A Melt Inclusion Record of Volatiles, Trace Elements and Li-B Isotope Variations in a Single Magma System from the Plat Pays Volcanic Complex, Dominica, Lesser Antilles

Glass inclusions in plagioclase and orthopyroxene from daciticpumice of the Cabrits Dome, Plat Pays Volcanic Complex in southernDominica reveal a complexity of element behavior and Li–Bisotope variations in a single volcanic center that would gounnoticed in a whole-rock study. Inclusions and matrix glassesare high-silica rhyolite with compositions consistent with about50% fractional crystallization of the observed phenocrysts.Estimated crystallization conditions are 760–880°C,200 MPa and oxygen fugacity of FMQ + 1 to +2 log units (whereFMQ is the fayalite–magnetite–quartz buffer). Manyinclusion glasses are volatile-rich (up to 6 wt % H₂O and 2900ppm Cl), but contents range down to 1 wt % H₂O and 2000 ppmCl as a result of shallow-level degassing. Sulfur contents arelow throughout, with <350 ppm S. The trace element compositionof inclusion glasses shows enrichment in light rare earth elements(LREE; (La/Sm)_n = 2·5–6·6) and elevatedBa, Th and K contents compared with whole rocks and similaror lower Nb and heavy REE (HREE; (Gd/Yb)_n = 0·5–1·0).Lithium and boron concentrations and isotope ratios in meltinclusions are highly variable (20–60 ppm Li with ⁷Li= +4 to +15 ± 2; 60–100 ppm B with ¹¹B = +6 to+13 ± 2) and imply trapping of isotopically heterogeneous,hybrid melts. Multiple sources and processes are required toexplain these features. The mid-ocean ridge basalt (MORB)-likeHREE, Nb and Y signature reflects the parental magma(s) derivedfrom the mantle wedge. Positive Ba/Nb, B/Nb and Th/Nb correlationsin inclusion glasses indicate coupled enrichment in stronglyfluid-mobile (Ba, B) and less-mobile (Th, Nb) trace elements,which can be explained by fractional crystallization of plagioclase,orthopyroxene and Fe–Ti oxides. The ⁷Li and ¹¹B valuesare at the high end of known ranges for other island arc magmas.We attribute the high values to a ¹¹B and ⁷Li-enriched slabcomponent derived from sea-floor-altered oceanic crust and possiblyfurther enriched in heavy isotopes by dehydration fractionation.The heterogeneity of isotope ratios in the evolved, trappedmelts is attributed to shallow-level assimilation of older volcanicrocks of the Plat Pays Volcanic Complex. KEY WORDS: subduction; volcanic arcs; igneous processes; melt inclusions; SIMS; trace elements; lithium and boron isotopes; diffusion     

黑龙江东部桦南地区早白垩世花岗闪长斑岩的成因及其地质意义

为确定黑龙江省东部桦南地区早白垩世花岗闪长斑岩的岩石成因及其构造背景,对花岗闪长斑岩样品进行了锆石U-Pb年代学与地球化学测试分析。LA-ICP-MS锆石U-Pb同位素分析结果显示,桦南地区花岗闪长斑岩形成于(123±1)Ma的早白垩世。岩石具有较高的SiO_2(66.06%~68.75%)和全碱(6.40%~7.23%)含量,较低的MgO(1.19%~1.50%)含量,并且富集大离子亲石元素(Rb、Ba、Th、U、K)和轻稀土元素,亏损Nb、Ta、Ti及P元素,显示其具有I型花岗岩属性。花岗闪长斑岩的正ε_(Hf)(t)值(+6.30~+11.51)及其二阶段模式年龄(778~445Ma)指示其原始岩浆来源于新生地壳物质的部分熔融。结合年代学、地球化学特征与区域地质调查结果,认为桦南地区早白垩世花岗闪长斑岩的形成与太平洋板块的俯冲作用有直接联系。     

山西新生代汉诺坝玄武岩成因探讨

根据区域地质调查资料,对山西新生代汉诺坝玄武岩的4个火山洼地、7条剖面进行研究。各个火山旋回底部先出现拉斑玄武岩,向上变为碱性玄武岩,岩石均富集大离子亲石元素和轻稀土元素。由东向西,火山喷发时间由早到晚,岩浆活动由弱到强,拉斑玄武岩减少,碱性玄武岩增多,亚碱性玄武岩的稀土元素和微量元素丰度降低,碱性玄武岩的稀土元素和微量元素丰度升高。在原始地幔标准化微量元素蛛网图上,亚碱性玄武岩具Nb、Ta负异常(槽)或呈双峰式,为岛弧玄武岩; 碱性玄武岩呈“隆起”状,类似于洋岛玄武岩(OIB)。山西汉诺坝玄武岩是板块俯冲与地幔柱联合作用的结果,以地幔柱成因为主,板块俯冲成因为辅。亚碱性玄武岩向碱性玄武岩转变,可能代表玄武岩以板块俯冲成因为主转为以地幔柱成因为主; 碱性玄武岩由钾质向钠质变化、亚碱性玄武岩向富铁镁演化,可能分别代表地幔柱向浅、板块俯冲向深的演化过程。     

新疆北阿尔泰造山带早古生代花岗岩类侵入序列及其构造意义

新疆阿尔泰早古生代造山带侵入岩占构造带面积50％以上,近年大量高精度SHRIMP和LA-ICP-MS锆石U-Pb年代学资料反映其构造属性为奥陶纪碰撞前序列和中志留-早泥盆世后碰撞序列.碰撞前序列岩石组合为(石英)闪长岩-英云闪长岩/奥长花岗岩/花岗闪长岩-二长花岗岩序列,类似TTG组合,锆石U-Pb同位素年龄峰值为450～ 465Ma.后碰撞由二长花岗岩-正长花岗岩及少量碱长花岗岩组成,属于广义的GG组合,同位素年龄峰值390～ 415Ma.前者主要分布在中南部,后者主要分布中北部,分布的极性显示俯冲带在南侧.而区域南侧的阿尔曼太蛇绿岩带同位素年龄与北阿尔泰奥陶纪碰撞前序列时代相同,本文推测该蛇绿岩带与北阿尔泰岩浆链带构成洋脊俯冲带模式;其间的南阿尔泰晚古生代增生带、额尔齐斯强变形带、北准噶尔晚古生代洋内弧带都是后来的上叠产物.     

小兴安岭西北部奥陶系火山岩形成环境

本文依据火山岩岩石化学、微量元素和稀土元素地球化学特征，论述了小兴安岭西北部中奥陶统火山岩形成于陆缘弧环境。并且，用板块俯冲机制对其形成机制进行了解释。     

青海东昆仑东段加当辉长岩LA-ICP-MS锆石U-Pb测年及其地质意义

本文对青海东昆仑东段加当辉长岩进行了岩石学、年代学和地球化学分析,有助于丰富东昆仑古特提斯构造岩浆演化的整体认识。利用LA-ICP-MS锆石U-Pb定年技术,获得加当辉长岩加权平均年龄为262.5±2.5Ma(n=38,MSWD=0.18),表明岩体形成时代为中二叠世晚期。岩石地球化学研究表明,加当辉长岩具有低TiO_2(0.79%~1.09%)、贫P_2O_5(0.06%~0.09%)、低碱(K_2O+Na_2O=1.99%~2.39%)及Na_2OK_2O的特征,属拉斑玄武岩系列。岩石微量元素总体上富集大离子亲石元素(LILE:Rb、Ba、K)和Pb,相对亏损高场强元素(HFSE:Nb、Ta、P),稀土元素总量(ΣREE)为32.08×10~(-6)~46.41×10~(-6),(La/Yb)N为1.59~2.00,平均1.82,δEu=0.95~1.32,具有弱的Eu正异常。地球化学特征表明辉长岩源区为岩石圈幔源岩浆,岩浆在演化过程中遭受了地壳物质的同化混染;构造环境分析表明加当辉长岩是形成于俯冲环境的岛弧岩浆岩。结合东昆仑区域构造演化,认为加当辉长岩是阿尼玛卿古特提斯洋向北俯冲的产物,这为东昆仑晚古生代-早中生代构造演化提供了新的年代学证据。     

新疆西准噶尔晚古生代大地构造演化的岩浆活动记录

晚石炭世-早二叠世是新疆北部最为重要的金属矿床成矿期.西准噶尔的区域大地构造、蛇绿岩、沉积岩、花岗岩、埃达克岩、富镁闪长岩以及广泛出露的中基性岩墙研究显示,该地区直到早二叠世早期(290Ma)仍有残余洋盆存在,并可能存在相关的俯冲活动.在290Ma之后,伴随着红色磨拉石的产出,西准噶尔地区进入碰撞造山阶段,伴有地壳快速...     

华北克拉通东部岩石圈破坏与幔柱的成因

华北克拉通东部是指大兴安岭—太行山重力梯度带以东的地区。该地区与东北及华南地区一样,也存在着岩石圈减薄和岩石圈破坏的现象。华北克拉通古生代与新生代的橄榄岩包体地热值分别为40mW/m~2和80mW/m~2,地热增高是岩石圈破坏的重要因素。中国东部—朝鲜半岛的GRACE卫星布格重力异常呈巨型环状展布,可能是地幔亚热柱所致。区内郯庐断裂带呈NNE向纵贯切割,最新的地震反射剖面成果反映,该断裂带以走滑为主,兼有逆冲和正断层,所组成的大型"花状"复杂断裂构造带,切穿地壳、莫霍面,直至岩石圈地幔,起到破坏岩石圈的作用。S波速成像结果证实,在苏鲁造山带下方,分布的碎块状波速扰动带延伸300km,应是中生代扬子板块走滑俯冲、断离、折返的产物;而在渤海湾盆地下方,下地幔也存在陡倾的破碎带,延伸300km,在岩石圈76km处及其深部,S波速降低,扰动很剧烈,可能是地幔柱头部呈粗大状的反映,故可认为渤海湾盆地是由蘑菇云状的地幔柱形成。再从华北克拉通的大陆根来看,东部为A型反时针pT轨迹麻粒岩分布,而中西部则为B型麻粒岩,这是因为东部新太古代绿岩带中赋存有科马提岩,其岩浆温度可高达1 600℃,如用幔柱构造模型解释成因最为合适。通过研究近年大量地震反射P波和S波层析资料,华北克拉通的东部在晚侏罗-早白垩世及新生代期间,受太平洋板块俯冲和地幔热柱上隆的相互作用,深部的地幔流体常沿构造破裂带运移,促使岩石圈拆沉,并发生热侵蚀作用,形成酸性大火成岩省(SLIP)、裂谷型盆地的广泛分布和成矿成藏作用的"大爆发"。由此认为,建立区域构造模型将有利于指导深部找矿工作。     

中国东南部晚中生代构造作用

濒太平洋西缘,位居东亚陆缘南段的中国东南部,是在EW向古亚洲构造域基底之上发育起来的。研究表明,该区在早、中侏罗世经历了一次从EW向古亚洲构造域向NE向西太平洋构造域的体制转换,其转换位置之一是在南岭一带,其地质标志是侏罗纪盆地内近东西走向的灰色沉积岩层、同位素年龄值为180 Ma左右的双峰式火山岩和中侏罗世A型花岗岩等。到早白垩世,本区已基本完成古亚洲域向西太平洋构造域的体制转换。中国东南部晚中生代火成岩的成因机制基本上可用古太平洋岩石圈消减作用、玄武岩浆底侵作用和地壳深熔作用相结合的模式来解释。日本中央构造线—台湾纵谷带—菲律宾民都洛-巴拉望带是晚中生代古太平洋板块向东亚陆缘的消减带。晚中生代古太平洋板块(伊泽奈琦和库拉板块)低角度(<30°)、快速率(>10cm/a)的俯冲,是西太平洋陆缘区能形成宽阔火山岩带的重要动力学原因。宽阔的火山—侵入杂岩区和6条区域断裂构成了中国东南部晚中生代的基本构造框架。台湾纵谷带为古太平洋板块的俯冲-缝合带,而发育在大陆内部的5条区域断裂则具不同构造属性:长乐—南澳带是晚中生代大陆内部的左旋走滑带,上虞—政和—大埔断裂是古基底隆升区与晚中生代火山—沉积盆地区的分界带,绍兴—江山—东乡—萍乡断裂是晚白垩世—古近纪红     

Relationship between Mesozoic Magmatism and Subduction in the Da Hinggan-Yanshan Area

High-resolution tomographic images of the belt crossing the Japan Trench-Changbai Mountains-Dong Ujimqin Qi are represented in this paper, revealing the shape of a subducted slab in the western Pacific region and characteristics of the lithospheric structures under the Changbai Mountains and the Da Hinggan Mountains. Studies of the spatial distribution, subduction time and the time-lag between the subduction and magmatism, combined with petrology and isotope geochemistry of the Late Mesozoic volcano-plutonic rocks from the Da Hinggan Mountains-Yanshan Mountains have further proved the independence of magmatic activities from the subduction of the Pacific plate. The Mesozoic tectono-thermal evolutionary history and structural characteristics of the lithosphere in the Da Hinggan Mountains and North China suggest that the formation and evolution of magma have probably a close relationship with the delamination and thinning of the continental lithosphere and the underplating resulting from the consequent up