岩石颗粒解离试验研究

试验确定，在用HCI和NaOH试剂解离硅质胶结的沉积岩时，浓度5％的试剂即可达到解离度95％以上，且颗粒表面特征、重矿物数量和重矿物标型特征较浓度10％的试剂处理的样品保存得更好。     

某些铀酰矿物加热后的荧光特征

本文描述了11个铀酰矿物加热后的显微荧光特征,并对实验结果进行了初步探讨。随着温度的升高,其相对荧光强度均有不同程度的衰减直至猝灭,但衰减的速度和猝灭的温度是各不相同的。热至200℃时测量的荧光光谱和常温下的荧光光谱相比,不同矿物变化也各不相同。本文根据实验结果绘制了荧光和温度关系曲线及加热至200℃时的荧光光谱曲线。这种荧光变化可能与加热后矿物失水和晶体结构变化有关。对鉴定铀酰矿物具有重要的意义。     

矿物热释氡找矿方法中氡的来源探讨

本文探讨了矿物热释氡找矿中氡的来源问题。我们对七五二花岗岩中铀矿床的无矿及含矿花岗岩用闪烁射气法进行了各种温度间的矿物热释氡量的测定;用包裹体爆裂法进行了爆裂温度及相对爆裂次数的测定。通过实验发现,加热样品在包裹体爆裂以前,能释放出大部分氡,在包裹体大量爆裂的温度区间热释氧量反而很少。磨破包裹体放出氡后,再加热仍然有氡气释放出来。用包裹体中的铀含量计算出的氡量低于测定方法的灵敏度,无法测出,说明矿物热释氡量与包裹体无关。样品又做了化学铀分析和放射化学镭分析。明显看出热释氡量与铀、氡含量成正相关关系。各种实验均证明氧气不是来自包裹体,而是来源于整个矿物。     

我国古代认识的主要含铜矿物

根据大量的考古出土实物,以及依据古籍中涉及矿物的形态、颜色、光泽、解理、断口、味感和某些化学性质的描述,我们认为中国古代认识的主要含铜矿物已达13种。它们是:自然元素一种:自然铜;硫化物三种:黄铜矿、辉铜矿、斑铜矿;硫盐三种:硫砷铜矿、车轮矿、黝铜矿;氧化物二种:黑铜矿、赤铜矿;硫酸盐二种:水胆矾、胆矾;碳酸盐二种:孔雀石、蓝铜矿（详见正文附表）。     

横断山不同成因类型花岗岩类岩石中黑云母的标型特征

本文研究了横断山区不同成因类型花岗岩类岩石中黑云母的化学成分、微量元素、结构和物理性质等。结合花岗岩类岩石的成因类型,将黑云母分为三个亚种:富镁黑云母(MF=1.3—1.5)、镁黑云母(MF=1—1.3)和富铁黑云母(MF=0.5-1)。     

粘土矿物在过去环境变化研究中的应用

粘土矿物是一种广泛分布于地表的沉积物,其组合及含量的变化记录了源区过去气候环境变化的信息。因此,可以根据粘土矿物的含量和组合变化等信息推知其形成时期的气候环境,重建古环境,揭示气候环境演变的规律。粘土矿物是一种研究古环境演化重要的代用指标,在过去气候环境变化研究中有广阔的应用前景。     

Late Quaternary clay minerals off Middle Vietnam in the western South China Sea: Implications for source analysis and East Asian monsoon evolution

High-resolution clay mineral records combined with oxygen isotopic stratigraphy over the past 450 ka during late Quaternary from Core MD05-2901 off Middle Vietnam in the western South China Sea are re-ported to reconstruct a history of East Asian monsoon evolution. Variations in Illite, chlorite, and kaolinite contents indicate a strong glacial-interglacial cyclicity, while changes in smectite content present a higher frequency cyclicity. The provenance analysis indicates a mixture of individual clay minerals from various sources surrounding the South China Sea. Smectite derived mainly from the Sunda shelf and its major source area of the Indonesian islands. Illite and chlorite originated mainly from the Mekong and Red rivers. Kaolinite was provided mainly by the Pearl River. Spectral analysis of the kaolin-ite/(illite chlorite) ratio displays a strong eccentricity period of 100 ka, implying the ice sheet-forced win-ter monsoon evolution; whereas higher frequency changes in the smectite content show an ice sheet-forced obliquity period of 41 ka, and precession periods of 23 and 19 ka and a semi-precession period of 13 ka as well, implying the tropical-forced summer monsoon evolution. The winter monsoon evolution is generally in coherence with the glacial-interglacial cyclicity, with intensified winter monsoon winds during glacials and weakened winter monsoon winds during interglacials; whereas the summer monsoon evolution provides an almost linear response to the summer insolation of low latitude in the Northern Hemisphere, with strengthened summer monsoon during higher insolation and weakened summer monsoon during lower insolation. The result suggests that the high-latitude ice sheet and low-latitude tropical factor could drive the late Quaternary evolution of East Asian winter and summer monsoons, respectively, implying their diplex and self-contained forcing mechanism.     

利用非金属矿制备白炭黑现状及发展前景

简术了白炭黑的用途和制备方法，综述了利用非金属矿制备白炭黑的方法和技术现状，对充分利用非金属矿制备白炭黑提供思路并展望其发展前景。     

The heat capacity of two natural chlorite group minerals derived from differential scanning calorimetry

The heat capacity of natural chamosite (X_Fe=0.889) and clinochlore (X_Fe=0.116) were measured by differential scanning calorimetry (DSC). The samples were characterised by X-ray diffraction, microprobe analysis and Mössbauer spectroscopy. DSC measurements between 143 and 623?K were made following the procedure of Bosenick et?al. (1996). The fitted data for natural chamosite (CA) in J?mol^?1?K^?1 give: C _p,CA = 1224.3–10.685?×?10³?×?T ^??0.5???6.4389?× 10⁶?×T ^??2?+?8.0279?×?10⁸?×?T ^??3 and for the natural clinochlore (CE): C _p,CE = 1200.5–10.908?×?10³?×T ^??0.5?? 5.6941?×?10⁶?×?T ^??2?+?7.1166?×?10⁸?×?T ^??3. The corrected C _p-polynomial for pure end-member chamosite (Fe₅Al)[Si₃AlO₁₀](OH)₈ is C _p,CAcor = 1248.3–11.116?× 10³?×?T ^??0.5???5.1623?×?10⁶?×?T ^??2?+?7.1867?×?10⁸×T ^??3 and the corrected C _p-polynomial for pure end-member clinochlore (Mg₅Al)[Si₃AlO₁₀](OH)₈ is C _p,CEcor = 1191.3–10.665?×?10³?×?T ^??0.5???6.5136?×?10⁶?×?T ^??2?+ 7.7206?×?10⁸?×?T ^??3. The corrected C _p-polynomial for clinochlore is in excellent agreement with that in the internally consistent data sets of Berman (1988) and Holland and Powell (1998). The derived C _p-polynomial for chamosite (C _p,CAcor) leads to a 4.4% higher heat capacity, at 300?K, compared to that estimated by Holland and Powell (1998) based on a summation method. The corrected C _p-polynomial (C _p,CAcor) is, however, in excellent agreement with the computed C _p-polynomial given by Saccocia and Seyfried (1993), thus supporting the reliability of Berman and Brown's (1985) estimation method of heat capacities.     

EXTRACTION OF THE STANDARD ENTHALPY OF FORMATION OF MINERALS FROM REVERSED EXPERIMENTAL DATA WITH INS

An improvement on the new method of Intervalhalving-Scanning (INS) proposed by the senior author for derivation of thermodynamic properties of minerals from reversed experiment (REP) data has been made in the present work. The treatment of the REP data of 6 reactions in the system MgO-SiO_2-H_2O and the derivation of △_(?)H(?) (298. 15K) for minerals Talc,Forsterite and Anthophyllite are chosen as an example for demonstration of the application of the method.INS is quite different from all the methods for the derivation in the literature and throughout based on thermodynamic principles and equations so that its thermodynamical validity is thoroughgoing.