Bulk modulus of Fe-rich olivines corrected for non-hydrostaticity

In situ X-ray diffraction was used to measure the isothermal bulk modulus at room conditions (K_T0) of synthetic olivines with different iron contents. The chemical formulae of the olivine samples were ${({\mathrm{Fe}}_x,{\mathrm{Mg}}_{1?x})}_2\mathrm{Si}{\mathrm{O}}_4$ with x = 0.45; 0.64; 0.82; 1, with 1% standard deviation (referenced as Fa45, Fa64, Fa82 and Fa100, respectively). All experiments were performed in the multi-anvil apparatus installed at NSLS beamline X17B2, to pressures up to about 7 GPa. Unit-cell volumes under hydrostatic conditions and differential stresses present in the samples were calculated using the method developed by Singh et al. (1998), and pressures measured using NaCl as a standard were then corrected for these stresses. Using a second-order Birch–Murnaghan equation of state, we obtained the isothermal bulk modulus of each composition: $K_{T0}^{\mathrm{Fa45}}=131.4\pm 2.6$ GPa, $K_{T0}^{\mathrm{Fa64}}=132.1\pm 3.1$ GPa, $K_{T0}^{\mathrm{Fa82}}=136.3\pm 1.7$ GPa and $K_{T0}^{\mathrm{Fa100}}=134.8\pm 1.4$ GPa. These values combined with data available in the literature show that the K_T0 of Fe-rich olivines increases very slowly with the Fe content, but possibly not in a simple linear trend.     

Spatial variation in organic matter utilization by benthic communities from Yura River–Estuary to offshore of Tango Sea,Japan

We investigated the distribution of δ¹³C and δ¹⁵N of organic matter among benthic communities from the upper estuary of Yura River to offshore of Tango Sea, Japan, to determine spatial variation in utilization of organic matter by benthic communities. The δ¹³C values of benthic animals ranged from −27 to −15‰ in the upper estuary, −21 to −15‰ in the lower estuary, −20 to −16‰ in the shallow coast (5–10 m depths), −18 to −16‰ in the deep coast (30–60 m depths) and −19 to −15‰ in offshore (100–150 m depths) stations. Adapting the dual isotope values to mixing models, we estimated the relative contributions of potential food sources to the benthos diet. Phytoplankton and macroalgae that intruded the estuary in summer were utilized as alternative food aside from the terrestrial-origin organic matter assimilated by the estuarine benthic consumers. Resuspended benthic microalgae were important source of energy in the shallow coastal stations, while abundant supply of phytodetritus fueled the deep coastal and offshore benthic food webs. Spatial difference in the diet of benthic communities depends largely on the shifts in the primary carbon source. Thus, benthic communities are important link of autochthonous/allochthonous production and secondary production in the continuous river–estuary–marine system.     

Estuarine resources use by juvenile Flagfin mojarra (Eucinostomus melanopterus) in an inverse tropical estuary (Sine Saloum,Senegal)

The Flagfin mojarra, Eucinostomus melanopterus, is a marine spawner whose young individuals are common in the Sine Saloum inverse estuary (Senegal). The species offers the opportunity to study both the use of the estuarine nursery resources and the impact of the particular environment of the inverse estuary on these resources. This will lead to a better understanding of the functioning of the nursery. We investigated the resources used by juvenile Flagfin mojarra by coupling stomach contents and stable isotopes methods.     

A Whitecap Coverage Model Based on the Surface Slope For Criterion of Wave Breaking

Using the limit surface slope as a criterion of wave breaking,a simple model for estimatingthe spatial fraction of breaking surface of sea at an instant,which is regarded as the whitecap coverge inthis paper,is analytically derived from the probability density of surface slope based on Gaussianstatistics.The resulting fraction is found depending on the fourth moment of wave spectum,m_4,as well asthe critical threshold of surface slope.By expressing the fourth moment in terms of the Neumannspectrum,a formula linking the fraction and wind speed for fully developed sea states is obtianed.Anotherformula relating the fraction to both wind speed and fetch(or duration)is achieved by expressing m_4 interms of the Krylov spectrum and applying the empirical relationships used in the SMB ocean wave pre-dicting technique.A comparison between these results and the field data of whitecap coverage collected byMonahan and O＇Muircheartuigh shows an encouraging agreement.     

Changes in trophic flow structure of Independence Bay (Peru) over an ENSO cycle

During the strong warm El Niño (EN) that occurred in 1997/98, Independence Bay (14°S, Peru) showed a ca. 10 °C increase in surface temperatures, higher oxygen concentrations, and clearer water due to decreased phytoplankton concentrations. Under these quasi-tropical conditions, many benthic species suffered (e.g. macroalgae, portunid crabs, and polychaetes) while others benefited (e.g. scallop, sea stars, and sea urchins). The most obvious change was the strong recruitment success and subsequent proliferation of the scallop Argopecten purpuratus, whose biomass increased fiftyfold. To understand these changes, steady-state models of the bay ecosystem trophic structure were constructed and compared for a normal upwelling year (1996) and during an EN (1998), and longer-term dynamics (1996–2003) were explored based on time series of catch and biomass using Ecopath with Ecosim (EwE) software. Model inputs were based on surveys and landings data collected by the Instituto del Mar del Perú (IMARPE). Results indicate that while ecosystem size (total throughput) is reduced by 18% during EN, mainly as a result of decreased total primary production, benthic biomass remains largely unchanged despite considerable shifts in the dominant benthic taxa (e.g. scallops replace polychaetes as secondary consumers). Under normal upwelling conditions, predation by snails and crabs utilize the production of their prey almost completely, resulting in more efficient energy flow to higher trophic levels than occurs during EN. However during EN, the proliferation of the scallop A. purpuratus combined with decreased phytoplankton increased the proportion of directly utilized primary production, while exports and flows to detritus are reduced. The simulations suggest that the main cause for the scallop outburst and for the reduction in crab and macroalgae biomass was a direct temperature effect, whereas other changes are partially explained by trophic interactions. The simulations suggest that bottom-up effects largely control the system.     

Distinctive stable isotope ratios in important zooplankton species in relation to estuarine salinity gradients: Potential tracer of fish migration

To assess the potential of stable isotope ratios as an indicator of fish migration within estuaries, stable isotope ratios in important zooplankton species were analyzed in relation to estuarine salinity gradients. Gut contents from migratory juveniles of the euryhaline marine fish Lateolabrax japonicus were examined along the Chikugo River estuary of the Ariake Sea, which has the most developed estuarine turbidity maximum (ETM) in Japan. Early juveniles in March and April preyed primarily on two copepod species; Sinocalanus sinensis at lower salinities and Acartia omorii at higher salinities. Late juveniles (standard length > 40 mm) at lower salinities preyed exclusively on the mysid Acanthomysis longirostris until July and complementarily on the decapod Acetes japonicus in August. These prey species were collected along the estuary during the spring–summer seasons of 2003 and 2004, and their carbon and nitrogen stable isotope ratios (δ¹³C and δ¹⁵N) were evaluated. The δ¹³C values of prey species were distinct from each other and were primarily depleted within and in close proximity to the ETM (salinity < 10); S. sinensis (−26.6‰) < Acanthomysis longirostris (−23.3‰) < Acartia omorii (−21.1‰) < Acetes japonicus (−18.5‰). The overall gradient of δ¹³C with salinity occurred for all prey species and showed minor temporal fluctuations, while it was not directly influenced by the δ¹³C values in particulate organic matter along the estuary. In contrast to δ¹³C, the δ¹⁵N values of prey species did not exhibit any clear relationship with salinity. The present study demonstrated that δ¹³C has the potential for application as a tracer of fish migration into lower salinity areas including the ETM.     

漫灌条件下内蒙孪井灌区土壤水分动态变化特征

根据内蒙孪井灌区土壤水分观测资料,本文讨论了漫灌条件下该区土壤水分的动态变化规律.由于观测期间降雨对该区影响很小,主要分析了春灌期、灌溉间隔期和作物生长期土壤水分的变化特点.春灌期,灌溉水主要补给上层砂壤土,对下层土壤的补给相对较小;经过2次灌溉过后,土壤含水率不断升高.就蓄水能力而言,粘砂土的蓄水能力最强,砂壤土次之,灌水后水分主要滞留在这2层.结合灌溉渗漏量分析,研究认为,该区灌溉模式使得灌溉渗漏量较大,造成水资源浪费的同时还会引起地下水位上升,致使灌区下游土壤次生盐渍化加重.因此,采用灌溉量较小的喷灌、滴灌等方式,可以避免产生深层渗漏,节约水资源.     

Petrographic and geochemical characterization of seep carbonate from Bush Hill (GC 185) gas vent and hydrate site of the Gulf of Mexico

Authigenic carbonates are common at cold seep sites as a result of microbial oxidation of hydrocarbons. Seep carbonate samples were collected from the surface of the Bush Hill (Green Canyon Block 185, Gulf of Mexico), a mound containing gas hydrate. The carbonates consisted of oily, porous limestone slabs and blocks containing bioclasts and matrix. Analysis by X-ray diffraction shows that aragonite is the dominant mineral (89–99 wt% with an average of 94 wt%) in the matrix of seep carbonate. This cement occurs in microcrystalline, microspar, and sparite forms. The moderate ¹³C depletion of the seep carbonate (the most depleted one has δ¹³C value of −29.4‰, and 26 of 38 subsamples have δ¹³C values >−20.0‰) indicates that the non-methane hydrocarbons was incorporated during seep carbonate precipitation. Relative enrichment of ¹⁸O may be related to localized destabilization of gas hydrate or derived from ¹⁸O-enriched pore water originated from smectite–illite transition in the deep sediments. The total content of rare earth elements (REE) of the 5% HNO₃-treated solution of the carbonates is from 0.40 ppm to 30.9 ppm. The shale-normalized REE patterns show varied Ce anomalies from significantly negative, slightly negative, and no to positive Ce anomalies. Variable content of trace elements, total REE, and Ce anomalies in different samples and even in the different carbonate mineral forms (microcrystalline, microspar and sparite) of the same sample suggest that the formation condition of the Bush Hill seep carbonate is variable and complex, which is possibly controlled by the rate of fluid flux.     

Seafarers' access to jurisdictions over labour matters

The Maritime Labour Convention, 2006 outlines a framework for states to enforce jurisdiction over maritime labour matters, including the Flag State, Port State and Labour Supplying State. However, the Convention does not provide explicit guidance on jurisdiction determination. This article argues that seafarers should have the right to access the jurisdictions of member states, and that future amendment to the Convention should confirm this right. This paper first analyses current theories of maritime labour jurisdiction. Secondly, it conducts a comparative doctrinal analysis regarding adjudicative jurisdiction principles in common law and civil law systems. Thirdly, in three case studies involving concurrence jurisdictions of member states, this article finds that the authority of any single member state is not reliably accessible to seafarers, in particular when the state has no strong link with the seafarers. This article recommends that seafarers’ rights in the Convention to choose one jurisdiction from relevant member states should be confirmed in a future amendment.     

Cycling of dissolved and particulate nitrogen and carbon in the Framvaren Fjord, Norway: stable isotopic variations

The reaction pathways of nitrogen and carbon in the Framvaren Fjord (Norway) were studied through stable isotope analysis (δ¹⁵N and δ¹³C) of dissolved inorganic and particulate organic matter (POM). The variations in the isotopic compositions of the various C and N pools within the water column were use to evaluate the historical deposition of material to the sediments. The high δ¹⁵N-NH₄⁺ at the O₂/H₂S interface, as a consequence of microbial uptake between 19 and 25 m, results in extremely depleted δ¹⁵N-particulate nitrogen (PN) of approximately 1‰ within the particulate maximum at approximately 19 m. The carbon isotopic distribution of dissolved inorganic carbon (DIC) and particulate organic carbon (POC) within the interface suggests that the distinct microbial flora (Chromatium sp. and Chlorobium sp.) fractionate inorganic carbon to different degrees. The extremely light δ¹³C-POC within the interface (−31‰) appears to be a result of carbon uptake by Chromatium sp. while δ¹³C-POC of −12‰ is more indicative of Chlorobium sp. Nitrogen isotopic mass balance calculations suggested that approximately 75% of the material sinking to the sediments was derived from the dense particulate maximum between 19 and 25 m. The sediment distribution of nitrogen isotopes varied from 2‰ at the surface to approximately 6‰ at 30 cm. The nitrogen isotopic variations with depth may be an indicator of the depth or position of the O₂/H₂S interface in the fjord. Low sediment δ¹⁵N indicated that the interface was within the photic zone of the water column, while more enriched values suggested that the interface was lower in the water column potentially allowing for less fractionation during biological incorporation of dissolved inorganic nitrogen. Results indicate that the dense layers of photo-autotrophic bacteria in the upper water column impart unique carbon and nitrogen isotopic signals that help follow processes within the water column and deposition to the sediments.