二(甲基环戊二烯)钐氯化物合成和晶体结构研究

作者以 Sm Cl3 与 (CH3 Cp) Na反应分离得到了三价稀土有机配合物 [(CH3 Cp) 2 Sm Cl·THF]2 的单晶 ,X-射线四圆衍射测定 ,该配合物属正交晶系 ,Pbna空间群 ,晶胞参数 a=9.6 6 2 (2 ) ,b=16 .4 76 (9) ,c=2 0 .582 (9) ;α=β=γ=90°,Z=4。并分析比较 [(CH3 Cp) 2 Sm Cl· THF]2 与其他三价稀土一氯化物的结构特点     

Analysis of Dynamic Characteristics of Submarine Free Spanning Pipelines by Complex Damping Method

Considering the effect of the internal flowing fluid and the external marine environmental condition, the differential equation for the vortex-induced vibration (V1V) of the free spanning pipeline is derived and is discretized by the Hermit interpolation function. The free vibration equation with the damping term is solved by the complex damping method for the natural frequency, and then the effect of fluid damping on the natural frequency of the free spanning pipeline is analyzed.The results show that fluid damping has a significant influence on the damped natural frequency of the free spanning pipeline in the lock-in state, while it has little influence when the pipeline is out of the lock-in state. In the meantime,the change of the free span length has the same effect on the damped natural frequency and the undamped natural frequency.     

胶南构造混杂岩带中糜棱岩的显微形变特征与古构造环境——来自榴辉岩围岩的构造信息

以胶南构造混杂岩带中榴辉岩的围岩——套程度不同的糜棱岩化岩石为研究对象,重点研究了其显微形变的结构特征及环境意义、石英组构特征及动力学信息,并讨论其形成的古构造环境和构造机制。     

Structure and Quaternary tectonic history of the Woodlark triple junction region,Solomon Islands

The Woodlark triple junction region, a topographically and structurally complex triangular area of Quaternary age, lies east of Simbo Ridge and southwest of the New Georgia island group, Solomon Islands, at the junction of the Pacific, Australian and Solomon Sea plates. SeaMARC II side-scan imagery and bathymetry in conjunction with seismic reflection profiles, 3.5 kHz records, and petrologic, magnetic and gravity data show that the active Woodlark spreading centre does not extend into this region.South of the triple junction region, the Woodlark spreading centre reoriented at about 2 Ma into a series of short ESE-trending segments. These segments continued to spread until about 0.5 Ma, when the lithosphere on their northern sides was transferred from the Solomon Sea plate to the Australian plate. Simultaneously the Simbo transform propagated northwards along the western side of the transferred lithosphere, forming a trench-trench-transform triple junction located NNW of Simbo island and a new leaky plate boundary segment that built Simbo Ridge.As the Pacific plate approached, the area east of northern Simbo Ridge was tilted northwards, sheared by dominantly right-lateral faults, elevated, and intruded by arc-related magmas to form Ghizo Ridge. Calc-alkalic magmas sourced beneath the Pacific plate built three large strato-volcanic edifices on the subducting Australian plate: Simbo at the northern end of Simbo Ridge, and Kana Keoki and Coleman seamounts on an extensional fracture adjoining the SE end of Ghizo Ridge.A sediment drape, supplied in part from Simbo and Kana Keoki volcanoes, mantles the east-facing slopes of northern Simbo and Ghizo Ridges and passes distally into sediment ponded in the trench adjoining the Pacific plate. As a consequence of plate convergence, parts of the sediment drape and pond are presently being deformed, and faults are dismembering Kana Keoki and Coleman seamounts.The Woodlark system differs from other modern or Tertiary ridge subduction systems, which show wide variation in character and behaviour. Existing models describing the consequences of ridge subduction are likely to be predictive in only a general way, and deduced rules for the behaviour of oceanic lithosphere in ridge subduction systems may not be generally applicable.     

塔里木盆地的构造演化

从地震大剖面显示，塔里木盆地发育为手风琴式的演化史。大体上形成有3层“断-坳”结构：①震旦系的“断”，古生界-三叠系的“坳”；②侏罗系的“断”，上白垩系的“坳”；③古近系的“断”，新近系的“坳”。断陷与坳陷分别由拉张与挤压应力场所致，这种应力场的变化是由相邻洋壳板块俯冲倾角由小到大的变化所引起的。由于地壳的多旋回运动，多次发生构造沉积演变，构成了多套生储盖组合，多领域、多种圈闭类型的油气藏，从震旦系-古生界-中生界-新生界，各断陷-坳陷结构的盆地都有可能形成油气藏的地质条件。     

复合酶法制备鯷鱼活性寡肽的研究

探讨了用复合酶法制备鱼是鱼活性寡肽及其氨基酸组成和相对分子质量分布情况。应用正交试验法研究了酶量、酶解温度、酶解时间对鱼是鱼蛋白质水解度和酶解液苦味的影响。结果表明,最佳酶解作用条件是:酶量为100u/mL;酶解温度为50℃;酶解时间为4h。此时的酶解液苦味较低,水解度可达62.81%。应用氨基酸分析仪和凝胶排阻高效液相色谱分析了该寡肽的氨基酸组成和相对分子质量的分布范围,其十肽以下的小肽占67.77%,氨基酸组成平衡,必需氨基酸含量丰富。鱼是鱼活性寡肽有望成为保健食品、医药等领域的新型高品质原料。     

Velocity-Interface Structure of the Southwestern Ryukyu Subduction Zone from EW9509-1 OBS/MCS Data

A wide-angle seismic survey, combining ocean-bottom seismometers (OBS) and multi-channel seismic (MCS) profiling, was implemented in the southwestern Ryukyu subduction zone during August and September 1995. In this paper, we present the data analysis of eight OBSs and the corresponding MCS line along profile EW9509-1 from this experiment. Seismic data modeling includes identification of refracted and reflected arrivals, initial model building from velocity analysis of the MCS data, and simultaneous and layer-stripping inversions of the OBS and MCS arrivals. The velocity-interface structure constructed along profile EW9509-1 shows that the northward subduction of the Philippine Sea Plate has resulted in a northward thickening of the sediments of the Ryukyu Trench and the Yaeyama accretionary wedge north of the trench. The boundary between the subducting oceanic crust and the overriding continental crust (represented by a velocity contour of 6.75 km/s) and a sudden increase of the subducting angle (from 5 degrees to 25 degrees) are well imaged below the Nanao Basin. Furthermore, velocity undulation and interface variation are found within the upper crust of the Ryukyu Arc. Therefore, the strongest compression due to subduction and a break-off of the slab may have occurred and induced the high seismicity in the forearc region. This revised version was published online in November 2006 with corrections to the Cover Date.     

灰色关联分析法在海洋环境质量评价中的应用

介绍了灰色关联分析法的原理,说明了其评价步骤。以青岛某海区海水水质评价为例阐明了该方法在海洋环境评价中的应用,并将评价结果与模糊综合评价结果加以比较,结果表明,两种评价方法的评价结果有着较明显的差别,分析了原因。本文还提出了海水污染防治措施,为海洋环境保护提供依据。     

渭河下游河道调整过程中的复杂响应现象

应用系统复杂响应的原理研究三门峡水库上游渭河河道调整过程,表明上游河道河床形态对基面上升所作出的响应是复杂的,弯曲系数的变化为先减小而后增大,宽深比的变化是先增大后减小,比降由先减小而后增大,最后均趋于稳定.     

THE INTRINSIC ACIDITY CONSTANTS AND SPECIFIC SURFACE AREA OF MARINE SOLID PARTICLESII. THE RELATIONSHIP BETWEEN THE INTRINSIC ACIDITY CONSTANT AND THE TERNARY SURFACE COMPLEX

This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.