元素向矿体迁移富集;发生明显带出的有Ba、Sr、Cu、Mg O、Na2O、Fe2O3、Ca O,说明Ba、Sr、Mg O、Na2O等受热液蚀变作用随流体迁出。矿区岩脉的稀土元素质量变化显著,发生明显的带入带出,岩脉交代蚀变前后的轻重稀土分馏均明显,蚀变后的岩脉轻重稀土分馏程度有减小趋势。赋矿闪长玢岩脉稀土元素配分曲线右倾,轻稀土富集,轻重稀土分馏明显,Eu强烈负异常,Ce弱负异常,说明库布苏金矿成矿流体条件应为较高温度和还原环境。从围岩与脉岩中元素的迁移程度和迁移范围可见,带入的成矿指示元素有As、W、Sb、Bi,带出的成矿指示元素有Mg、Na。     

Exhumation of the Mesozoic Guojialing Granodiorite: Implication for the Preservation of Gold Deposits in the Jiaobei Terrane,China

Preservation conditions are very important for mineral systems and a suitable exhumation process is critical for endogenetic deposits, especially for those deposits formed in orogenic settings, where deposits are inclined to erode away due to strong uplift. The G uojialing batholith, intruding into the L inglong granites and the J iaodong G roup right before regional gold mineralization, is one of the most important gold ore‐hosting M esozoic intrusions in the J iaobei terrane. Gold deposits and the intrusion together underwent similar tectonothermal evolutionary processes. Exhumation and denudation process of the G uojialing granodiorite was constrained by biotite geobarometry and apatite fission track (FT ) analysis. Biotite geobarometric data yields an emplacement depth of 3.0 km, while denudation since 110 M a was calculated from the FT data at about 2.7 km. FT inverse modeling revealed a rapid uplift since ca 100 Ma. Compared with the gold ore‐forming depth which is confined between 2.5 and 9.5 km by fluid inclusion studies, great gold potential in the depths is inferred in the J iaobei terrane. Our result is consistent, to some extent, with the hypothesis of a M esozoic paleoplateau in E ast C hina.     

The geology of the Morro Velho gold deposit in the Archean Rio das Velhas greenstone belt, Quadrilátero Ferrífero, Brazil

The Morro Velho gold deposit, Quadrilátero Ferrífero region, Minas Gerais, Brazil, is hosted by rocks at the base of the Archean Rio das Velhas greenstone belt. The deposit occurs within a thick carbonaceous phyllite package, containing intercalations of felsic and intermediate volcaniclastic rocks and dolomites. Considering the temporal and spatial association of the deposit with the Rio das Velhas orogeny, and location in close proximity to a major NNW-trending fault zone, it can be classified as an orogenic gold deposit. Hydrothermal activity was characterized by intense enrichment in alteration zones of carbonates, sulfides, chlorite, white mica±biotite, albite and quartz, as described in other Archean lode-type gold ores. Two types of ore occur in the deposit: dark gray quartz veins and sulfide-rich gold orebodies. The sulfide-rich orebodies range from disseminated concentrations of sulfide minerals to massive sulfide bodies. The sulfide assemblage comprises (by volume), on average, 74% pyrrhotite, 17% arsenopyrite, 8% pyrite and 1% chalcopyrite. The orebodies have a long axis parallel to the local stretching lineation, with continuity down the plunge of fold axis for at least 4.8 km. The group of rocks hosting the Morro Velho gold mineralization is locally referred to as lapa seca. These were isoclinally folded and metamorphosed prior to gold mineralization. The lapa seca and the orebodies it hosts are distributed in five main tight folds related to F1 (the best examples are the X, Main and South orebodies, in level 25), which are disrupted by NE- to E-striking shear zones. Textural features indicate that the sulfide mineralization postdated regional peak metamorphism, and that the massive sulfide ore has subsequently been neither metamorphosed nor deformed. Lead isotope ratios indicate a model age of 2.82 ± 0.05 Ga for both sulfide and gold mineralization. The lapa seca are interpreted as the results of a pre-gold alteration process and may be divided into carbonatic, micaceous and quartzose types. The carbonatic lapa seca is subdivided into gray and brown subtypes. Non-mineralized, gray carbonatic lapa seca forms the hanging wall to the orebodies, and is interpreted as the product of extreme CO₂ metasomatism during hydrothermal alteration. This dolomitic lapa seca ranges in composition from relatively pure limestone and dolomite to silty limestone and dolomite. The brown carbonatic and micaceous lapa secas are the host rocks to gold. These units are interpreted to correspond to the sheared and hydrothermal products of metamorphosed volcaniclastic and/or volcanic rocks of varying composition from dacitic to andesitic, forming various types of schists and phyllites. The high-grade, massive sulfide orebodies occur at the base of the gray carbonatic lapa seca. Both disseminated mineralization and quartz veins are hosted by micaceous lapa seca. The data are consistent with a model of epigenetic mineralization for the lapa seca, from a hydrothermal fluid derived in part from the Archean basement or older crust material.     

湖南大新金矿床构造控矿特征及矿床成因

湖南大新金矿床位于湘中白马山-龙山东西向成矿带中部的大乘山穹隆北东端。受区域基底断裂的分割与挟持,及其下伏岩浆活动的上侵作用,穹隆核部震旦系江口组地层发生脆性断裂,从而为成矿提供了导矿和容矿构造,矿区矿脉严格受NE、NW、近SN向三组断裂控制。矿床为破碎蚀变岩夹石英脉型金矿床,含矿热液沿断裂破碎带充填交代而成矿。     

Developing the tools for geological shape analysis,with regional‐ to local‐scale examples from the Kalgoorlie Terrane of Western Australia

Geological map data are often underused in mineral‐exploration programs, which rely increasingly on regolith geochemistry and geophysical and other remotely sensed data to generate exploration targets. However, solid geology maps, which are progressively being upgraded due to improved interpretations of superior, remotely sensed images and airborne geophysical data, can be useful in targeting specific types of mineral deposits, which formed late in the evolutionary history of the host terrane. In such terranes, the present map geometry is essentially the same as that at the time of deposit formation. This is the case for orogenic lode‐gold deposits, which commonly show predictable structural controls and/or structural geometry. Thus, the shape of a rock body, or combinations of structures and rock bodies, may provide an important guide to the exploration potential for orogenic lode‐gold deposits. However, until recently, there has been a dearth of techniques to quantify the various properties of shape, and hence test the potential of the two‐dimensional shape of geological bodies in map view as an exploration tool. Integrating techniques from the field of pattern recognition with a modern Geographical Information System (GIS) can provide the shape‐analysis tools required to investigate the geometries of geological shapes. Two‐dimensional shape analysis is now possible through the calculation of several shape metrics including, but not restricted to, aspect ratio, blockiness, elongation, compactness, complexity, roundness, spreadness and squareness. Methods are developed for describing the geometries of rock units about mineral deposits, or any geological features, at any scale, which for the first time makes it possible to compare shapes. These shape‐analysis techniques are tested using orogenic lode‐gold deposits, particularly those in the Kalgoorlie Terrane of the highly auriferous Late Archaean Norseman‐Wiluna Belt of Western Australia. On a global scale, shape analysis indicates that those greenstone belts whose volcanic rock sequences have high elongation and relative low roundness, complexity and aspect ratio (e.g. Kalgoorlie Terrane) are likely to be the most richly endowed in gold. On a more local scale, characteristics of the shape of geological features around the Golden Mile deposit are calculated and used to test the likelihood of occurrence of gold deposits with similar geometry elsewhere in the Kalgoorlie Terrane. The area with the most closely matching shape, on the basis of a 2 km clipping‐circle radius, chosen on the basis of available proximity‐analysis data, corresponds to the recently discovered Ghost Crab deposit, illustrating the potential of the shape analysis methodology in mineral exploration. Shape analysis is, at least in part, scale dependent, due to the inherent problem of being able to define rock boundaries more precisely in units that have strong geophysical signatures than those with weak signatures in poorly exposed terranes. Overcoming this problem is a challenge to the application of this methodology.     

Syngenetic gold in western Victoria: occurrence,age and dimensions

In western Victoria, a widespread stratiform style of gold enrichment in Palaeozoic black mudstone and chert—clearly different from the classic mesothermal quartz vein deposits of the Victorian goldfields—has been confirmed by whole-rock geochemistry and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICPMS). This enrichment pre-dates compaction, deformation and low-grade metamorphism of the sedimentary host-rocks, and therefore possibly developed diagenetically during slow deposition of the thin carbonaceous black mudstone beds and the thinner layers of chert. These paired strata have been documented at many locations in three regional outcrop areas of chevron-folded Cambrian and Lower Ordovician metasediments in the Stawell and Bendigo Zones, where they are interbedded with quartz-rich turbidites. The layers were named ‘indicators’ by the early miners, who found locally rich nuggety gold deposits at intersections between these layers and mesothermal quartz veins. Gold is present in euhedral pyrite crystals in both black shale and chert. LA-ICPMS analysis of individual pyrite crystals in the indicator beds shows that pyrite is enriched in Au, As, Sb, Se, Te and Bi. The Au content of pyrite varies from 0.03 to 2.69 ppm with a mean of 0.58 ppm and shows a positive correlation with As, which varies from 1000 to 6000 ppm. Many pyrite crystals show enrichment of gold in their cores and depletion in their rims, confirming the likely syngenetic or syndiagenetic accumulation of gold during pyrite formation in the sediments. Prior to regional metamorphism, folding and faulting, the many indicator strata in the outcrop areas were parts of an extensive marine sequence of Late Cambrian and Early Ordovician age. The former primary source of this mineralisation is considered to have been one or more contemporaneously exhalative submarine hydrothermal systems. Thus, the older Palaeozoic sediments of the western Lachlan Fold Belt were significantly enriched in syngenetic gold in the Early Palaeozoic, at least 40 million years before emplacement of the quartz – gold vein deposits of the goldfields.     

甘肃岷县锁龙—马坞一带金矿资源潜力评价

西秦岭“五朵金花”岩体是寨上—马坞金矿整装勘查区一带重要的金矿成矿地质体,围绕“五朵金花”岩体已发现有多达100余处金矿（床）点,是西秦岭重要的金矿集中区。锁龙—马坞一带研究区正好包括了整个教场坝岩体以及中川岩体及柏家庄岩体北部大部分区域,具有良好的形成金矿的潜力。因此本次工作在收集前人1∶5万矿调及锁龙金矿矿产勘查成果资料的基础上,利用MRAS软件对该区域金资源潜力进行了评价,同时预测了23处金成矿的有利区域,为该区下一步工作部署提供了靶区。     

西藏甲玛矿床磁黄铁矿微量元素特征及其与金富集沉淀的耦合机制

【研究目的】甲玛矿床是西藏冈底斯成矿带最重要的斑岩成矿系统之一,具有斑岩、矽卡岩、角岩、脉状金矿四位一体矿体结构,形成了丰富的矿物种类和多样的金属矿化。其中,磁黄铁矿作为重要的金属矿物之一,其矿物地球化学特征以及与金矿化的耦合关系一直不明确。【研究方法】此次,以甲玛斑岩成矿系统外围和远端的不同产状的磁黄铁矿为研究对象,基于详细的野外地质调查和镜下鉴定,通过激光剥蚀电感耦合等离子质谱分析方法（LAICP-MS）对不同产状的磁黄铁矿开展测点分析和扫描分析,详细揭示其地球化学特征。【研究结果】结果显示,甲玛矿床磁黄铁矿主要富集Co、Ni、Cu、Zn、Ge、Se,弱富集Pb、Bi、Sb、Te、Ag、As,而Mo、Cd、In、Sn、Ba、W、Au、Tl、Th、U等元素含量较低。其中,矽卡岩中的磁黄铁矿具有较高的Co/Ni比值,能有效揭示其岩浆热液成因,而角岩中磁黄铁矿可能继承了一定的沉积特征。【结论】甲玛矿区磁黄铁矿的Cu、Zn、Pb含量变化特征与矿床空间矿化规律一致。矽卡岩中的块状磁黄铁矿与金矿化关系密切,金主要呈他形、不规则的独立金矿物产于磁黄铁矿的孔隙和粒间。同时,金的富集和沉淀可能与富铋的熔体有关。创新点：磁黄铁矿是甲玛超大型斑岩成矿系统中典型的金属矿物之一,其微区原位分析清晰揭示其微量元素地球化学特征和矿物成因,同时,证实矽卡岩中磁黄铁矿的高品位金与成矿流体中的富铋熔体有关。     

胶东焦家断裂带与金矿的成生关系

文中着重阐述了控矿断裂活动与焦家金矿Ⅱ、Ⅰ、Ⅲ号矿体之间的成生关系。指出:焦家金矿Ⅱ号矿体与控矿断裂第一期活动有关,Ⅰ号矿体与第二期活动有关,Ⅲ号矿体与第三期活动有关。控矿断裂第一、二期活动显压扭性,第三期活动则显张扭性特征,Ⅰ、Ⅱ号矿体的矿化类型为破碎蚀变岩型,Ⅲ号矿体为多金属硫化物脉型。      

用双孔热解石墨管原子吸收法测定微量金

石墨炉原子吸收法在对化探样品微量金的测试过程中存在因载气进入而使待测样品溅出的问题。利用自制的双孔热解石墨管代替普通石墨管可解决上述问题。通过大量的实验证明,仪器在最佳工作条件下,硫脲介质浓度10g·l-1、解脱时间40min时,获得检出限0 10×10-9、加标回收率为98 4%～103 7%的分析结果。