A reconnaissance study of oxygen, hydrogen and strontium isotopes in geochemically diverse lakes, Western Nebraska, USA

Reconnaissance ¹⁸O,, D, and ⁸⁷Sr data for fifteen lakes in the Western Lakes Region of the Sand Hills of Nebraska indicate dynamic hydrologic systems. The rather narrow range of ⁸⁷Sr from lake water (1.1 to 2.1) and groundwater (0.9 to 1.7) indicates that the groundwater is generally unradiogenic. Groundwater residence times and relatively unradiogenic volcanic ash within the dune sediments control the ⁸⁷Sr values. Based on the mutual variations of ¹⁸O and D, the lakes can be divided into three groups. In Group 1, both ¹⁸O and D values increase from spring to fall. The ¹⁸O and D values in Group 2 decreased from spring to fall. Group 3 are ephemeral lakes that went dry some time during 1992. The data and isotopic modeling show that variations in the ratio of evaporation relative to groundwater inflow, local humidity conditions, and the _a has substantial influence on the isotopic composition. In addition, isotopic behavior in ephemeral lakes can be rather unusual because of the changing activities of water and mineral precipitation and redissolution. The annual and interannual isotopic variability of these lakes which is reflected in the paleonvironmental indicators may be the rule rather than the exception in these types of systems.     

青藏高原的隆起与海洋锶同位素组成的演化

近年来,随着构造隆升驱动气候变化假说的提出,青藏高原的隆起受到越来越多的关注,并将之与大陆化学风化速率及海洋锶同位素的演化紧密联系。围绕青藏高原的隆升及其环境与气候效应,对海洋锶同位素组成的演化特征及其影响因素的较为全面而详细的论述表明:将青藏高原的隆升与全球气候变化、大陆化学风化速率及海洋锶同位素组成的演化相联系,也许是解决目前关于海洋锶同位素组成的演化及其物源问题的重要手段,根据海洋锶同位素的演化历史来研究全球气候变化规律及青藏高原的构造演化历史将是本研究领域的重点。     

河南西峡晚白垩世恐龙蛋化石壳超高异常Sr的发现及其意义

利用电感耦合等离子体发射光谱仪(ICP-AES),对采自河南西峡晚白垩世的十三枚恐龙蛋化石壳及蛋内充填物和部分围岩进行了测试。发现Sr元素具有明显的超高异常。恐龙蛋化石壳中的Sr的含量分布在1962×10-6～11010×10-6之间,平均5532×10-6,比古代和现代富Sr的腕足类外壳高一到数倍,比地壳丰度值高一个数量级还多。这种超高异常可能与恐龙蛋壳中含有一定数量的文石有关。而由于文石稳定性较差,在石化过程中会逐渐向低镁方解石转化,所以现在已无法再见到蛋壳中的文石,但Sr却保留了下来。反映了中生代时陆生爬行动物的蛋壳与海相生物硬壳一样具有文石和方解石共存的局面。     

中国(天青石)锶矿床概述

中国 (天青石 )锶矿资源丰富 ,矿床以大型、特大型单一 (天青石 )锶矿为主 ,构成我国目前主要的工业锶源。依据成矿作用和成矿地质特征 ,将我国 (天青石 )锶矿床划分为沉积型、岩浆 热液型、沉积 热卤水改造型和表生淋积型等四大类七个亚类。主要产于印支、燕山、喜马拉雅三个旋回之中 ,不同类型矿床分别与一定的大地构造环境、沉积岩相、岩浆岩、热液及热卤水等作用有关。中国四川东南部、柴达木盆地东北部、苏南、鄂东南、云南云龙 -维西一带、陕西黄龙铺及四川攀西等 7个地区具有良好的找矿前景     

东天山康古尔金矿床成矿流体地球化学特征及其来源

新疆康古尔金矿床是分布于晚古生代火山岩区受脆韧性剪切带控制的蚀变岩型金矿。该矿床成矿流体具有中低温度（３２０～１００℃）、中等ＮａＣｌ质量分数（１１４％～１７０％）、弱还原等特征。包裹体气相成分以Ｈ２Ｏ和ＣＯ２为主,液相成分中富Ｎａ＋、Ｃｌ－,而贫Ｋ＋、Ｆ－。成矿流体δＤ为－４５‰～－６６‰,δ１８Ｏ为－８３４‰～２９８‰,（８７Ｓｒ／８６Ｓｒ）ｉ值为０７０７７～０７１０６,反映了成矿流体由变质水、大气降水和岩浆水混合组成的特点     

上扬子晚古生代海相地层锶同位素曲线的LOWESS拟合

目前仍难以有一种具体的函数关系来描述随时问或随地层厚度变化的地质数据,L0wESS方法被证明是拟合这类数据的较为有效的方法.采用LOWESS方法对我国上扬子地区晚古生代98个海相碳酸盐的锶同位素数据进行科学的拟合,使拟舍得出的曲线具有更好的全球可对比性,从而提高我国锶同位素地层学的研究水平,并使之与相应的国际研究接轨.同时,还从数学角度讨论参数回归和非参数回归的区别,并对影响拟合结果的两个参数和误差范围进行讨论.     

Identifying the Sources of Solutes in Karst Groundwater in Chongqing,China: a Combined Sulfate and Strontium Isotope Approach

Groundwater from karst subterranean streams is among the world’s most important sources of drinking water supplies, and the hydrochemical characteristics of karst water are impacted by both natural environment and people. Therefore, the study of hydrochemistry and its solutes’ sources is very important to ensure the normal function of life support systems. In this paper, thirty?five representative karst groundwater samples were collected from different aquifers (limestone and dolomite) and various land use types in Chongqing to trace the sources of solutes and relative hydrochemical processes. Hydrogeochemical types of karst groundwater in Chongqing were mainly of the Ca?HCO3 type or Ca (Mg)?HCO3 type. However, some hydrochemical types of karst groundwater were the K+Na+Ca?SO4 type (G25 site) or Ca?HCO3+SO4 type (G26 and G14 site), indicating that the hydrochemistry of these sites might be strongly influenced by anthropogenic activities or unique geological characteristics. The dissolved Sr concentrations of the studied groundwater ranged from 0.57 to 15.06 μmmol/L, and the 87Sr/86Sr varied from 0.70751 to 0.71627. The δ34S?SO42? fell into a range of ?6.8‰?21.5‰, with a mean value of 5.6‰. The variations of both 87Sr/86Sr and Sr values of the groundwater samples indicated that the Sr element was controlled by the weathering of limestone, dolomite and silicate rock. However, the figure of 87Sr/86Sr vs. Sr2+/[K++Na+] showed that the anthropogenic inputs also obviously contributed to the Sr contents. For tracing the detailed anthropogenic effects, we traced the sources of solutes collected karst groundwater samples in Chongqing according to the δ34S value of potential sulfate sources. The variations of both δ34S and 1/SO42? values of the groundwater samples indicated that the atmospheric acid deposition (AAD), dissolution of gypsum (GD), oxidation of sul?de mineral (OS) or anthropogenic inputs (SF: sewage or fertilizer) have contributed to solutes in karst groundwater. The influence of oxidation of sul?de mineral, atmospheric acid deposit and anthropogenic inputs to groundwater in Chongqing karst areas was much widespread.     

鄂尔多斯盆地苏里格地区奥陶系马家沟组马五段白云岩的地球化学特征

苏里格地区奥陶系马家沟组马五段白云岩是重要的油气储集层.多年来,马家沟组白云岩的成因一直是地质研究者讨论的热点话题.对苏里格地区马家沟组马五段白云岩的微量元素及C、O、Sr同位素地球化学资料的分析表明,微量元素表现为高铁、低锰、低锶、低钠;白云石、白云质角砾和孔洞充填白云岩的δ13C和δ18O值较为近似,且白云岩的δ1...     

X射线荧光光谱法测定高锶高钡的硅酸盐样品中主量元素

用百分总和检查硅酸盐岩石全分析数据的质量是分析工作者的传统做法,但对于微量元素含量较高的样品,采用X射线荧光光谱法(XRF)进行测定,如果不考虑微量元素的含量及其对主量元素基体效应的影响,往往会使主量元素含量更加偏离真实值。本文针对Sr、Ba含量较高的硅酸盐样品,通过人工配制标准样品,扩大了Sr、Ba校准曲线的定量范围,主量元素校准中加入Sr、Ba的基体校正系数,达到了主量元素定量更加准确可靠的实际效果。采用此方法分析国家标准物质,各主量元素的精密度(RSD)均小于2%;分析不参加回归的标准物质和人工配制的标准样品,主量元素的测量值与标准值(或参考值)基本一致。该方法可以满足硅酸盐的测定要求,主量元素各项结果的加和能够达到《地质矿产实验室测试质量管理规范》的一级标准(99.3%～100.7%)。     

陕北贾大峁遗址出土动物遗骸的锶同位素比值分析

史前时期动物驯养技术的跨大陆交流与传播是令人瞩目的 前沿课题.陕北地区位于欧亚草原早期青铜文化和中原地区古代文化交汇碰撞的前沿地带.贾大峁遗址位于陕西省横山县,年代为距今约4500～4300年的龙山早期.作为陕北地区目前发现的最早出现牛和羊的考古遗址之一,牛和羊是当地驯养抑或外来的,是值得我们探讨的问题.本文通过热电离...