Dehydration experiments on natural omphacites: qualitative and quantitative characterization by various spectroscopic methods

A series of natural omphacites from a wide range of P, T occurrences were investigated by electron microprobe (EMP), infrared (IR)-, Mössbauer (MS)- and optical spectroscopy in the UV/VIS spectral range (UV/VIS), secondary ion mass spectrometry (SIMS) and single crystal structure refinement by X-ray diffraction (XRD) to study the influence of hydrogen loss on valence state and site occupancies of iron. In accordance with literature data we found Fe²⁺ at M1 as well as at M2, and in a first approach assigned Fe³⁺ to M1, as indicated by MS and XRD results. Hydrogen content of three of our omphacite samples were measured by SIMS. In combination with IR spectroscopy we determined an absorption coefficient: ε _i,tot = 65,000 ± 3,000 lmol_H2O ^?1 cm^?2. Using this new ε _i,tot value, we obtained water concentrations ranging from 60 to 700 ppm H₂O (by weight). Hydrogen loss was simulated by stepwise heating the most water rich samples in air up to 800°C. After heat treatment the samples were analyzed again by IR, MS, UV/VIS, and XRD. Depending on the type of the OH defect, the grade of dehydration with increasing temperature is significantly different. In samples relatively poor in Fe³⁺ (<0.1 Fe³⁺ pfu), hydrogen associated with vacancies at M2 (OH bands around 3,450 cm^?1) starts to leave the structure at about 550°C and is completely gone at 780°C. Hydrogen associated with Al³⁺ at the tetrahedral site (OH bands around 3,525 cm^?1, Koch-Müller et al., Am Mineral, 89:921–931, 2004) remains completely unaffected by heat treatment up to 700°C. But all hydrogen vanished at about 775°C. However, this is different for a more Fe³⁺-rich sample (0.2 Fe³⁺ pfu). Its IR spectrum is characterized by a very intense OH band at 3,515 cm^?1 plus shoulder at 3,450 cm^?1. We assign this intense high-energy band to vibrations of an OH dipole associated with Fe³⁺ at M1 and a vacancy either at M1 or M2. OH release during heating is positively correlated with decrease in Fe²⁺ and combined with increase in Fe³⁺. That dehydration is correlated with oxidation of Fe²⁺ is indirectly confirmed by annealing of one sample in a gas mixing furnace at 700°C under reducing conditions keeping almost constant OH^? content and giving no indication of Fe²⁺-oxidation. Obtained data indicate that in samples with a relatively high concentration of Fe²⁺ at M2 and low-water concentrations, i.e., at a ratio of Fe^{2+ M2}/H > 10 dehydration occurs by iron oxidation of Fe²⁺ exclusively at the M2 site following the reaction: \( {\left[ {{\text{Fe}}^{{{\text{2 + [ M2]}}}}{\text{OH}}^{ - } } \right]} = {\left[ {{\text{Fe}}^{{{\text{3 + [ M2]}}}} {\text{O}}^{{{\text{2}} - }} } \right]} + {\text{1/2}}\;{\text{H}}_{{\text{2}}} \uparrow . \) In samples having relatively low concentration of Fe²⁺ at M2 but high-water concentrations, i.e., ratio of Fe^{2+ M2}/H < 5.0 dehydration occurs through oxidation of Fe²⁺ at M1.     

国际标准电子海图显示中几个关键技术的实现

针对我国建立基于标准电子海图显示信息系统(ECDIS)的关键技术问题,提出了相应的解决方案,包括自主知识产权的国际标准电子海图显示平台,符合国际海道测量组织(IHO)颁布的S-57、S-52和国际海事组织(IMO)颁布的(A)817、(A)694的数字海图显示标准。     

极地地区北斗三号单点定位精度分析

为分析BDS-3在极地地区的定位精度,选取两极地区10个MGEX站连续7 d的观测数据进行SPP和PPP实验。结果表明,BDS-3在两极地区可见卫星数及PDOP基本一致,平均可见卫星数约为9颗,PDOP约为2.3。BDS-3各频点间定位精度相差不大,南极地区SPP定位精度略优于北极,特别是U方向。北极地区E、N、U方向定位精度分别优于1 m、1 m和5 m,南极地区E、N、U方向定位精度分别优于1 m、1 m和2 m。BDS-3在两极地区PPP定位精度相当,与GPS定位精度基本一致,各频点组合定位精度在E、N、U方向均优于2 cm。     

新疆农垦148团农用土地估价研究

在分析农用土地价格特点的基础上,依据投入产出调查资料,采用标准田地价比照法,以参评作物地价和综合地价相结合的方式,建立了研究区包括平均地价和变幅的农用土地基准地价体系,并可据此计算每一宗地的地价。     

海雾生成过程中平流、湍流、辐射效应研究

推导出一个相对湿度方程,分析了在海雾生成过程中平流、湍流和辐射的效应.     

山东省沿海滩涂治理开发及建议

对山东省风暴潮灾害和已建的防潮工程进行初步分析;介绍山东省滩涂治理开发规划;对海堤标准、几种灾害遭遇的机率、防潮堤和防潮闸规划、必要的技术政策问题提出了自己的见解。     

A Comparison of Growth Biomarkers for Assessing Sublethal Effects of Cadmium on a Marine Gastropod, Nassarius festivus

The effect of cadmium on the growth of an intertidal marine gastropod, Nassarius festivus, was investigated using a number of biomarkers namely conventional measurements in terms of increase in shell length or body weight, scope for growth (SfG) and RNA/DNA ratio. After eight days of cadmium exposure, the no observable effect concentration (NOEC) and lowest observable effect concentration (LOEC) for the rate of increase in wet weight were 1.00 and 1.38 mg/l, respectively, while those for shell length did not show any significant difference from the control until day 16. After 16 days of cadmium exposure, the LOEC for both shell length and wet weight measurements was 0.22 mg/l. The 8-day SfG test was sensitive to cadmium stress, showing a significant decrease at 0.16 mg/l cadmium when compared to the control. The NOEC and LOEC of RNA/DNA ratio determination were 0.52 and 0.93 mg/l, respectively. An assessment based on sensitivity and technical complexity suggests that Scope for Growth is the most sensitive growth biomarker, followed by the RNA/DNA ratio, and then the conventional growth measurement based on shell size and body weight.     

航空电磁法在黄河口地区寻找浅层淡水的地质效果

对利用航空电磁法寻找浅层淡水的方法技术进行了探索,根据找水需要编制了保留区域场的三频标差异常图,对本区的海侵界线及海侵程度进行了研究,并在咸水区内圈定浅层淡水远景区29处,对各淡水远景区进行了分析与评价.     

工业测量中特高精度控制网的建立方法

提出一种同时利用精密标准尺的长度精度和精密经纬仪的角度精度的方法,阐明建立此等控制网的理论与实际操作要点。此种方法还可用于一组ＧＰＳ接收机的精度检验。     

冻土力学发展的新领域——深土冻土力学

Based on the practice of artificial freezing engineering in deep alluvium and simulation tests, it is found that there exists an obvious difference between frozen soil mechanics for shallow alluvium and for deep alluvium. The concept of frozen soil mechanics for deep alluvium, its research topics and methods are presented in this paper.