天然矿泉水特殊组分的地球化学初步研究

本文以ＧＢ８５３７－８７《饮用天然矿泉水国家标准》为依据，从理论上阐述了天然矿泉水特殊组分（锂、氡、锶、铁、锌、溴、氟、碘、钼、偏硅酸、偏硼酸、硒、二氧化碳）的物理化学性质，分布、岍存形式及迁移规律，以便对我国矿泉水勘察和开发能有所裨益。     

长江口海域悬浮颗粒有机物的稳定氮同位素分布及其生物地球化学意义

对2006年2,5,8,11月份长江口海域表层水体中的悬浮颗粒物(SPM)进行稳定氮同位素分析,根据不同季节、不同区域内其1δ5N值的变化研究水体中氮的迁移、转化等生物地球化学过程,揭示其环境行为,从而对该海域的氮循环机制进行探索。研究发现:该海域悬浮颗粒有机物的稳定氮同位素组成(1δ5Np)分布范围较宽,在0.6‰~8.2‰之间,具有明显的时空分布特点,反映了不同程度的陆源输入和氮的生物地球化学过程的影响。口门内,表层水体中1δ5Np的变化主要受长江径流的陆源输入影响,生物地球化学作用影响较弱;最大浑浊带,水体中的悬浮颗粒有机氮受微生物的降解活动影响明显,各季节均存在不同程度的颗粒物分解作用;外海区,陆源输入减弱,悬浮颗粒物的δ15Np值主要受微藻的同化吸收作用以及一定程度的颗粒物分解作用影响。     

桂林洞穴滴水对应CaCO3沉积物的稳定同位素特征与环境意义

桂林地区降水及茅茅头大岩滴水滴速和现代碳酸盐的碳氧同位素研究表明:(1)滴水沉积的δ18O达到了同位素沉积平衡,洞穴滴水的δ18O与同期降雨的δ18O值呈正相关关系;(2)在旱季和湿季交替时,滴水δ18O值滞后于降雨δ18O受活塞效应的影响;(3)δ13C难以达到同位素沉积平衡,主要受滴水动力学影响;(4)同一洞穴不同滴水对环境的响应不同,如果洞穴顶板覆盖较厚,水分在土壤和岩层中滞留时间较长,滴水则反映受到平滑作用的降雨,反之则波动较大。     

Sea state estimation using multiple ships simultaneously as sailing wave buoys

The article presents initial ideas towards a network-based approach for sea state estimation used for marine operations and other maritime applications. In principle, all available means, ranging from in situ buoys, fleet of ships to remote sensing by satellite and aircraft, could be considered, emphasising that each means and any combinations among may act simultaneously. This study focuses on just one of the means; the use of ships as sailing wave buoys. The article introduces the wave buoy analogy, i.e. ship-as-a-wave-buoy, and it makes a proposal on how to impose (different) weights to the single ship-specific wave spectrum estimates obtained from multiple ships. Moreover, the work includes a discussion about the importance to associate a measure to reflect the (un)certainty of the wave spectrum estimate. The article presents a numerical case study, where multiple ships act simultaneously as wave spectrum-estimators. The case study relies on numerical motion simulations, as appropriate full-scale data is not yet available. In the analysis, it is shown that the use of simultaneous data from multiple ships leads to more accurate wave spectrum estimations.     

Fluid sources and stable isotope signatures in authigenic carbonates from the Northern Apennines,Italy

Authigenic carbonates are frequently associated with methane cold-seep systems, which extensively occur in various geologic settings worldwide. Of interest is the relation between the fluids involved in their formation and the isotopic signals recorded in the carbonate cements. Along the Northern Apennines foothills (Italy), hydrocarbons and connate waters still seeping nowadays are believed to be the primary sources for the formation of fossil authigenic carbonate found in Plio-Pleistocene marine sediments. Four selected outcrops of dolomitic authigenic carbonates were analysed to compare signature of seeping fluids with fractionation of stable carbon and oxygen isotopes recorded in the carbonate.Along the foothills, deep methane-rich fluids spontaneously rise to the surface through mud volcanoes or are exploited in wells drilled nearby to the fossil Plio-Pleistocene authigenic carbonates. The plumbing system providing fluids to present-day cold seeps was structurally achieved in Late Miocene and Plio-Pleistocene. δ¹³C values of methane, which vary from −51.9 to −43.0‰ VPDB, indicate that gas composition from the deep hydrocarbon reservoirs is relatively uniform along the foothills. On the contrary, δ¹³C in fossil authigenic carbonates strongly varies among different areas and also within the same outcrop.The different carbon sources that fed the investigated carbonates were identified and include: thermogenic methane from the deep Miocene reservoirs, ¹³C-enriched CO₂ derived from secondary methanogenesis and microbial methane from Pliocene successions buried in the Po Plain. The δ¹³C variability documented among samples from a single outcrop testifies that the authigenic carbonates might represent a record of varying biogeochemical processes in the hydrocarbon reservoirs. The sources of stable oxygen isotopes in authigenic carbonates are often ascribed to marine water. Oxygen isotopic fractionation in the dolomite cements indicates that marine pore water couldn't be the sole source of oxygen. δ¹⁸O values provide a preliminary evidence that connate waters had a role in the carbonates precipitation. The concomitant occurrence of active cold seepages and fossil record of former plumbing systems suggests that generation and migration of hydrocarbons are long-lasting and very effective processes along the Northern Apennines foothills.     

Sea,freshwater or saltpans? Foraging ecology of terns to assess mercury inputs in a wetland landscape: The Ebro Delta

The Ebro catchment, the largest river basin in Spain, includes various heavily industrialized areas. Among these is the Flix site, where a chemical plant has been operating since the beginning of the 20th century. This extended operational period, together with the construction of a dam next to the factory around 1960, resulted in the accumulation of large amounts of heavily polluted sediments in the adjacent riverbed, many of which are contaminated by mercury. Pollutants from Flix are carried downstream by the Ebro River to its delta. In order to assess the transfer of mercury to the complex river estuary ecosystem, we studied the ecology of the tern community living there as these birds segregate into a range of habitats. For this purpose, first we used stable isotope analysis (SIA) (δ³⁴S, δ¹³C, δ¹⁵N) of eggs to determine the trophic ecology and habitat partitioning of several tern species (Common, Sandwich, Little, Gull-Billed and Whiskered Tern) breeding sympatrically, in order to link their foraging ecology with habitat types. Next we measured mercury concentrations in eggs to monitor the input of this metal into the diverse habitats. With the exception of the Little Tern, the other terns used a restricted habitat range in the Ebro Delta, as shown by C and S isotopes; the Gull-Billed and Whiskered Tern foraged in freshwater habitats, while the Common and Sandwich Tern used marine habitats. This restricted feeding behavior of the Gull-Billed and Common Tern contrasts with previous reports in other breeding sites. The Little Tern, which showed a wide range of isotopic values, was found to be an opportunistic forager but fed mainly in saltpans, a feeding habitat not reported previously for this species in this area. We found that mercury concentrations are related to foraging habitat and diet, and are unexpectedly higher in species feeding on demersal prey in marine habitats and also higher in birds feeding in saltpans than in those feeding in freshwater habitats. The mercury concentrations found in the Little and Common Tern eggs sampled in “Punta de la Banya” may be sufficiently high to endanger breeding success.     

Chemosynthetic trophic support for the benthic community at an intertidal cold seep site at Mocha Island off central Chile

We analyzed C and N stable isotope ratios of benthic fauna and their potential food sources at an intertidal methane seep site and a control site without emanation at Mocha Island (central Chile). The objective was to trace the origin of the main food sources used by the local heterotrophic fauna, based on the hypothesis that chemosynthetic production could be partially fueling the local food web at the seep site. Food sources sampled at both sites included macroalgae, particulate organic matter and bacteria-like filaments found growing over the red algae Gelidium lingulatum within the areas of active methane release.     

Evidence That Sea State Bias is Different for Ascending and Descending Tracks

Jason-1 and TOPEX/Poseidon (T/P) measured sea-surface heights (SSHs) are compared for five regions during the verification tandem phase. The five regions are of similar latitude and spatial extent and include the Gulf of Mexico, Arabian Sea, Bay of Bengal, and locations in the Pacific and Atlantic Oceans away from land. In all five regions, a bias, defined as Jason SSH—TOPEX-B SSH, exists that is different for ascending and descending tracks. For example, in the Gulf of Mexico the bias for ascending tracks was ?0.13 cm and the bias for descending tracks was 2.19 cm. In the Arabian Sea the bias for ascending tracks was ?2.45 cm and the bias for descending tracks was ?1.31 cm. The bias was found to depend on track orientation and significant wave height (SWH), indicating an error in the sea state bias (SSB) model for one or both altimeters. The bias in all five regions can be significantly reduced by calculating separate corrections for ascending and descending tracks in each region as a function of SWH. The correction is calculated by fitting a second-order polynomial to the bias as a function of SWH separately for ascending and descending tracks. An additional constraint is required to properly apply the correction, and we chose to minimize the sum of the TOPEX-B and Jason-1 root-mean-square (rms) crossover differences to be consistent with present SSB models. Application of this constraint shows that the correction, though consistent within each region, is different for each region and that each satellite contributes to the bias. One potential source that may account for a portion of the difference in bias is the leakage in the wave forms in TOPEX-B due to differing altitude rates for ascending and descending tracks. Global SSB models could be improved by separating the tracks into ascenders and descenders and calculating a separate SSB model for each track.     

页岩气成藏的关键因素

为了了解页岩气成藏的主控因素,对国内外页岩气的成藏条件进行了梳理,经综合分析认为,稳定的区域构造环境为泥、页岩的持续沉降提供了可容空间,奠定了页岩气成藏的物质基础;持续的沉降作用为泥、页岩的不间断受热和生烃提供了热力学条件;构造隆升幅度小为页岩气的保存提供了的保障,因此,区域构造稳定可能是页岩气成藏的关键。以美国福特沃斯盆地Barnett页岩的埋藏史为基础,通过四川盆地和鄂尔多斯盆地古生界泥页岩的埋藏史对比分析认为,鄂尔多斯盆地页岩气的成藏条件可能好于四川盆地,实现页岩气突破的可能性更大。     

Habitat heterogeneity influences cold‐seep macrofaunal communities within and among seeps along the Norwegian margin – Part 2: contribution of chemosynthesis and nutritional patterns

The relative contribution of chemosynthesis in heterotrophic fauna at seeps is known to be influenced by depth and by habitat. Using stable isotopes of carbon and nitrogen, we investigated macro‐ and megafaunal nutritional patterns in Norwegian margin cold seeps by comparing food webs both among habitats within a seep site and between different sites. The very active Håkon Mosby mud volcano (HMMV) is characterized by geochemical gradients, microbial activity and faunal zonation from the centre to the periphery. The Storegga Slide (600–900 m depth) has pockmarks with patchy less active seeps, and also shows concentric zonation of habitats but at much smaller spatial scale. The dominant carbon source for macrofaunal nutrition in both areas was chemosynthetically fixed and the bulk of organic carbon was derived from sulphur‐oxidizing bacteria. In HMMV, food chains were clearly separated according to habitats, with significantly lighter δ¹³C signatures on microbial mats and adjacent sediment (?33.06 to ?50.62‰) than in siboglinid fields (?19.83 to ?35.03‰). Mixing model outputs revealed that the contribution of methane‐derived carbon was small in siboglinid fields (0–17%) but significant (39–61%) in the microbial mats. Moreover, the variability of macrofauna signatures within this later habitat suggests the co‐occurrence of two food chains, one based on primary production via methanotrophy and the other via sulphide oxidation. The length of the food chains also varied among habitats, with at least one more trophic level in the siboglinid fields located at the periphery of the volcano. Conversely, in Storrega pockmarks, faunal δ¹³C signatures did not vary among habitats but among species, although separate food chains seem to co‐occur. The small size of the seepage areas and their lower fluxes compared to HMMV allow more background species to penetrate the seep area, increasing the range of δ¹⁵N and the trophic level number. Probably due to the higher flux of photosynthetic particulate organic carbon, the overall chemosynthesis‐based carbon contribution in invertebrate nutrition was lower than that in HMMV.