基于动态降温结晶工艺的盐湖卤水镁锂分离研究

青海盐湖卤水锂资源储量丰富,高镁锂比卤水存在镁锂分离难的问题。基于非平衡动态降温过程中不同盐组分结晶行为存在差异的原理,开展了强制分离高镁锂比卤水的研究,考察了卤水镁锂比、降温速率、流体状态和卤水温度对镁锂分离效果的影响,并分析了结晶过程中镁锂分离的介稳性特点。结果表明,通过非平衡动态降温结晶析出MgCl₂·6H₂O,可以实现卤水脱镁和镁锂分离,当降温速率为-1.25℃/min、卤水温度在70℃至50℃范围内,镁锂比在10∶1～80∶1时,镁锂分离因子最高可达到1.876,结晶的MgCl₂·6H₂O纯度最高为99.42%。非平衡动态降温结晶工艺相较于经典的盐田工艺,最多可将锂损失率从模拟盐田工艺的38.39%降至7.56%。该工艺为盐湖卤水镁锂分离提供了一条新的思路,也为后续高纯锂盐的制备奠定了基础。     

全新世岱海流域化学风化及其对气候事件的响应

通过对岱海 12.08 m沉积岩芯 210Pb和 AMS- 14C精确定年及地球化学、物理指标的综合分析,重建了包括 8.2 ka冷期、中世纪暖期 (MWP)和小冰期 (LIA)等典型气候事件在内的全新世以来所经历的化学风化及其环境演化过程.全新世早-中期 (9.0～ 3.5 ka),岱海流域处于温暖湿润气候环境,主要环境特征表现为流域化学风化显著增强、生物生产力逐步提高、湖泊水位大幅度抬升.在 7.90～ 8.25 ka期间存在一次冷气候事件,其发生时间与来自湖沼、海洋、生物组合和极地冰芯等在内的全球环境记录基本一致,具体表现为流域化学风化减弱、湖泊生产力降低以及湖泊水位下降. 2.5 ka以来,岱海沉积物中环境指标的显著变化,表明进入气候波动更频繁的新冰期.岱海沉积物中的指标变化也展示了本世纪以来的气候增暖过程,但其化学风化强度还没有达到 MWP的程度.     

东濮凹陷古近系沙河街组沙三段沉积期湖岸线的变化及岩相古地理特征

东濮凹陷沙三段地层为深水相暗色泥岩与砂岩频繁互层及深水相暗色泥岩与盐膏岩频繁互层.这种砂体是东濮凹陷很重要的含油气储层。过去这种砂体往往按照静态的模式被解释为重力流成因,随着勘探的不断深入,越来越多的证据表明这些砂体中存在着牵引流和暴露地表的标志,其成因和沉积模式需要重新认识。东濮凹陷沙三段沉积时期,湖平面变化频繁,有长周期,也有短周期。根据录井、电性及岩心等资料识别出湖平面变化的5级周期,其变化频率约为1000次/Ma。根据计算,东濮凹陷沙三段沉积时期湖水最大深度为30 m。高水位沉积期,湖岸线距盆地中心较远,盆地沉积中心发育暗色泥岩夹薄层碳酸盐岩,盆地边缘发育粗碎屑岩沉积;水位下降期,边缘相砂体不断向盆地中心进积;低水位期湖岸线向盆地中心退缩了1030 km,盆地沉积中心发育盐膏岩沉积,盐膏岩的周围发育低水位三角洲、扇三角洲和滨湖滩坝相的粗碎屑岩体。正是由于湖平面的变化引起的湖岸线迁移,导致高水位沉积期和低水位期湖盆的岩相古地理面貌发生很大的变化,根据这种动态的模式来预测砂体的分布,在指导油气勘探中产生了明显的效果。     

高盐度湖泊艾比湖风生流三维数值模拟

根据高盐度湖泊水动力特征,以西北咸水湖泊艾比湖为例,建立三维水动力数学模型。选取典型风场,分析风力作用下的高盐度湖泊风生流形成过程以及风生流水动力参数的三维空间分布特征。结果表明,艾比湖风生流形成在时间上可分为湖水流向和风向一致阶段、湖水运动方向逐渐偏离风向的过渡阶段及环流形成的稳定阶段等3个阶段。当流场达到稳定状态时,表层水体除中部存在若干小尺度环流外,大部分水域流向与风向基本一致;而湖泊中心区域底层水体流向与表层水体的流向大致相反,表现为很明显的补偿流。总体上,水平方向的流速自表层向下呈现递减的变化趋势,岸边流速大于中心流速,表现出与淡水湖泊基本相似的水动力空间分布特征。水体盐度增加对湖泊环流结构无影响。     

Major and trace element geochemistry of neutral and acidic thermal springs at El Chichón volcano,Mexico: Implications for monitoring of the volcanic activity

Four groups of thermal springs with temperatures from 50 to 80 °C are located on the S–SW–W slopes of El Chichón volcano, a composite dome-tephra edifice, which exploded in 1982 with a 1 km wide, 160 m deep crater left. Very dynamic thermal activity inside the crater (variations in chemistry and migration of pools and fumaroles, drastic changes in the crater lake volume and chemistry) contrasts with the stable behavior of the flank hot springs during the time of observations (1974–2005). All known groups of hot springs are located on the contact of the basement and volcanic edifice, and only on the W–SW–S slopes of the volcano at almost same elevations 600–650 m asl and less than 3 km of direct distance from the crater. Three groups of near-neutral (pH ≈ 6) springs at SW–S slopes have the total thermal water outflow rate higher than 300 l/s and are similar in composition. The fourth and farthest group on the western slope discharges acidic (pH ≈ 2) saline (10 g/kg of Cl) water with a much lower outflow rate (< 10 l/s).     

基于Copula函数的连河通江湖泊防洪安全设计:以洪泽湖为例

湖泊作为一种蓄水单元,尤其是大型过水性湖泊,是一种典型的平原型水库,在功能上与山谷型水库具有许多相似之处,但由于其特殊的地理地形构造,使得入湖洪水过程与入库洪水过程存在着较大的差异.在防洪安全设计研究中,山谷型水库关注的多是坝址洪水,即总的入库洪水过程,而对于湖泊来说,还需要关注各个分区的入湖洪水过程对湖区洪水演进的影...     

库车坳陷侏罗纪沉积环境和层序地层分析

通过对库车坳陷野外露头和钻井资料以及地震剖面的综合分析,对库车盆地侏罗纪沉积环境、层序划分进行了研究.库车盆地在侏罗纪时期为一非对称型坳陷型盆地,主要物源在盆地的北部.划分了13个三级层序,三个层序组,反映了三个大级别的旋回.最大湖侵期为阳霞组中上部,与当时有一个明显的气候变热期相一致.沉积环境在侏罗纪早期为辫状河-辫状河三角洲环境、中期为曲流河-三角洲环境,后期为三角洲和浅湖环境,中期有短暂的海泛发生.影响侏罗纪湖平面变化的主控因素为构造运动、气候变化、物源条件、河水的流入以及海侵的影响.在中侏罗世早期、晚期的最大湖侵和海泛的短暂时期,形成了厚层的烃源岩分布.库车坳陷侏罗系虽然砂体分布广泛,厚度较大,然而由于陆相沉积环境的控制,非均质性较强、     

Playa‐lake sedimentation and organic matter accumulation in an Andean piggyback basin: the recent record from the Cuenca de Pozuelos,North‐west Argentina

Expansive playa‐lake systems situated in high‐altitude piggyback basins are important and conspicuous components of both modern and ancient cordilleran orogenic systems. Extant playa lakes provide vital habitat for numerous endemic species, whereas sediments from these deposystems may record signals of climate change or develop natural resources over geological time. Laguna de los Pozuelos (North‐west Argentina) provides the opportunity for an actualistic sedimentological and geochemical assessment of a piggyback basin playa lake in an area of critical interest for understanding Quaternary palaeoclimate dynamics. Silty clays and diatom ooze are the dominant playa‐lake centre microfacies, with concentrations of total organic carbon and biogenic silica commonly exceeding 1·5 wt% in this sub‐environment. Elemental and stable isotopic analyses point to a mixed organic matter composition in the playa‐lake centre, with substantial contributions from algae and transported aquatic macrophytes. Bulk sediment and organic mass accumulation rates in the southern playa‐lake centre approach 0·22 g cm^?2 year^?1 and 2·89 mg cm^?2 year^?1, respectively, indicating moderately rapid deposition with negligible deflation over historic time. Playa margin facies contain higher percentages of fragmented biogenic carbonate (ostracods and charophytes) and inorganically precipitated aragonite crusts due to seasonal pumping and evaporation of ground water. Organic matter accumulation is limited along these heavily bioturbated wet and dry mud flats. Fluvial–lacustrine transitional environments, which are key waterbird habitats, are either silty terminal splay (northern axis) or sandy deltas (southern axis) containing highly oxidized and partially allochthonous organic matter. Modern analogue data from Laguna de los Pozuelos provide key insights for: (i) environmental reconstructions of ancient lake sequences; and (ii) improving facies models for piggyback basins.     

青藏高原班公错的湖盆成因及构造演化

依据河湖相沉积物的沉积特征、沉积年龄和分布规律, 结合ETM+构造和第四系沉积地层的遥感解译, 对班公错湖盆的成因和构造演化特征进行系统的剖析.从地形地貌、沉积建造和构造上分析, 推断班公错湖盆为构造成因的拉分断陷湖盆.根据湖盆周边的断层活动特征和湖盆的沉积响应, 将班公错湖盆的演化分为4个阶段, 依次为湖盆打开的幼年期(晚于早中新世)、湖盆扩展的青年期(早于8.1±1Ma)、湖盆急剧扩展伴随湖盆中心南移的壮年期(晚于0.94Ma)和湖盆不对称萎缩的老年期(晚于0.23Ma).