An Air‐Cooled,High‐Yield,Compact and Inexpensive Teflon Still for High‐Purity Reagents

Mattinson’s (1972) well‐known simple design of a sub‐boiling still for the preparation of ultra high‐purity reagents consists of two Teflon bottles connected at right angles with one acting as the feed bottle and heated on its upper surface by infrared radiation and the other kept in a cold water bath serving both as the condenser and receiver. Connection of the two bottles in a vertical configuration and replacement of radiative surface heating with conductive bulk heating result in an equally simple and inexpensive still but with a smaller footprint, much larger yield and higher energy efficiency using only ambient air cooling. It can be easily configured for tandem distillation, supply of continuously purified reagent and fractional distillation. Ease and very low cost of fabrication of this still may be of particular interest to many geochemical laboratories requiring up to 500 ml of mineral acids and other common reagents per day.     

Seismic potential of the North Qazvin zone,Alborz

The North Qazvin region is a part of the Central Alborz Mountains in Iran and has experienced destructive earthquakes. This region is a popular and industrial zone near Tehran, capital of Iran. To identify the highest and lowest seismic hazard location and consequently the seismic zonation of this region, different parameters, such as topography, geology, tectonics and seismicity, have been focused. Accordingly, the north of Qazvin region can be divided into three subzones: western, eastern and southern. Seismic activity of the western zone is higher than the other ones and seismic potential of the eastern zone is higher than the other two zones. This zoning is also necessary for all seismic active areas to find the most dangerous zone.     

Facies model of a mixed clastic–carbonate,wave‐dominated open‐coast tidal flat (Tithonian–Berriasian,north‐east Spain)

Detailed logging and analysis of the facies architecture of the upper Tithonian to middle Berriasian Aguilar del Alfambra Formation (Galve sub‐basin, north‐east Spain) have made it possible to characterize a wide variety of clastic, mixed clastic–carbonate and carbonate facies, which were deposited in coastal mudflats to shallow subtidal areas of an open‐coast tidal flat. The sedimentary model proposed improves what is known about mixed coastal systems, both concerning facies and sedimentary processes. This sedimentary system was located in an embayed, non‐protected area of a wide C‐shaped coast that was seasonally dominated by wave storms. Clastic and mixed clastic–carbonate muds accumulated in poorly drained to well‐drained, marine‐influenced coastal mudflat areas, with local fluvial sandstones (tide‐influenced fluvial channels and sheet‐flood deposits) and conglomerate tsunami deposits. Carbonate‐dominated tidal flat areas were the loci of deposition of fenestral‐laminated carbonate muds and grainy (peloidal) sediments with hummocky cross‐stratification. Laterally, the tidal flat was clastic‐dominated and characterized by heterolithic sediments with hummocky cross‐stratification and local tidal sandy bars. Peloidal and heterolithic sediments with hummocky cross‐stratification are the key facies for interpreting the wave (storm) dominance in the tidal flat. Subsidence and high rates of sedimentation controlled the rapid burial of the storm features and thus preserved them from reworking by fair‐weather waves and tides.     

Can rapidly accumulating Holocene peat profiles provide sub‐decadal resolution proxy climate data?

To test the potential for developing sub‐decadal resolution records of ombrotrophic bog surface wetness (BSW), selected abrupt climate events were identified in cores from four sites in north‐west Europe and time‐slices over each event were investigated at 2–5‐mm resolution using peat humification, testate amoeba and plant macrofossil analyses. Age–depth models based on radiocarbon, spheroidal carbonaceous particle and tephra dates were applied and the error in these models was used to determine the effective temporal sampling resolution, which in most cases was sub‐decadal. Fine‐resolution results revealed some inconsistencies in the co‐variability of individual proxies and there was a lack of correspondence between some results from adjacent cores. However, we found evidence of abrupt shifts in BSW occurring over ca. 5–20 years, indicating a more rapid proxy response than identified in previous research. To maximize potential temporal resolution and produce reliable sub‐decadal BSW data in future research, we recommended that peat‐based studies should obtain the best possible chronological control, focus on sites with high species diversity and rapid accumulation rates and perform replicate coring, or use open peat sections where the stratigraphy can be clearly seen, to assess intra‐site differences in microtopography. Site‐specific factors should be a primary consideration in the selection of sites for future fine‐resolution research. Copyright © 2012 John Wiley & Sons, Ltd.     

The use of integrated sedimentological and geophysical methods in drumlin research – a case study of Pigeon Point,Clew Bay,Northwest Ireland

Despite significant advances over the past decades, our understanding of drumlin formation and associated ice‐bed processes is still incomplete. In this paper, we present the integrated use of geomorphological, sedimentological and geophysical techniques as a powerful means to force a breakthrough towards solving the drumlin enigma. We report on investigations of the anatomy of the Pigeon Point drumlin, Clew Bay, Ireland. We found that the bulk of the landform, which displays a classical drumlin shape, consists of silty‐clayey diamicton showing evidence of deformation, hydrofracturing and comminution. The unit is interpreted as a sub‐glacial traction till/comminution till. The thin unit overlying this basal till consists of silty‐sandy diamicton, and is interpreted as a para‐glacially modified melt‐out till. The partly cemented third unit consists of stratified, massive to graded sands and gravels. Its contact with the sub‐glacial traction till consists of a series of concave shapes, which suggests that it was deposited in meltwater channels that flowed in sub‐glacial cavities and that cut laterally into the drumlin. We propose that highs in the undulating rockhead relief, as shown in the seismic profile, have provided nuclei which initiated drumlin formation. This idea is supported by the observation of local detached bedrock slabs that grade upwards into a comminution till. In the long profile, very high normalized induced polarization (IP) values form a wedge‐shape, which is interpreted as a set of conjugate thrusts, or a ‘pop‐up’ structure. The structure is positioned directly above one of the undulations in the bedrock, suggesting a direct relationship. The high values are thought to reflect the presence of pre‐existing clays, which were sheared into the till, thus forming linings in the thrust features. It is concluded that glacitectonic processes, notably differential bedrock weathering and thrusting, have played a key role in the formation of this drumlin. Copyright © 2011 John Wiley & Sons, Ltd.     

Statistical probability distribution of snow depth at the model sub‐grid cell spatial scale

Comprehensive snow depth data, collected using georadar and hand probing, were used for statistical analyses of snow depths inside 1 km grid cells. The sub‐grid cell spatial scale was 100 m. Statistical distribution functions were found to have varying parameters, and an attempt was made to connect these statistical parameters to different terrain variables. The results showed that the two parameters mean and standard deviation of snow depth were significantly related to the sub‐grid terrain characteristics. Linear regression models could explain up to 50% of the variation for both of the snowcover parameters mentioned. Copyright © 2004 John Wiley & Sons, Ltd.     

Chemical evolution of circumstellar matter around young stellar objects

Recent observational studies of the chemical composition of circumstellar matter around both high- and low-mass young stellar objects are reviewed. The molecular abundances are found to be a strong function of evolutionary state, but not of system mass or luminosity. The data are discussed with reference to recent theoretical models.     

Identifying and linking source areas of flow and P transport in dairy‐grazed headwater catchments,North Island,New Zealand

We examined the applicability of the critical‐source area (CSA) concept to the dairy‐grazed 192‐ha Upper Toenepi catchment and its 8·7‐ha Kiwitahi sub‐catchment, New Zealand. We evaluated if phosphorus (P) transport from land into stream is dominated by saturation‐excess (SE) and infiltration‐excess (IE) runoff during stormflow and by sub‐surface (<1·5 m depth) flows during baseflow. We measured stream flow and shallow groundwater levels, collected monthly stream, tile drain (TDA) and groundwater samples, and flow‐proportional stream samples from the Kiwitahi sub‐catchment, and determined their dissolved reactive phosphorus (DRP) and total phosphorus (TP) concentrations. In the Kiwitahi sub‐catchment, during storm events, IE contributions were significant. Contributions from SE appeared significant in the Upper Toenepi catchment. However, in both catchments, sub‐surface contributions dominated stormflow and baseflow periods. Absence of water table at the surface and the water table gradient towards the stream indicated that P transport during events was not limited to surface runoff. The dynamics of the groundwater table and the occurrence of SE areas were influenced by proximity to the stream and hillslope positions. Baseflow accounted for 42% of the annual flow in the Kiwitahi sub‐catchment, and contributed 37 and 52% to the DRP and TP loads, respectively. The P transport during baseflow appeared equally important as P losses from CSAs during stormflow. The close resemblance in P levels between groundwater and stream samples during baseflow demonstrates the importance of shallow groundwater for stream flow. In the Upper Toenepi catchment, contributions from effluent ponds (EFFs) dominated P loads. Management strategies should focus on controlling P release from EFFs, and on decreasing Olsen P concentrations in soil to minimize leaching of P via sub‐surface flow to streams. Research is needed to quantify the role of sub‐surface flow as well as to expand management strategies to minimize P transfers during stormflow and baseflow conditions. Copyright © 2010 John Wiley & Sons, Ltd.