滇黔北坳陷寒武系碳酸盐岩古海洋环境特征及地质意义

为厘定滇黔北坳陷寒武系碳酸盐岩古海洋环境,揭示成岩流体与岩溶作用的潜在联系,并预测有利储层发育层段,基于镇雄羊场碳酸盐岩剖面实测及系统取样基础上,采用微量元素、碳氧锶同位素及铸体薄片等分析手段,地球化学与岩石学方法相结合,探讨碳酸盐岩古海洋环境及地质意义。研究结果表明:滇黔北坳陷寒武系清虚洞组-娄山关组整体为海相环境,古海洋温度处于12.82℃~32.84℃之间,主体为温暖或炎热的亚热带气候。海平面具有主体震荡下降的趋势,存在8期海平面变化旋回,发育对应的岩相组合,其同位素演化曲线可作为地层划分依据。微量元素、同位素地球化学及岩石学特征证实娄山关组岩溶作用相对发育,成岩流体混入强氧化性低温大气水,有利储层纵向上主要分布在海平面下降旋回的高部位。     

鄂尔多斯盆地南部马莲河流域地下水中锶富集特征及成因分析

马莲河流域地处鄂尔多斯盆地南部黄土高原区,按储水介质和埋藏条件可将地下水分为黄土潜水、基岩潜水和基岩承压水三类,利用2015—2018年流域的295组地下水水化学数据,分析了地下水中锶(Sr²⁺)的质量浓度水平、垂向分布及沿流向分布的特征,并采用因子相关性研究地下水中Sr²⁺的来源和富集成因。结果表明:马莲河流域地下水富锶现象显著,黄土潜水、基岩潜水和基岩承压水中锶的平均质量浓度分别为1.14 mg/l、1.39 mg/l和5.24 mg/l;地下水中锶富集成因主要是含锶矿物天然状态下的水-岩作用,黄土潜水、基岩潜水和基岩承压水三类地下水中Sr²⁺的主要来源分别为碳酸盐岩与铝硅酸盐岩、碳酸盐岩与硫酸盐和碳酸盐矿物的溶滤作用;地下水中Sr²⁺的质量浓度沿流向呈逐渐增大的趋势,在不同区域中随深度变化的趋势不一致。     

川东下三叠统飞仙关组-嘉陵江组界线附近的锶同位素组成

作为化学地层学的重要分支之一,锶同位素地层学已经逐步成为全球海平面变化、造山运动、古气候和古环境等全球事件研究和对比的有效工具,根据锶同位素地层学的基本原理,在对样品进行沉积岩组构、化学成分分析和对同期海水代表性评估的基础上,测试了四川东部华蓥山地区下三叠统飞仙关组-嘉陵江组界线附近6个碳酸盐岩样品的锶同位素组成。结果表明,该界线附近的锶同位素组成与前人公布的早三叠世同期海水的锶同位素组成数据基本一致。锶同位素地层学研究的引入,可望为我国南方海相三叠系飞仙关组和嘉陵江组的年代地层学对比研究提供重要依据。     

磷矿石中磷、钙、镁、锶、氟测定方法评述

本文系统分析了磷矿石高含量磷、钙、镁、锶、氟诸元素存在时对其测定的相互影响及其测定中存在的问题,比较全面地总结了国内分析工作者针对该问题,对诸难测元素在常规分析方法方面的工作进展。     

Application of a Bayesian model to infer the contribution of coalbed natural gas produced water to the Powder River,Wyoming and Montana

The Powder River Basin (PRB) of Wyoming and Montana contains significant coal and coal bed natural gas (CBNG) resources. CBNG extraction requires the production of large volumes of water, much of which is discharged into existing drainages. Compared to surface waters, the CBNG produced water is high in sodium relative to calcium and magnesium, elevating the sodium adsorption ratio (SAR). To mitigate the possible impact this produced water may have on the quality of surface water used for irrigation, the State of Montana passed water anti‐degradation legislation, which could affect CBNG production in Wyoming. In this study, we sought to determine the proportion of CBNG produced water discharged to tributaries that reaches the Powder River by implementing a four end‐member mixing model within a Bayesian statistical framework. The model accounts for the ⁸⁷Sr/⁸⁶Sr, δ¹³C_DIC, [Sr] and [DIC] of CBNG produced water and surface water interacting with the three primary lithologies exposed in the PRB. The model estimates the relative contribution of the end members to the river water, while incorporating uncertainty associated with measurement and process error. Model results confirm that both of the tributaries associated with high CBNG activity are mostly composed of CBNG produced water (70–100%). The model indicates that up to 50% of the Powder River is composed of CBNG produced water downstream from the CBNG tributaries, decreasing with distance by dilution from non‐CBNG impacted tributaries from the point sources to ~10–20% at the Montana border. This amount of CBNG produced water does not significantly affect the SAR or electrical conductivity of the Powder River in Montana. Copyright © 2013 John Wiley & Sons, Ltd.     

格尔木冲洪积扇地下水锶物质流通量分析

在分析格尔木含锶矿水田供锶环境和水迁移条件的基础上，将形成含锶矿水田的地质空间分为两个区：山区淋溶迁移区和平原迁移聚集区，运用物质流通量分析的观点，对锶的迁移聚集进行了系统分析，山区为锶矿水的形成提供了物质环境，平原区为锶矿水提供了贮存环境。     

四川盆地东北部三叠系飞仙关组碳酸盐岩成岩作用和白云岩成因的研究现状和存在问题

四川盆地东北部三叠系飞仙关组是我国重要的天然气储集层，优质储层形成机制直接与碳酸盐岩成岩作用、尤其是白云岩化作用相关，但飞仙关组碳酸盐岩在锰含量、锶含量、阴极发光性等特征上反映其成岩过程与经典成岩理论相悖；碳酸盐岩的锶同位素组成和锰、锶含量的关系也表明与大气水有关的成岩过程和作为重要储集岩的结晶白云岩的形成机制无关，传统的白云岩化机制难以解释结晶白云岩的成因。具有海源色彩的高锶、低锰成岩流体在很大程度上控制了飞仙关组碳酸盐的成岩作用，其来源与成因值得进一步关注，控制其运移、封存和发生水—岩反应的时空机制有待回答。整个海相三叠纪时间段盆地尺度碳酸盐岩和蒸发岩的沉积地球化学研究、尤其是不同结构组分碳酸盐的锶同位素组成、锶和锰含量研究（包括碳酸盐岩中不同结构组分的阴极发光性研究），可为四川盆地东北部飞仙关组碳酸盐岩成岩作用（尤其是白云岩化作用和作为重要储集岩的结晶白云岩的成因研究），天青石矿床成因研究和四川盆地三叠系深层富钾、锶、硼、溴卤水的成因研究提供重要的线索。     

Sr isotope diversity of hot spring and volcanic lake waters from Zao volcano,Japan

The ratio of ⁸⁷Sr/⁸⁶Sr was measured from different water samples of thermal/mineral (hot spring as well as crater lake) and meteoric origins, in order to specify the location and to verify the detailed model of a volcano-hydrothermal system beneath Zao volcano. The ratio showed a trimodal distribution for the case of thermal/mineral water: 0.7052–0.7053 (Type A, Zao hot spring), 0.7039–0.7043 (Type B, Okama crater lake and Shin-funkiko hot spring), and 0.7070–0.7073 (Type C, Gaga, Aone, and Togatta hot springs), respectively. However, in comparison, the ratio was found to be higher for meteoric waters (0.7077–0.7079). The water from the central volcanic edifice (Type B) was found to be similar to that of nearby volcanic rocks in their Sr isotopic ratio. This indicates that the Sr in water was derived from shallow volcanic rocks. The ⁸⁷Sr/⁸⁶Sr ratio for water from the Zao hot spring (Type A) was intermediate between those of the pre-Tertiary granitic and the Quaternary volcanic rocks, thus suggesting that the water had reacted with both volcanic and granitic rocks. The location of the vapor–liquid separation was determined as the boundary of the pre-Tertiary granitic and the Quaternary volcanic rocks by comparing the results of this strontium isotopic study with those of Kiyosu and Kurahashi [Kiyosu, Y., Kurahashi, M., 1984. Isotopic geochemistry of acid thermal waters and volcanic gases from Zao volcano in Japan. J. Volcanol. Geotherm. Res. 21, 313–331.].     

唐山豪门（集团）公司玉田啤酒厂饮用天然矿泉水

玉田啤酒厂饮用天然矿泉水井位于城关镇三里屯西２００ｍ，玉田酒厂院内，矿泉水赋存于第四系砂、砾卵石层中，属含锶、偏硅酸的重碳酸钙·镁型矿泉水，现已开发利用。